Search results for " est"
showing 10 items of 4799 documents
The ensemble switch method and related approaches to obtain interfacial free energies between coexisting phases from simulations: a brief review
2015
The accurate estimation of the excess free energy due to an interface between coexisting phases of a model system by computer simulation often is a challenging task. We review here two methods, whi...
Phosphasalen group IV metal complexes: synthesis, characterization and ring opening polymerization of lactide.
2020
International audience; We report the synthesis of a series of Zr and Ti complexes bearing phosphasalen which differs from salen by the incorporation of two P atoms in the ligand backbone. The reaction of phosphasalen proligands (1a-1c)H2 with Zr(CH2Ph)4 led to different products depending on the nature of the N,N-linker in the ligand. In case of ethylene-linked phosphasalen, octahedral Zr complex 2a formed as a single stereoisomer in trans geometry. With the phenylene linker, it was shown by dynamic NMR spectroscopy that complex 2b exists as a mixture of trans and cis-β isomers in solution, both enantiomers (Δ and Λ) of the cis-β isomer being in fast equilibrium with respect to the NMR tim…
Anticipating the impact of pitfalls in kinetic biodegradation parameter estimation from substrate depletion curves of organic pollutants
2019
[EN] Accurate and reliable estimation of kinetic parameters of pollutant biodegradation processes is essential for environmental and health risk assessment. Common biodegradation models proposed in the literature, such as the nonlinear Monod equation and its simplified versions (e.g. Michaelis-Menten-like and first-order equations), are problematic in terms of accuracy of kinetic parameters due to the parameter correlation. However, a comparison between these models in terms of accuracy and reliability, related to data imprecision, has not been performed in the literature. This task is necessary, mainly because the model selection cannot be straightforward, as shown in this work. To facilit…
Soil moisture modelling of a SMOS pixel: interest of using the PERSIANN database over the Valencia Anchor Station
2010
In the framework of Soil Moisture and Ocean Salinity (SMOS) Calibration/Validation (Cal/Val) activities, this study addresses the use of the PERSIANN-CCS<sup>1</sup>database in hydrological applications to accurately simulate a whole SMOS pixel by representing the spatial and temporal heterogeneity of the soil moisture fields over a wide area (50×50 km<sup>2</sup>). The study focuses on the Valencia Anchor Station (VAS) experimental site, in Spain, which is one of the main SMOS Cal/Val sites in Europe. <br><br> A faithful representation of the soil moisture distribution at SMOS pixel scale (50×50 km<sup>2</sup>) requires an accurate estimation…
A Comparison between Drifter and X-Band Wave Radar for Sea Surface Current Estimation
2016
This paper deals with exploitation of the wave radar system for sea surface current estimation in a coastal zone. In particular, we present the results of the processing of the radar data collected by an X-band marine radar installed in Capo Granitola site, which is located in the south-west part of Sicily, on 15 May 2015. The effectiveness of the data processing is analyzed by comparing the wave radar estimated sea surface current with that provided by the Lagrangian drifters along its movement trajectory. During the measurement campaign, three drifter releases are carried out and for each one the comparison is provided in terms of the mean error and standard deviation. In addition, we rep…
Economic performance and risk of farming systems specialized in perennial crops: An analysis of Italian hazelnut production
2019
Abstract Assessing farm profitability and economic risk is important to support farmers' decisions. Several factors affect yields and product prices, in turn influencing farmers' income level and economic risk. However, the literature has often neglected to explicitly account for the role of product quality. This is particularly important for crops such as hazelnut because farmers' prices vary according to the quality of the harvested product. Furthermore, it seems fundamental to disentangle the role of parameters influencing farm results, noticeably yield, product price and quality. This is because farmers select their risk management tools to satisfy their needs, but these are often suita…
The north-eastern aeolian ‘European Sand Belt’ as potential record of environmental changes: A case study from Eastern Latvia and Southern Estonia
2016
Abstract The Latvian and Estonian inland dunes belong to the north-eastern part of the ‘European Sand Belt’ (ESB). These dunes are widely distributed over broad glaciolacustrine plains and Late Glacial alluvial deltas, considered to be potential sources for the aeolian material. Little is known about these aeolian sediments and their substratum; here we present a detailed sedimentary structural and textural characterisation together with a luminescence-based chronology. Through a comparison between grain-size, rounding of quartz grains and surface characteristics in medium/coarse (0.5–0.8 mm) sand, and the light mineral content, we found an alternation of aeolian and periglacial components.…
Shell sclerochronology and stable isotopes of the bivalve Anomalocardia flexuosa (Linnaeus, 1767) from southern Brazil: Implications for environmenta…
2017
Abstract This study presents the first stable isotopic and sclerochronological calibration of the bivalve Anomalocardia flexuosa (Linnaeus, 1767) in relation to environmental variables in a subtropical coastal area of southern Brazil. We investigate incremental shell growth patterns and δ18O and δ13C values of modern specimens collected alive from the Laguna Lagoonal System (LLS). Shells of Anomalocardia flexuosa are also one of the main biological components of pre-Columbian archaeological shell mounds and middens distributed along the Brazilian coastline. We therefore selected archaeological specimens from a local late Holocene shell mound (Cabecuda) to compare their stable carbon and oxy…
New data about the landscape of the first occupation of Mallorca: Coval Simó (Escorca, Mallorca)
2020
The Coval Simó shelter provides some of the oldest evidence for settlement on the island of Mallorca and the Balearic archipelago. It also has the peculiarity of being a habitat in a mountain area, so that the human groups that settled there had to adapt their agricultural and farming system to this environment. The plant remains (wood charcoal and seeds) recovered in the occupation levels allow us to address these issues, since they are the result of the different activities developed in this cavity: fuel for domestic activities, food for livestock, etc. The results of this study show that between the III and II millennium cal BC, an agricultural system based on livestock and cereal farmi…
Stage boundaries, global stratigraphy, and the time scale: towards a simplification
2004
International audience; This paper examines four facets of stratigraphic terminology and usage considered faulty and proposes corrective measures. The four perfectible areas are: (1) The system of dual nomenclature requiring discrete terminologies for the superpositional and temporal aspects of rock units. (2) The premise that a GSSP establishes the base of a stage as being coincident with the top of the preceding stage rather than simply defining it as the boundary between stages. (3) The rejection of supplementary (auxiliary) sections that would broaden the knowledge of a GSSP and enlarge the area in which it is easily usable. (4) The current dual system of nomenclature for Precambrian an…