Search results for " glass"

Third-harmonic generation in optical microfibers: From silica experiments to highly nonlinear glass prospects

2012

International audience; Using optical microfibers, phase matching between different propagation modes allows for third-harmonic generation (THG). After detailing the relevant phase matching conditions and overlap integrals, we provide a comparison between THG effective efficiencies in silica and tellurite glasses. We also explain the relatively easy, wideband, conversion that we observe experimentally in silica glass microfibers, from 155 mu m to the green, by the geometry of the tapering region.

Assembly and dichroism of a four-component halogen-bonded metal-organic cocrystal salt solvate involving dicyanoaurate(I) acceptors

2017

We describe the use of dicyanoaurate ions as linear ditopic metal–organic acceptors for the halogen bond-driven assembly of a dichroic metal–organic cocrystal based on azobenzene chromophores. Structural analysis by single crystal X-ray diffraction revealed that the material is a four-component solid, consisting of anticipated anionic metal–organic halogen-bonded chains based on dicyanoaurate ions, as well as complex potassium-based cations and discrete molecules of the crown ether 15-crown-5. Importantly, the structural analysis revealed the parallel alignment of the halogen-bonded chains required for dichroic behaviour, confirming that crystal engineering principles developed for the desi…

The glass transition in (KI)0.5(ND4I)0.5 mixed crystals as studied by deuteron spin-lattice relaxation

1993

Abstract Nuclear spin resonance has been used to study the deuteron magnetization recovery in (KI)0.5(ND4I)0.5 mixed crystals. At high temperatures the spin-lattice-relaxation is exponential. For T ⪅ 45 K deviations from this simple behaviour occur, signalling the onset of spatial inhomogeneities due to the formation of an orientational glass. The results demonstrate that the transition of (KI)0.5(ND4I)0.5 into the glassy state is driven by the freezing of random bonds.

Characterization of a fiber-reinforced new fully aromatic liquid crystalline polymer

1998

A new rigid liquid crystalline polymer that demonstrates good mechanical and thermomechanical properties and acceptable processing temperature has been recently synthesized and characterized. The melting temperature and some thermomechanical properties do not seem, however, suitable for use in some applications at high temperature or in the presence of aggressive fluids. The use of appropriate inorganic fillers can overcome these shortcomings. In this work the new LCP, polymerized in a bench-scale apparatus, and the same sample filled with carbon fibers are characterized. The properties of the carbon fiber filled LCP are compared with those of another filled wholly aromatic commercial LCP,…

Field-cooling experiments on the quadrupolar-glass state of (KBr)0.47(KCN)0.53

1990

The shear strain of a mixed cyanide crystal has been measured under field-cooling conditions. The time decay after field removal follows a Kohlrausch-Williams-Watts law. The results are analogous to spin glasses, except that residual permanent strains can be frozen-in.

Fractional viscoelastic characterization of laminated glass beams under time-varying loading

2021

Abstract Laminated glass is a composite made of elastic glass layers sandwiching thin viscoelastic polymeric interlayers. There are several types of polymers, traditionally modelled as linear viscoelastic materials using a Prony’s series of units in the Maxwell-Wiechert arrangement. We show that one single element with fractional viscoelastic properties (two constitutive parameters that depend on environmental temperature), is sufficient to provide an accurate description of the polymer response under arbitrary time-varying actions. This is a great advantage over the classical viscoelastic characterization, which requires at least 10–15 terms in the Prony’s series, each one characterized by…

Flexural Behavior of Glass Beams with T and I Shape Cross Sections

2017

AbstractGlass beams having T or I cross sections can be obtained as glass panels or laminated glass (LG) panels assembled with polymer adhesives of different types, such as semirigid (silicones, mo...

1984

The synthesis and phase behaviour of azo dye containing liquid crystalline side group copolymers are described. These Copolymers show the same electro-optical effects as low molar mass guest-host systems. Their macroscopic oriented nematic structure can be frozen in below the glass transition temperature resulting in a polymer film with dichroic properties. The behaviour of the copolymers (phase behaviour, surface and electric field orientation) can be improved via mixtures with low molar mass liquid crystals.

Atmospheric aging and surface degradation in As2S3 fibers in relation with suspended-core profile

2015

Abstract Microstructured optical fibers (MOF) can be seen as next generation fiber of significance in advancing the compact optics because of its excellent compatibility in integrated optics. However, the degradation of their physicochemical properties limits their efficiency and lifetime. Atmospheric moisture is responsible for the degradation of amorphous systems especially chalcogenide glasses. In the light of previously reported studies, in order to clarify the aging process continuously evolving in sulfide microstructured optical fiber over time, a detailed investigation of this phenomenon has been conducted. The time-dependent transmission and glass chemical deterioration have been st…

On the handedness of helical aggregates of C3 tricarboxamides: a multichiroptical characterization

2015

A complete chiroptical characterization of the supramolecular polymers formed by tricarboxamides (S)-1 and (R)-1 is performed using ECD, VCD and CPL dichroic techniques. The helical aggregates show an intense CPL signal and their absolute P- or M-configuration is assigned with the help of theoretical calculations.