Search results for " function"
showing 10 items of 9395 documents
Transverse resolution improvement using rotating-grating time-multiplexing approach
2008
The ability to improve the limited resolving power of optical imaging systems while approaching the theoretical diffraction limit has been an attractive discipline with growing interest over the last years due to its benefits in many applied optics systems. This paper presents a new approach to achieve transverse superresolution in far-field imaging systems, with direct application in both digital microscopy and digital holographic microscopy. Theoretical analysis and computer simulations show the validity of the presented approach.
Instantaneous distribution of global and diffuse radiation on horizontal surfaces
1991
Abstract The aim of this paper is to obtain a general expression for estimating both the instantaneous global and diffuse radiations on horizontal surfaces from the respective daily values. The proposed expression is a modified Gaussian distribution with two parameters which take into account its width and the asymmetries between morning and afternoon hours. The performance of the method has been tested by comparing the theoretical hourly results with the experimental data of six actinometric stations with different geographical location and climatic conditions. The comparison has shown that the method here proposed is accurate for both the diffuse and global radiation.
Functional A Posteriori Error Estimate for a Nonsymmetric Stationary Diffusion Problem
2015
In this paper, a posteriori error estimates of functional type for a stationary diffusion problem with nonsymmetric coefficients are derived. The estimate is guaranteed and does not depend on any particular numerical method. An algorithm for the global minimization of the error estimate with respect to an auxiliary function over some finite dimensional subspace is presented. In numerical tests, global minimization is done over the subspace generated by Raviart-Thomas elements. The improvement of the error bound due to the p-refinement of these spaces is investigated.
Density Functional Theory Investigation on the Nucleation of Homo- and Heteronuclear Metal Clusters on Defective Graphene
2016
Nucleation of homo- (Ni, Pd, Re, Pt) and heterometallic (Ni–Pd, Re–Pt) clusters on monovacancy sites of a graphene sheet has been investigated by means of periodic density functional theory calculations. It is shown that a vacant site in graphene is an effective nucleation center for both the monometallic and bimetallic clusters, whose characteristics are described in terms of structural distortions, nucleation energetics, affinities between different metal atoms, metal–carbon interactions, and ease of diffusion of metal atoms on graphene.
Implementation of pattern recognition algorithm based on RBF neural network
2002
In this paper, we present implementations of a pattern recognition algorithm which uses a RBF (Radial Basis Function) neural network. Our aim is to elaborate a quite efficient system which realizes real time faces tracking and identity verification in natural video sequences. Hardware implementations have been realized on an embedded system developed by our laboratory. This system is based on a DSP (Digital Signal Processor) TMS320C6x. The optimization of implementations allow us to obtain a processing speed of 4.8 images (240x320 pixels) per second with a correct rate of 95% of faces tracking and identity verification.
Electrochemical synthesis of 2-arylimino-4,5-di(2-furyl)-1,3-dioxoles and (E)-1,2-di(2-furyl)vinylene bis(N-arylchloroformimidates). HF and B3LYP com…
2009
Abstract Cathodic reductions of 2,2′-furils in the presence of N-arylcarbonimidoyl dichlorides lead to 2-arylimino-4,5-di(2-furyl)-1,3-dioxoles in high yields, along with minor amounts of (E)-1,2-di(2-furyl)vinylene bis(N-arylchloroformimidates). HF and B3LYP density functional theory methods have been applied to the determination of molecular geometries and to study the topomerization mechanism of aryliminodioxoles. The molecular structure of (E)-1,2-di(2-furyl)vinylene bis[N-(2-chloro-4-methylphenyl)chloroformimidate] has been determined by X-ray crystallography and compared with the calculated structure.
Comments on “Mean velocity and turbulent characteristics of flow over half-cycle cosine sharp-crested weirs” by Salehi S., Esmaili K., Azimi A.H.
2019
Abstract In this paper the stage-discharge equation of a half-cycle cosine weir is theoretically deduced applying the Π-Theorem of dimensional analysis and the self-similarity theory. The coefficients of the new stage-discharge relationships are estimated using the results of the experimental runs by Salehi et al..
Stereoselective 1,3-Dipolar Cycloadditions of a Chiral Nitrone Derived from Erythrulose. An Experimental and DFT Theoretical Study
2000
We have investigated several 1,3-dipolar cycloadditions of a chiral nitrone prepared from L-erythrulose. While cycloadditions to carbon-carbon multiple bonds of dipolarophiles such as ethyl acrylate, ethyl propiolate, or dimethyl acetylenedicarboxylate were poorly stereoselective, reaction with acrylonitrile provided predominantly one diastereomeric adduct. Furthermore, the regioselectivity exhibited by the two structurally similar dipolarophiles ethyl acrylate and ethyl propiolate was found to be opposite. The molecular mechanisms of these cycloadditions have thus been investigated by means of density functional theory (DFT) methods with the B3LYP functional and the 6-31G and 6-31+G basis …
Antiferromagnetic Interactions in Copper(II) µ-Oxalato Dinuclear Complexes: The Role of the Counterion
2018
We report the preparation, crystal structure determination, magnetic properties and DFT calculations of five oxalato-bridged dicopper(II) complexes of formula [Cu-2(bpy)(2-)(H2O)(2)(C2O4)](CF3SO3)(2) (1), [Cu-2(bpy)(2)(C2O4)](PF6)(2) (2), [Cu-2(bpy)(2)(C2O4)](ClO4)(2) (3), [Cu-2(bpy)(2)Cl-2(C2O4)]center dot H2O (4) and [Cu-2(bpy)(2)(NO2)(2)(C2O4)] (5) (bpy = 2,2'-bipyridine and C2O42-= oxalate). Compounds 1, 2, 4 and 5 crystallize in the monoclinic system and 3 crystallizes in the triclinic system. The oxalate ligands in 1-5 adopt the bis-bidentate coordination mode and the two bpy molecules act as terminal ligands. The coordination of the counterions and the surroundings of the copper(II) …
A theoretical study on the regioselectivity of 1,3-dipolar cycloadditions using dft-based reactivity indexes
2004
The regioselectivity for a series of four 1,3-dipolar cycloaddition reactions has been studied using global and local reactivity indexes. The results of the theoretical analysis suggest that for asynchronous cycloadditions associated to polar processes, the regioselectivity is consistently explained by the most favorable two-center interactions between the highest nucleophilic and electrophilic sites of the reagents.