Search results for " equilibrium"
showing 10 items of 533 documents
Aqueous Solubility Diagrams for Cementitious Waste Stabilization Systems: II, End-Member Stoichiometries of Ideal Calcium Silicate Hydrate Solid Solu…
2001
Solubility in the fully hydrated CaO–SiO2–H2O system can be best described using two ideal C-S-H-(I) and C-S-H-(II) binary solid solution phases. The most recent structural ideas about the C-S-H gel permit one to write stoichiometries of polymerized C-S-H-(II) end-members as hydrated precursors of the stable tobermorite and jennite minerals in the form of 5Ca(OH)2·6SiO2·5H2O and 10Ca(OH)2·6SiO2·6H2O, respectively. For thermodynamic modeling purposes, it is more convenient to express the number of basic silica and portlandite units in these stoichiometries using the coefficients nSi and nCa. Thermodynamic solid-solution aqueous-solution equilibrium modeling by applying the Gibbs energy minim…
Interaction of polyelectrolytes with oppositely charged micelles studied by fluorescence and liquid chromatography
2005
It is studied by spectrofluorimetry the association of ionized cationic micelles (cetyltrimethylammonium bromide, CTAB) with oppositely charged polyelectrolyte [sodium poly(styrenesulfonate), PSSNa]. CTAB provokes a change in the fluorescence intensity emitted by PSSNa. The investigated surfactants form micelle-like aggregates before critical micellar concentration (CMC). Two approaches (binding and partition equilibrium) are used to obtain the association constant, KA, number of CTAB molecules in a binding site, N, and apparent partition coefficient, Γ. Analysis of the parameters as a function of polymer concentration and ionic strength μ is performed. The effect of μ shows an enhancement …
Biosensor-based kinetic and thermodynamic characterization of opioids interaction with human μ-opioid receptor.
2019
Development of opioid analgesics with minimal side effects requires substantial knowledge on structure-kinetic and -thermodynamic relationship of opioid-receptor interactions. Here, combined kinetics and thermodynamics of opioid agonist binding to human μ-opioid receptor (h-μOR) was investigated using real-time label-free surface plasmon resonance (SPR)-based method. The N-terminal end truncated and C-terminal 6His-tagged h-μOR was constructed and expressed in E. coli. Receptor was purified, detergent-solubilized and characterized by circular dichroism. The uniform immobilization of h-μOR on Ni-NTA chips was achieved using hybrid capture-coupling approach followed by reconstitution in lipid…
Producer's spatial equilibrium with a fuzzy constraint
1980
The classical theory of the producer’s equilibrium rests on two sets of particularly restrictive hypotheses. First it is implicitely assumed that all inputs and outputs are located in a single place where the producer is also implanted and where the production is carried out. Next it is assumed that the producer follows a precise behaviour pattern, by this we mean that the producer has complete information concerning the conditions of hisproductive activity and he has perfect command over both the set of inputs and the set of outputs; he realises the maximum profit allowed by the technological constraint which limits his possible actions and by the given price system. The aim of this study …
On Capturing Rent from a Non-Renewable Resource International Monopoly: A Dynamic Game Approach
2005
In this paper we model the case of an international non-renewable resource monopolist as a dynamic game between a monopolist and n importing countries governments, and we investigate whether a tariff on resource imports can be advantageous for the consumers of the importing countries when the monopolist sets the price and the importing countries governments act in a non-cooperative way. We find that a tariff is advantageous for the consumers even when there is not commitment to the trade policy although the part of the rent that can be reaped by the importing countries decreases substantially with the number of importing countries. The optimality of the tariff in our dynamic game is explain…
Phytoplankton equilibrium phases during thermal stratification in a deep subtropical reservoir
2008
SUMMARY 1. Equilibrium and non-equilibrium hypotheses have often been used to explain observations in community ecology. Published case studies have demonstrated that steady state phytoplankton assemblages are more likely to occur in deep lakes than in shallow mixed ones. 2. Phytoplankton seasonal succession was studied by weekly sampling in Faxinal Reservoir (S Brazil), a subtropical deep, clear, warm monomictic and slightly eutrophic reservoir. This study demonstrated an alternation of steady and non-steady state phases of phytoplankton assemblages with different dominant species during the steady states. 3. During the studied period, three steady states were identified with different dom…
The Economic Impact of the South-North Water Transfer Project in China: A Computable General Equilibrium Analysis
2006
Water resources are unevenly spread in China. Especially the basins of the Yellow, Hui and Hai rivers in the North are rather dry. To increase the supply of water in these basins, the South-to-North Water Transfer project (SNWT) was launched. Using a computable general equilibrium model this study estimates the impact of the project on the economy of China and the rest of the world. We contrast three alternative groups of scenarios. All are directly concerned with the South-to-North water transfer project to increase water supply. In the first group of scenarios additional supply implies productivity gains. We call it the “non-market” solution. The second group of scenarios is called “marke…
A global perspective on effectiveness of aid for trade
2013
Recent global initiatives on debt relief and development assistance call for increasing aid for trade to the poorest countries. The paper applies a multi-country computable general equilibrium model to measure the effectiveness of alternative aid for trade categories. The findings show that aid for trade policies expand trade and alleviate international income inequalities in the recipient countries, that will benefit mainly from aid for trade adjustment and technical assistance.
A General Equilibrium Analysis of Climate Change Impacts on Tourism
2004
This paper studies the economic implications of climate-change-induced variations in tourism demand, using a world CGE model. The model is first re-calibrated at some future years, obtaining hypothetical benchmark equilibria, which are subsequently perturbed by shocks, simulating the effects of climate change. We portray the impact of climate change on tourism by means of two sets of shocks, occurring simultaneously. The first shocks translate predicted variations in tourist flows into changes of consumption preferences for domestically produced goods. The second shocks reallocate income across world regions, simulating the effect of higher or lower tourists' expenditure. Our analysis highl…
The economic impact of water taxes: a computable general equilibrium analysis with an international data set
2008
Water is scarce in many countries. One instrument for improving the allocation of a scarce resource is (efficient) pricing or taxation. However, water is implicitly traded on international markets, particularly through food and textiles, so that the impacts of water taxes cannot be studied in isolation, but require an analysis of international trade implications. We include water as a production factor in a multi-region, multi-sector computable general equilibrium model (GTAP), to assess a series of water tax policies. We find that water taxes reduce water use and lead to shifts in production, consumption and international trade patterns. Countries that do not levy water taxes are nonethele…