Search results for " engineering"

Intramolecular Hydrogen Bond, Hirshfeld Analysis, AIM; DFT Studies of Pyran-2,4-dione Derivatives

2021

Intra and intermolecular interactions found in the developed crystals of the synthesized py-ron-2,4-dione derivatives play crucial rules in the molecular conformations and crystal stabili-ties, respectively. In this regard, Hirshfeld calculations were used to quantitatively analyze the different intermolecular interactions in the crystal structures of some functionalized py-ran-2,4-dione derivatives. The X-ray structure of pyran-2,4-dione derivative namely (3E,3′E)-3,3′-((ethane-1,2-diylbis(azanediyl))bis(phenylmethanylylidene))bis(6-phenyl-2H-pyran-2,4(3H)-dione) was determined. It crystallized in the monoclinic crystal system and C2/c space group with unit cell parameters: a = 14.0869(4) …

Crystal structure of the pyridine–diiodine (1/1) adduct

2015

In the title adduct, C5H5N·I2, the N—I distance [2.424 (8) Å] is remarkably shorter than the sum of the van der Waals radii. The line through the I atoms forms an angle of 78.39 (16)° with the normal to the pyridine ring.

Halogen Bonds in 2,5-Dihalopyridine-Copper(I) Halide Coordination Polymers

2019

Two series of 2,5-dihalopyridine-Cu(I)A (A = I, Br) complexes based on 2-X-5-iodopyridine and 2-X-5-bromopyridine (X = F, Cl, Br and I) are characterized by using single-crystal X-ray diffraction analysis to examine the nature of C2&minus

Pyrolytic behavior of lignocellulosic-based polysaccharides

2018

The thermochemical behavior of cellulose, glucomannan, and xylan was investigated by pyrolysis–gas chromatographymass spectrometry (Py-GC/MS). In each case, major GC-amenable condensable products were classified into several compound groups, and the formation of these monomer-related fragments from the model substance samples was determined at 500, 600, and 700 C with a residence time of 5 s and 20 s. The results revealed that despite some general formation trends, no compound group was selectively formed at certain temperatures. Of the 11 product groups, the primary ones, including lactone, furan, and cyclopentenone derivatives, accounted for 72–85% (from cellulose), 86–90% (from glucomann…

System for Executing Encrypted Java Programs

2017

A System to Control the Atmosphere in the Headspace of the Malaxation Machine to Improve the Fatty Acid Composition of Extra Virgin Olive Oils

2015

In recent years, oxygen content regulation during malaxation has been noted as a process parameter. As concluded by many studies, the presence of oxygen during malaxation has a key role in for improving the quality of Extra Virgin Olive Oil (EVOO) in terms of volatile and phenolic components. There are, however, very few studies of the influence of oxygen in the malaxation machine headspace on the fatty acid composition of Extra Virgin Olive Oil (EVOO). The aim of this study is to evaluate the influence of oxygen in the malaxation machine headspace on Nocellara del Belice EVOO fatty acids. During of the malaxation process, the atmosphere inside the malaxation machine was modified by blowing…

ELECTRICAL DISCHARGE MACHINING - A HIGH FUTURE NONCONVENTIONAL PROCESSING PROCESS

2021

Electrical discharge machining is one of the most common processes for processing metallic materials. This process is characterized by the lack of mechanical pressure on the object that ensures the macroscopic location of the erosive agent. This scientific paper highlights a study based on experimental data processing as well as modeling the most important technological parameters for dimensional processing by electrical discharge machining with and without magnetic activation. In this context, the modeling and optimization of process parameters is approached, which can lead to the quality increasing of the processed surface, to an increase of the processing productivity and to a reduction …

Transferts de matière au travers des emballages au contact de produits alimentaires

2009

Le point sur des recherches dans le domaine des transferts de matière au travers des emballages : impact sur la qualité du produit, causes de ces transferts.

Explaining local governments' cost efficiency: Controllable and uncontrollable factors

2020

Abstract Efficient and effective management of public resources is essential at all levels of government. This issue has gained momentum due to the strains that affected public sector finances after the onset of the 2007/08 crisis in many countries, particularly in Europe. In this article, we evaluate the influence of environmental variables that affect local government efficiency in one European country, Spain, during the crisis years (2009–2015). To this end, and considering the possible influence of both controllable and uncontrollable factors, we use an approach that is able to analyse their impact across the conditional distribution of performance, and which controls for the (likely) e…

Rayleigh-instability-driven dewetting of thin Au and Ag films on indium-tin-oxide surface under nanosecond laser irradiations

2013

Investigations have been carried out on laser-beam-induced nanoparticle (NP) formation in thin (5 nm) Au and Ag films on indium-tin-oxide substrate. After the irradiation the films were observed to break-up into NPs through a dewetting mechanism. This mechanism was investigated as a Rayleigh-instability- driven process. In fact, for each used laser fluence, the resulting Au and Ag NPs' mean size and surface-to-surface mean distance were quantified and correlated between them in the framework of the Rayleigh-instability theory showing an excellent agreement. © The Institution of Engineering and Technology 2013.