Search results for " geometry"
showing 10 items of 2294 documents
Mononuclear and tetranuclear Fe(III) complexes with two different types of N, O donor Schiff base ligands
2013
Abstract A mononuclear Fe(III) complex of a tetradentate N 2 O 2 donor Schiff base ligand derived from 3-ethoxysalicaldehyde and ethylenediamine has been reported. In addition two tetranuclear Fe(III) complexes with discrete Fe 4 III (μ 4 -O) cores have been synthesized and characterized using two Schiff base ligands (H 2 L 1–2 ) derived from two different aromatic acid hydrazides and diacetyl monoxime. The mononuclear Fe(III) and one of the tetranuclear Fe(III) complexes have been structurally characterized by single-crystal X-ray crystallography. The mononuclear complex has a highly distorted octahedral geometry. The tetranuclear Fe(III) complexes are found to be rare examples with discre…
Mössbauer relaxation spectra in arbitrarily ordered absorbers—Line shape analysis for an iron(II) spincrossover complex in the presence of texture
1989
The stochastic theory of Mossbauer line shapes is formulated in a fashion which allows the evaluation of the spectral shapes for absorbers of arbitrary thickness, texture, and an anisotropic Lamb—Mossbauer factor. The results are specialized to a two-state-relaxation model of fluctuating electric hyperfine interaction in the case of an absorber of axially symmetric texture. The formalism is applied to the line shape analysis of Mossbauer spectra of a textured sample of the spin-crossover complex [Fe(mtz)6] (PF6)2 (mtz=1-methyltetrazole). It is found that between 185 and 240 K the rate constants for the HS→LS conversion are temperature independent, whereas an Arrhenius behaviour is found for…
Dynamics of spin state conversion processes in the solid state
1989
High spin (HS) ⇌ low spin (LS) conversions in transition metal complexes are nonradiative transitions between spin states. In this contribution, we present a study of the temperature and pressure dependence of the HS ⇌ LS intersystem crossing dynamics. For some iron(II) spin-crossover complexes, the rate constants were determined by line shape analysis of57Fe Mossbauer spectra. Their temperature dependence is described by an Arrhenius equation, their pressure dependence is interpreted within absolute rate theory. HS → LS conversion rates at low temperatures were determined from the relaxation of light-induced formation of HS states, monitored by optical spectroscopy. Deviations from a simpl…
Optimal Guard Placement Problem Under L-Visibility
2006
Two points a and b in the presence of polygonal obstacles are L-visible if the length of the shortest path avoiding obstacles is no more than L. For a given convex polygon Q, Gewali et al [4]. addressed the guard placement problem on the exterior boundary that will cover the maximum area exterior to the polygon under L-visibility. They proposed a linear time algorithm for some given value of L. When the length L is greater than half of the perimeter, they declared that problem as open. Here we address that open problem and present an algorithm whose time complexity is linear in number of vertices of the polygon.
Diffeomorphisms, Noether charges, and the canonical formalism in two-dimensional dilaton gravity
1995
We carry out a parallel study of the covariant phase space and the conservation laws of local symmetries in two-dimensional dilaton gravity. Our analysis is based on the fact that the Lagrangian can be brought to a form that vanishes on-shell giving rise to a well-defined covariant potential for the symplectic current. We explicitly compute the symplectic structure and its potential and show that the requirement to be finite and independent of the Cauchy surface restricts the asymptotic symmetries.
The stratified two-sided jet of Cygnus A. Acceleration and collimation
2015
High-resolution Very-Long-Baseline Interferometry observations of relativistic jets are essential to constrain fundamental parameters of jet formation models. At a distance of 249 Mpc, Cygnus A is a unique target for such studies, being the only Fanaroff-Riley Class II radio galaxy for which a detailed sub-parsec scale imaging of the base of both jet and counter-jet can be obtained. Observing at millimeter wavelengths unveils those regions which appear self-absorbed at longer wavelengths and enables an extremely sharp view towards the nucleus to be obtained. We performed 7 mm Global VLBI observations, achieving ultra-high resolution imaging on scales down to 90 $\mu$as. This resolution corr…
Regularization of spherical and axisymmetric evolution codes in numerical relativity
2007
Several interesting astrophysical phenomena are symmetric with respect to the rotation axis, like the head-on collision of compact bodies, the collapse and/or accretion of fields with a large variety of geometries, or some forms of gravitational waves. Most current numerical relativity codes, however, can not take advantage of these symmetries due to the fact that singularities in the adapted coordinates, either at the origin or at the axis of symmetry, rapidly cause the simulation to crash. Because of this regularity problem it has become common practice to use full-blown Cartesian three-dimensional codes to simulate axi-symmetric systems. In this work we follow a recent idea idea of Rinne…
"Table 23" of "Energy dependence of event shapes and of alpha(s) at LEP-2."
1999
Distributions of Planarity at cm energies 133, 161 and 172 GeV.
"Table 24" of "Energy dependence of event shapes and of alpha(s) at LEP-2."
1999
Distribution of Planarity at cm energy 183 GeV.
"README and Table of Contents" of "Search for trilepton resonances from chargino and neutralino pair production in $\sqrt{s}$ = 13 TeV $pp$ collision…
2021
This is the HEPData space for the trilepton resonance wino search, the full resolution figures can be found here https://atlas.web.cern.ch/Atlas/GROUPS/PHYSICS/PAPERS/SUSY-2018-36/. The full statistical likelihoods have been provided for this analysis. They can be downloaded by clicking on the purple 'Resources' buttun above where they can then be found in the 'Common Resources' area. A detailed README for how to use the likelihoods is also included in this download. Exclusion contours: Obs. data vs SM bkg. exp. in CRs and VRs $\ell=(e, \mu, \tau)$, Obs_0 $\ell=(e, \mu, \tau)$, Obs_0_Up $\ell=(e, \mu, \tau)$, Obs_0_Down $\ell=(e, \mu, \tau)$, Exp_0 $\ell=(e, \mu, \tau)$, Exp_0_Up $\ell=(e, …