Search results for " glass"
showing 10 items of 409 documents
Evidence for a glassy dynamics in (Rb-NH 4 ) 2 SO 4 mixed compounds
1996
An orientational glass behavior is evidenced in a [Rb0.7(NH4)0.3]2SO4 mixed crystal. Dielectric experiments (1 kHz–250 MHz) performed along the c-axis evidenced a polydispersive relaxation process. Its temperature dependence follows a Vogel-Fulcher law with a freezing temperature of 12 K.
In vitro degradation and bioactivity of composite poly-l-lactic (PLLA)/bioactive glass (BG) scaffolds: comparison of 45S5 and 1393BG compositions
2017
The objective of this study was to compare the effect of two bioglass (BG) compositions 45S5 and 1393 in poly-l-lactic composite scaffolds in terms of morphology, mechanical properties, biodegradation, water uptake and bioactivity. The scaffolds were produced via thermally induced phase separation starting from a ternary polymer solution (polymer/solvent/non-solvent). Furthermore, different BG to polymer ratios have been selected (1, 2.5, 5% wt/wt) to evaluate the effect of the amount of filler on the composite structure. Results show that the addition of 1393BG does not affect the scaffold morphology, whereas the 45S5BG at the highest amount tends to appreciably modify the scaffold archite…
'Cold' crystallization in nanostructurized 80GeSe2-20Ga2Se3 glass
2015
International audience; 'Cold' crystallization in 80GeSe 2-20Ga 2 Se 3 chalcogenide glass nanostructurized due to thermal annealing at 380°C for 10, 25, 50, 80, and 100 h are probed with X-ray diffraction, atomic force, and scanning electron microscopy, as well as positron annihilation spectroscopy performed in positron annihilation lifetime and Doppler broadening of annihilation line modes. It is shown that changes in defect-related component in the fit of experimental positron lifetime spectra for nanocrystallized glasses testify in favor of structural fragmentation of larger free-volume entities into smaller ones. Nanocrystallites of Ga 2 Se 3 and/or GeGa 4 Se 8 phases and prevalent GeSe…
Multifunctional properties of nanocomposites made by 1D and 2D graphene based fillers
2015
High aspect ratio graphene based fillers with different dimensionalities showed the ability to greatly modify rheological, mechanical, thermal and electrical properties of polymers at very low content. In this work, the effect of filler dimensionality on the multifunctional properties of an epoxy matrix reinforced by both carbon nanotubes (1D) and graphite nanoplatelets (2D) have been investigated across the percolation region. Keywords-- Carbon nanotube, Graphite nanoplatelet, nanocomposites, mechanical properties, ...
Chalcogenide Microstructured Fibers for Infrared Systems, Elaboration, Modelization, and Characterization
2009
special issue " Fiber Optic Research in France " (Part III of III); International audience; Chalcogenide fibers present numerous possible applications in the IR field. For many applications, single mode fibers must be obtained. An original way is the realization of microstructured optical fibers (MOFs) with solid core. These fibers present a broad range of optical properties thanks to the high number of freedom degrees of their geometrical structure. In this context, we have developed MOFs for near and mid IR transmission with different geometries and properties such as multimode or endless single-mode operation, small or large mode area fibers. We have also investigated numerically the mai…
Mid-infrared 2000-nm bandwidth supercontinuum generation in suspended-core microstructured Sulfide and Tellurite optical fibers
2012
International audience; In this work, we report the experimental observation of supercontinua generation in two kinds of suspended-core microstructured soft-glass optical fibers. Low loss, highly nonlinear, tellurite and As2S3 chalcogenide fibers have been fabricated and pumped close to their zero-dispersion wavelength in the femtosecond regime by means of an optical parametric oscillator pumped by a Ti:Sapphire laser. When coupled into the fibers, the femtosecond pulses result in 2000-nm bandwidth supercontinua reaching the Mid-Infrared region and extending from 750 nm to 2.8 mu m in tellurite fibers and 1 mu m to 3.2 mu m in chalcogenide fibers, respectively.
Theoretical study of cascade laser in erbium-doped chalcogenide glass fibers
2010
International audience; A theoretical investigation of an innovative cascade laser source is performed. The main goal of the work is the design of a continuous-wave (CW) photonic crystal fiber (PCF) laser, based on an erbium-doped chalcogenide glass. Due to the comparable lifetimes of the 4I13/2, 4I11/2 and 4I9/2 erbium energy levels, the simultaneous emissions at the wavelengths close to 2.7 μm and 4.5 μm are obtained with a pump wavelength close to 806 nm (direct pumping into the level 4I9/2). This scheme could be useful to develop high efficiency, high beam-quality and compact Near-IR and Mid-IR oscillators with single-mode output for applications not only in surgery but also in spectros…
Mid-IR Fibres from Various Soft Glasses for Wide Band Sources
2013
Optical fibres from various soft glasses (tellurite, sulphide…) are designed, drawn and characterized with the purpose of light generation, through non linear effects, on a wide infrared band, targeting a 1-5 µm continuum source.
Gd 3+ -doped sol-gel silica glass for remote ionizing radiation dosimetry
2019
Gadolinium-doped silica glass was prepared, using the sol-gel route, for ionizing radiation dosimetry applications. Such a glassy rod was drawn to a cane at a temperature of 2000 °C. The structural and optical properties of the obtained material were studied using Raman, optical absorption, and photoluminescence spectroscopies. Thereafter, a small piece of this Gd-doped scintillating cane was spliced to a transport passive optical fiber, allowing the remote monitoring of the X-ray dose rate through a radioluminescence (RL) signal. The sample exhibited a linear RL intensity response versus the dose rate from 125 µGy(SiO2)/s up to 12.25 Gy/s. These results confirm the potentialities of this m…
Low temperature afterglow from SrAl 2 O 4 : Eu, Dy, B containing glass
2020
V.V. acknowledges the financial support of ERDF PostDoc project No. 1.1.1.2/VIAA/3/19/440 (University of Latvia Institute of Solid State Physics, Latvia) and LP the Academy of Finland (Flagship Programme, Photonics Research and Innovation PREIN 320165 and Academy Project -326418) for the financial support. Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01- 2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART 2 .