Search results for " fuel cell."
showing 10 items of 166 documents
X-ray Spectroscopy of (Ba,Sr,La)(Fe,Zn,Y)O3-δIdentifies Structural and Electronic Features Favoring Proton Uptake
2020
Mixed protonic–electronic conducting oxides are key functional materials for protonic ceramic fuel cells. Here, (Ba,Sr,La)(Fe,Zn,Y)O3−δ perovskites are comprehensively investigated by X-ray spectroscopy (in oxidized and reduced states). Extended X-ray absorption fine structure shows that Zn,Y doping strongly increases the tendency for Fe–O–Fe buckling. X-ray absorption near-edge spectroscopy at the Fe K-edge and X-ray Raman scattering at the O K edge demonstrate that both iron and oxygen states are involved when the samples are oxidized, and for the Zn,Y doped materials, the hole transfer from iron to oxygen is less pronounced. This can be correlated with the observation that these material…
Flash microwave synthesis and sintering of nanosized La0.75Sr0.25Cr0.93Ru0.07o3–δ for fuel cell application.
2009
International audience; Perovskite-oxide nanocrystals of La0.75Sr0.25Cr0.93Ru0.07O3–δ with a mean size around 10 nm were prepared by microwave flash synthesis. This reaction was performed in alcoholic solution using metallic salts, sodium ethoxide and microwave autoclave. The obtained powder was characterised after purification by energy dispersive X-ray analysis (EDX), X-ray powder diffraction (XRD), BET adsorption technique, photon correlation spectroscopy (PCS) and transmission electron microscopy (TEM). The results show that integrated perovskite-type phase and uniform particle size were obtained in the microwave treated samples. At last the synthesised powder was directly used in a sin…
Development of anode supported Single Chamber Solid Oxide Fuel Cells running in air/methane mixture
2013
International audience; Single Chamber Solid Oxide Fuel Cells (SCFC) show a growing interest and are the concern of more and more papers. In such device, anode and cathode are ex-posed to a gas mixture of fuel (hydrocarbon) and oxidant (air) so that no more sealing with electrolyte is necessary. Their operating principle is based on the different catalytic activities of anode and cathode: Ideally, the anode has to be active for the oxidation of fuel while the cathode should present only a strong electro-activity for oxygen reduction. In this paper, we present the development of an anode supported SCFC device running in air/methane mixture characterized by their volume ratio, Rmix = CH4/O2.
Design and Modeling of an Interleaving Boost Converter with Quasi-Saturated Inductors for Electric Vehicles
2020
This paper is focused on the analysis and modeling of DC-DC boost converters in interleaving configuration exploiting inductors in the quasi-saturation region. The converter is designed to optimize the power density by minimizing the size of the inductors. A simulation study for electric vehicle applications is conducted analyzing the effects of duty cycle and temperature variation on the ripple of the input current giving, moreover, information on the performances and dynamics of the converter for further implementation and optimizations.
Microbial Fuel Cell with Ni–Co Cathode Powered with Yeast Wastewater
2018
Wastewater originating from the yeast industry is characterized by high concentration of pollutants that need to be reduced before the sludge can be applied, for instance, for fertilization of croplands. As a result of the special requirements associated with the characteristics of this production, huge amounts of wastewater are generated. A microbial fuel cell (MFC) forms a device that can apply wastewater as a fuel. MFC is capable of performing two functions at the same time: wastewater treatment and electricity production. The function of MFC is the production of electricity during bacterial digestion (wastewater treatment). This paper analyzes the possibility of applying yeast wastewate…
Solid-state compatibility of Ca:LaNbO4 with perovskite cathodes: Evidences from X-ray microspectroscopy
2022
The solid-state compatibility between calcium-doped lanthanum niobate and three perovskite cathode materials was investigated using two X-ray microbeam techniques, micro X-ray fluorescence and micro X-ray absorption spectroscopy. The cathode powders (lanthanum strontium ferrite, either cobalt or copper-doped, and lanthanum strontium cobaltite) in contact with the dense electrolyte pellet were annealed at 1150 degrees C for 12-144 h to simulate the effect of thermal stresses due to fabrication and long-term operation. As a result, several interdiffusion phenomena were then observed on the bilayer cross-sections: in particular, the chemical state and coordination environment of calcium, iron,…
Cu-B alloy - analysis of use possibility as fuel cell cathode catalyst
2016
In recent years there has been a development of non-conventional and renewable sources of energy. One such sources of energy are fuel cells. Fuel cells are ecological and high efficiency sources of electric energy. However, the use of fuel cells on a large scale is limited, mainly by the high cost of catalysts. Platinum is most commonly used as the catalyst. But due to the high price of platinum there’s a need for finding other catalysts. Replacement of platinum will contribute to the fast development of green energy sources. This paper presents a study of possibility of using Cu-B alloy as catalyst for oxygen electrode in fuel cells. Researches were done in glass vessel, on a copper electr…
MICROBIAL FUEL CELL WITH Cu-B CATHODE POWERING WITH WASTEWATER FROM YEAST PRODUCTION
2017
With the increasing standard of living, energy consumption increases as well. So, waste production, including wastewater, increases as well. One of the types of waste-water is wastewater from yeast industry. Wastewater from this industry has not only a high pollutants load but it is produced in great amounts as well. Technical devices that can accomplish the wastewater treatment and electricity production from wastewater is a microbial fuel cell. In microbial fuel cells activated sludge bacteria can be used for electricity production during wastewater treatment. The possibility of using the Cu-B alloy as cathode catalyst for microbial fuel cells to wastewater treatment of wastewater from ye…
Electricity Production from Yeast Wastewater in Membrane-Less Microbial Fuel Cell with Cu-Ag Cathode
2023
Wastewater has high potential as an energy source. Therefore, it is important to recover even the smallest part of this energy, e.g., in microbial fuel cells (MFCs). The obtained electricity production depends on the process rate of the electrodes. In MFC, the microorganisms are the catalyst, and the cathode is usually made of carbon material (e.g., with the addition of Pt). To increase the MFC efficiency (and reduce costs by reducing use of the noble metals), it is necessary to search the new cathode materials. In this work, the electricity production from yeast wastewater in membrane-less microbial fuel cells with Cu-Ag cathode was analyzed. In the first place, the measurements of the sta…
Microbial fuel cell with Ni-Co cathode
2017
Wraz ze wzrostem poziomu życia wzrasta zarówno zużycie energii, jak i ilość ścieków. Istnieje jednak możliwość produkcji energii z jednoczesnym oczyszczaniem ścieków. Urządzeniem, które może zrealizować to zadanie jest mikrobiologiczne ogniwo paliwowe. W ogniwach tego typu bakterie osadu czynnego wykorzystane są do produkcji energii podczas oczyszczania ścieków. Jednym z ograniczeń tego rozwiązania jest niska gęstość uzyskiwanego prądu. Możliwe jest jednak podwyższenie tego parametru przy wykorzystaniu odpowiedniego katalizatora elektrod. W artykule przedstawiono możliwość wykorzystania stopu Ni-Co jako katalizatora katody. Badania obejmowały przygotowanie elektrody oraz porównanie zmian st…