Search results for " function"

showing 10 items of 9395 documents

Play assessment for group settings : validating a measurement tool for assessment of children's play performance in the day-care context

2012

leikkiinstrument developmentarviointimenetelmätinternal scale validitytest-retest reliabilityplay performancespecific language impairment (SLI)päivähoitoleikitperson response validityinter-rater reliabilitykielellinen kehitysdifferential item function (DIF)kielen kehityksen erityisvaikeusplay assessment for group settings (PAGS)lapset
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Linguistic diversity and assessment in multilingual schools

2018

En un entorno en el que la diversidad lingüística es natural, la metodología de evaluación afronta nuevos retos. La equidad en el proceso evaluativo aconseja la consideración de aspectos relacionados con las características psicométricas de las pruebas, el desarrollo de la competencia lingüística, o el contexto sociolingüístico, a través de modelos explicativos sobre las variables contextuales de naturaleza lingüística que inciden en el rendimiento. Utilizando datos poblacionales de centros educativos de segundo curso de enseñanza secundaria obligatoria que ofertan más de un modelo lingüístico en la Comunidad Autónoma del País Vasco (N=45), este trabajo analiza las respuestas de 2783 estudi…

lengua oficial060201 languages & linguisticsLinguistic contextSecondary educationsistema educativoLinguistic diversityLinear model06 humanities and the artsevaluaciónDifferential item functioningmatemáticaslengua vascaEducationLinguistic competencemultilingüismolengua materna0602 languages and literatureMathematics educationPopulation data:PEDAGOGÍA [UNESCO]lengua españolarendimientoUNESCO::PEDAGOGÍACompetence (human resources)RELIEVE - Revista Electrónica de Investigación y Evaluación Educativa
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Prompt and delayed spectroscopy of 203At : Observation of a shears band and a 29/2+ isomeric state

2018

Using fusion-evaporation reactions, a gas-filled recoil separator, recoil-gating technique and recoil-isomer decay tagging technique we have extended the level scheme of 203 At ( N = 118 ) significantly. We have observed an isomeric [ τ = 14.1 ( 3 ) μ s ] state with a spin and parity of 29 / 2 + . The isomeric state is suggested to originate from the π ( h 9 / 2 ) ⊗ ∣ ∣ 202 Po ; 11 − ⟩ coupling, and it is depopulated through 286 keV E 2 and 366 keV E 3 transitions. In addition, we have observed a cascade of magnetic-dipole transitions which is suggested to be generated by the shears mechanism. peerReviewed

level densitiesnuclear spinelectromagnetic transitionsnuclear density functional theorytiheysfunktionaaliteoriaspektroskopialifetimeswidthsenergy levelsNuclear Experimentisomer decaysydinfysiikkanuclear parity
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Del álgebra a la geometría : la sistematización de las coordenadas cartesianas y la representación gráfica de funciones en la Introductio in analysin…

2012

Este trabajo de investigación explora la presentación del sistema de coordenadas cartesianas en la Introductio in Analysin Infinitorum de Euler y en los libros de texto de Lacroix Traité du calcul différentiel et du calcul intégral and Traité Élémentaire de Trigonométrie Rectiligne et Sphérique, et d’Application de l’Algèbre a la Géométrie, indagando qué componentes hicieron posible su sistematización, y teniendo presente las dificultades de los estudiantes en el uso de las coordenadas cartesianas. Es un hecho harto conocido que los estudiantes tienen dificultades en la comprensión y el uso de la representación de funciones en el sistema de coordenadas cartesianas (SCC). Esta problemática d…

libros de textocurves drawingUNESCO::HISTORIA::Historia por especialidades::Historia de la educaciónLacroixgraphical representation of functionstrazado de curvasEulerUNESCO::MATEMÁTICAS::Análisis y análisis funcional::Otrascoordenadas cartesianasUNESCO::MATEMÁTICAS::Otras especialidades matemáticastextbooksrepresentación gráfica de funcionescartesian coordinatesUNESCO::MATEMÁTICAS::Álgebra::Otras
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Palladium-Catalyzed Direct Arylation of Heteroaromatics with Activated Aryl Chlorides Using a Sterically Relieved Ferrocenyl-Diphosphane

2012

International audience; The palladium-catalyzed direct arylations at C3 or C4 positions of heteroaromatics are known to be more challenging than at C2 or C5 positions. Aryl chlorides are also challenging substrates for direct arylation of heteroaromatics. We observed that in the presence of a palladium-catalyst combining only 0.5 mol % of Pd(OAc)2 with the sterically relieved new ferrocenyl diphosphane Sylphos, the direct arylation at C3 or C4 of oxazoles, a benzofuran, an indole, and a pyrazole was found to proceed in moderate to high yields using a variety of electron deficient aryl chlorides. Turnover numbers up to 176 have been obtained with this catalyst. Assessment of the electron-don…

ligand designSteric effectsC−H bond functionalizationaryl chlorideschemistry.chemical_elementPyrazole010402 general chemistry01 natural sciencesMedicinal chemistryCatalysis[ CHIM.CATA ] Chemical Sciences/Catalysischemistry.chemical_compoundOrganic chemistryDiphosphaneMethyleneBenzofuranIndole test010405 organic chemistryArylferrocenylphosphaneheteroarenes[CHIM.CATA]Chemical Sciences/CatalysisGeneral Chemistrypalladium0104 chemical scienceschemistry13. Climate actionPalladiumACS Catalysis
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Computational Criteria for Hydrogen Evolution Activity on Ligand-Protected Au25-Based Nanoclusters

2023

The hydrogen evolution reaction (HER) is a critical reaction in addressing climate change; however, it requires catalysts to be generated on an industrial scale. Nanomaterials offer several advantages over conventional HER catalysts, including the possibility of atomic precision in tailoring the intrinsic activity. Ligand-protected metal clusters, such as the thiolate-protected MAu24(SR)18 (where M is Au, Cu, Pd), are of particular interest as not only are they electrocatalytically active toward HER, but the charge state and composition can be precisely tuned. Here, we present a comprehensive computational study examining how the charge state and dopants affect the catalytic activity of [MA…

ligand protected clusterelektrokatalyysinanorakenteetgold nanoclustertiheysfunktionaaliteoriaelectrocatalysisHERdopingdensity functional theoryredox potential
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Extracellular Vesicles as Biological Shuttles for Targeted Therapies.

2019

The development of effective nanosystems for drug delivery represents a key challenge for the improvement of most current anticancer therapies. Recent progress in the understanding of structure and function of extracellular vesicles (EVs)—specialized membrane-bound nanocarriers for intercellular communication—suggests that they might also serve as optimal delivery systems of therapeutics. In addition to carrying proteins, lipids, DNA and different forms of RNAs, EVs can be engineered to deliver specific bioactive molecules to target cells. Exploitation of their molecular composition and physical properties, together with improvement in bio-techniques to modify their content are critical iss…

liposomesMolecular compositionBioactive moleculesReviewExtracellular vesiclesCatalysislcsh:ChemistryInorganic Chemistry03 medical and health sciencesExtracellular Vesicles0302 clinical medicineDrug Delivery SystemsPlant-derived extracellular vesicleAnimalsHumanstarget therapiesTarget therapyPhysical and Theoretical ChemistryRNA Small Interferinglcsh:QH301-705.5Molecular BiologySpectroscopy030304 developmental biology0303 health sciencesDrug CarriersChemistryOrganic ChemistryGeneral MedicinePlantsComputer Science ApplicationsStructure and functionCell biologyLiposomeplant-derived extracellular vesicleslcsh:Biology (General)lcsh:QD1-999Pharmaceutical Preparations030220 oncology & carcinogenesisDrug deliverydrug deliveryExtracellular vesicleNanocarriersDrug carrierInternational journal of molecular sciences
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Ledrappier-Young formula and exact dimensionality of self-affine measures

2017

In this paper, we solve the long standing open problem on exact dimensionality of self-affine measures on the plane. We show that every self-affine measure on the plane is exact dimensional regardless of the choice of the defining iterated function system. In higher dimensions, under certain assumptions, we prove that self-affine and quasi self-affine measures are exact dimensional. In both cases, the measures satisfy the Ledrappier-Young formula. peerReviewed

local dimensionPlane (geometry)General MathematicsOpen problem010102 general mathematicsMathematical analysista111Dynamical Systems (math.DS)01 natural sciencesMeasure (mathematics)self-affine set010101 applied mathematicsIterated function systemself-affine measureHausdorff dimension37C45 28A80FOS: MathematicsApplied mathematicsAffine transformation0101 mathematicsMathematics - Dynamical Systemshausdorff dimensionMathematicsCurse of dimensionality
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MR3631681 Reviewed Nigsch, E. A.(A-WIENM) On a nonlinear Peetre's theorem in full Colombeau algebras. (English summary) Comment. Math. Univ. Carolin.…

2017

Colombeau algebras are defined as quotients of spaces containing the representatives of generalized functions given by smooth mappings: R:C∞(Ω,D(Ω))→C∞(Ω), where Ω is an open subset of Rn. In this paper the notion of locality defined by the author for a representative R of a nonlinear generalized function is characterized in such a way that the representative depends only on its ∞-jet. Finally, the author examines the possibility of defining a notion of order for the mapping R.

local functionColombeau algebraSettore MAT/05 - Analisi Matematicanonlinear Peetre's theorem
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Existence and classification of critical points for nondifferentiable functions

2004

A general min-max principle established by Ghoussoub is extended to the case of functionals which are the sum of a locally Lipschitz continuous term and of a convex, proper, lower semicontinuous function. Some topological properties of the min-max-generated critical points in such a framework are then pointed out.

locally Lipschitz continus functionlower semicontinuous functionApplied Mathematicsconvexcritical pointAnalysipropercritical point; locally Lipschitz continus function; convex proper lower semicontinuous function49J3558E05Analysis47J30
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