Search results for " gases"

The role of melt composition on aqueous fluid vs. silicate melt partitioning of bromine in magmas

2018

International audience; Volcanogenic halogens, in particular bromine, potentially play an important role in the ozone depletion of the atmosphere. Understanding bromine behaviour in magmas is therefore crucial to properly evaluate the contribution of volcanic eruptions to atmospheric chemistry and their environmental impact. To date, bromine partitioning between silicate melts and the gas phase is very poorly constrained, with the only relevant experimental studies limited to investigation of synthetic melt with silicic compositions. In this study, fluid/melt partitioning experiments were performed using natural silicate glasses with mafic, intermediate and silicic compositions. For each co…

UCT-MBR vs IFAS-UCT-MBR for Wastewater Treatment: A Comprehensive Comparison Including N2O Emission

2017

In this study the performance (in terms of carbon and nutrient removal) and N2O emission of two plant configurations adopting innovative technologies were investigated. With this regards, an University Cape Town (UCT) membrane bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS) -UCT-MBR plant were monitored. Both plants treat real wastewater under two different values of the influent carbon nitrogen ratio (C/N = 5 mgCOD/mgN and C/N = 10 mgCOD/mgN). Results have shown the highest carbon and nutrients removal efficiencies for the IFAS-UCT-MBR configuration during both the two investigated C/N values. Furthermore, the lowest N2O emission occurred for the IFAS-UCT-MBR.

A globally relevant stock of soil nitrogen in the Yedoma permafrost domain

2022

AbstractNitrogen regulates multiple aspects of the permafrost climate feedback, including plant growth, organic matter decomposition, and the production of the potent greenhouse gas nitrous oxide. Despite its importance, current estimates of permafrost nitrogen are highly uncertain. Here, we compiled a dataset of >2000 samples to quantify nitrogen stocks in the Yedoma domain, a region with organic-rich permafrost that contains ~25% of all permafrost carbon. We estimate that the Yedoma domain contains 41.2 gigatons of nitrogen down to ~20 metre for the deepest unit, which increases the previous estimate for the entire permafrost zone by ~46%. Approximately 90% of this nitrogen (37 gigaton…

Multiple origins of methane in fluids circulating in the Othrys ophiolite, central Greece

2018

The complex geology of Greece includes two important parallel running ophiolitic belts. The Othrys Massif in central Greece belongs to westernmost of them. In and around this wide ophiolite outcrop, some cold hyperalkaline and some hypothermal (T < 40°C) alkaline springs are present. Thirty water samples were collected at 17 different sites and both bubbling and dissolved gases were analysed for their chemical (He, Ne, H2, O2, N2, CH4, C2H6, CO2 and H2S) and isotope (He, δ13C-CO2, δ 13C-CH4, δ 2H-CH4) composition. All samples except one have H2S contents below detection limit (10 μmol/mol), whilst H2 (from <2 to 2500 μmol/mol), CO2 (up to 26,000 but generally below 1000 μmol/mol) and …

Influencia de la fermentación colónica en los esteroles de la dieta

2018

La adición de esteroles vegetales (EV) está permitida a varios alimentos por su efecto hipocolesterolemiante, con el fin de “mantener normales los niveles de colesterol sanguíneo” y “prevención de patologías cardiovasculares”. Los EV presentan una baja absorción (2-3%), mientras que los del colesterol oscilan entre el 30 y el 60%. Los esteroles no absorbidos llegan al colon y son transformados por la microbiota. Es conocida la biotransformación microbiana del colesterol a coprostanol y en menor medida a coprostanona y colestanol. Los EV también son metabolizados por la microbiota a fitostanonas, fitostenonas y fitostanoles. El objetivo de la presente tesis doctoral es evaluar la influencia …

Laboratorio de química física II: presentación, guiones y medidas de seguridad en inglés

2020

El document forma part dels materials docents programats mitjançant l'ajut del Servei de Política Lingüística de la Universitat de València. En esta aportación se muestra el material necesario para llevar a cabo la asignatura de laboratorio de química física II (grado en químicas) en inglés. En este sentido, se aporta: 1) Una presentación de la asignatura, con los objetivos generales de la asignatura, así como el funcionamiento interno del laboratorio y el trabajo a desarrolar por el estudiante. 2) Las medidas de seguridad propias que se han de seguir en cada sesión práctica de laboratorio y 3) Guiones de las prácticas que se realizan en este laboratorio. Todo el material aportado en este d…

2017

Abstract. Remote sensing of the gaseous composition of non-eruptive, passively degassing volcanic plumes can be a tool to gain insight into volcano interior processes. Here, we report on a field study in September 2015 that demonstrates the feasibility of remotely measuring the volcanic enhancements of carbon dioxide (CO2), hydrogen fluoride (HF), hydrogen chloride (HCl), sulfur dioxide (SO2), and bromine monoxide (BrO) in the downwind plume of Mt. Etna using portable and rugged spectroscopic instrumentation. To this end, we operated the Fourier transform spectrometer EM27/SUN for the shortwave-infrared (SWIR) spectral range together with a co-mounted UV spectrometer on a mobile platform in…

A multi-purpose, multi-rotor drone system for long-range and high-altitude volcanic gas plume measurements

2021

A multi-rotor drone has been adapted for studies of volcanic gas plumes. This adaptation includes improved capacity for high-altitude and long-range, real-time SO2 concentration monitoring, long-range manual control, remotely activated bag sampling and plume speed measurement capability. The drone is capable of acting as a stable platform for various instrument configurations, including multi-component gas analysis system (MultiGAS) instruments for in situ measurements of SO2, H2S, and CO2 concentrations in the gas plume and portable differential optical absorption spectrometer (MobileDOAS) instruments for spectroscopic measurement of total SO2 emission rate, remotely controlled gas samplin…

Unrest at the Nevados de Chillán volcanic complex: a failed or yet to unfold magmatic eruption?

2018

Resuming erupting activity at volcanoes that have been long quiescent poses a significant challenge to hazard assessment, as it require assessment of whether the change in activity is an isolated event or the beginning of a new eruptive sequence. Such inception is often poorly characterised as quiescent volcanoes tend to be poorly equipped and not extensively monitored, especially with respect to gas geochemistry. Here, we report gas composition and flux measurements from a newly opened vent at the very onset of eruptive activity at the Nevados de Chillán volcanic complex (Chile) in January-February 2016. The molar proportions of H2O, CO2, SO2, H2S and H2 gases are found to be 98.4, 0.97, 0…

Degassing of halogens from basaltic volcanism: Insights from volcanic gas observations

2009

Abstract The currently available data set of S–Cl–F abundances in volcanic gas plumes and high-temperature fumarolic gas samples from basaltic volcanism is reviewed here in the attempt to derive constraints on the modes of halogen degassing from mafic silicate melts. Apart from large volcano-to-volcano variations, reflecting remarkable differences in volatile abundances in the source magmas, each of the explored volcanoes displays large changes of SO2/HCl and SO2/HF ratios with the style of volcanic activity, with HCl/HF staying fairly constant. Halogen abundances are low and SO2/HCl and SO2/HF are high when fresh (volatile-rich) magmas sustain degassing, as during explosive eruptions, at t…