Search results for " fiber"
showing 10 items of 1776 documents
Addition of Secondary Amines to α,β-Unsaturated Carbonyl Compounds and Nitriles by Using Microstructured Reactors
2006
Several additions of amines to a,ß-unsaturated carbonyl compounds (Michael additions) were performed in a continuous-flow microstructured reactor rig and compared to the respective batch reaction. Dimethylamine/diethylamine/piperidine and acrylic acid ethyl ester/acrylonitrile were employed as two sets of reactants, giving six reactions. Some of these reactions are highly exothermal. Using the traditional batch procedure the olefin must be added quite slowly to the diluted amine to ensure temperature control and safe operation; especially this is necessary for the addition of dimethylamine (40 mass % aqueous solution) to acrylonitrile. Good yields (>85%) are achieved in this way; however…
Thermodynamic approach of supercontinuum generation
2009
International audience; This paper is aimed at providing an overview on recent theoretical and experimental works in which a thermodynamic description of the incoherent regime of supercontinuum generation has been formulated. On the basis of the wave turbulence theory, we show that this highly nonlinear and quasi-continuous-wave regime of supercontinuum generation is characterized by two different phenomena. (i) A process of optical wave thermalization ruled by the four-wave mixing effects: The spectral broadening inherent to supercontinuum generation is shown to result from the natural tendency of the optical field to reach its thermodynamic equilibrium state, i. e., the state of maximum n…
Spatial soliton formation in photonic crystal fibers
2003
We demonstrate the existence of spatial soliton solutions in photonic crystal fibers (PCF's). These guided localized nonlinear waves appear as a result of the balance between the linear and nonlinear diffraction properties of the inhomogeneous photonic crystal cladding. The spatial soliton is realized self-consistently as the fundamental mode of the effective fiber defined simultaneously by the PCF linear and the self-induced nonlinear refractive indices. It is also shown that the photonic crystal cladding is able to stabilize these solutions, which would be unstable otherwise if the medium was entirely homogeneous.
Experimental observation of temporal dispersion gratings in fiber optics
2017
We experimentally demonstrate a temporal analog to the diffraction optical grating in the Fraunhofer formalism. Using amplitude and phase temporal periodic modulations, we show that the accumulation of dispersion in fiber optics induces the development of temporally well-separated sidebands similar to the spatial orders of diffraction that are commonly observed in an optical grating operating in the far field.
Mechanical Behavior of Steel Fiber-Reinforced Concrete Beams Bonded with External Carbon Fiber Sheets
2017
This study investigates the mechanical behavior of steel fiber-reinforced concrete (SFRC) beams internally reinforced with steel bars and externally bonded with carbon fiber-reinforced polymer (CFRP) sheets fixed by adhesive and hybrid jointing techniques. In particular, attention is paid to the load resistance and failure modes of composite beams. The steel fibers were used to avoiding the rip-off failure of the concrete cover. The CFRP sheets were fixed to the concrete surface by epoxy adhesive as well as combined with various configurations of small-diameter steel pins for mechanical fastening to form a hybrid connection. Such hybrid jointing techniques were found to be particularly adva…
Experimental assessment of the shield-to-salt-fog properties of basalt and glass fiber reinforced composites in cork core sandwich panels applications
2018
Abstract In this paper, the effect of salt-fog exposition on the mechanical behavior of sandwich panels having cork agglomerate core was investigated. In particular, the aim of this research work is to assess the shield function of unidirectional basalt and E-glass reinforced polymer on the aging and failure mechanism of the core when such class of material are destined to operate in hostile environments (e.g., marine environment). To do this, the manufactured sandwich panels were exposed up to 60 days to salt-fog environment, according to ASTM B 117 standard. Unaged and aged specimens were analyzed through three point bending tests after aging time of 10, 25 and 60 days. Digital Image Corr…
A Next‐Generation Air‐Stable Palladium(I) Dimer Enables Olefin Migration and Selective C−C Coupling in Air
2020
Abstract We report a new air‐stable PdI dimer, [Pd(μ‐I)(PCy2 tBu)]2, which triggers E‐selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C−C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C−Br, C−OTf/OFs, and C−Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C−OTf.
Single-frequency active Q-switched Distributed Fiber Laser Using Acoustic Waves
2007
This letter presents a single mode, actively Q-switched distributed feedback fiber laser. Acoustic pulses are launched into an erbium-doped fiber Bragg grating, resulting in the introduction of a traveling defect. Thus, a transmission peak appears in the reflection band while the pulse travels along the grating. This effect allows the laser to operate in a Q-switched regime, providing optical pulses which repetition rate was continuously tuned up to 10 kHz. Pulses of 168 mW of peak power and 73 ns of temporal width were obtained at low repetition rate.
Polarization switchable Erbium-doped all-fiber laser
2008
We report an experimental study of an erbium-doped all-fiber laser with electrically switchable output polarization. Fiber Bragg grating written in a polarization maintaining optical fiber and attached to a piezo-ceramic actuator is used to commute the polarization state of the laser emission. The laser oscillates at one of two orthogonal polarizations depending on voltage applied to the actuator.
Tunable dual-wavelength thulium-doped fiber laser in the range from 2067 to 2073.5 nm
2017
A tunable dual-wavelength lineal cavity Tm-doped fiber laser is presented. The generation of the laser lines is based on the use of cascaded fiber Bragg gratings and a Hi-Bi fiber optic loop mirror.