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showing 10 items of 1277 documents

Dimensional Confinement in Carbon-based Structures - From 3D to 1D

2017

We present an overview of charge transport in selected one-, two- and three-dimensional carbon-based materials with exciting properties. The systems are atomically defined bottom-up synthesized graphene nanoribbons, doped graphene and turbostratic graphene micro-disks, where up to 100 graphene layers are rotationally stacked. For turbostratic graphene we show how this system lends itself to spintronic applications. This follows from the inner graphene layers where charge carriers are protected and thus highly mobile. Doped graphene and graphene nanoribbons offer the possibility to tailor the electronic properties of graphene either by introducing heteroatoms or by confining the system geome…

Materials scienceSpintronicsGrapheneHeteroatomGeneral Physics and Astronomychemistry.chemical_elementNanotechnology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciences7. Clean energy0104 chemical scienceslaw.inventionchemistrylawCharge carrier0210 nano-technologyBilayer grapheneCarbonGraphene nanoribbonsGraphene oxide paperAnnalen der Physik
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Polymorphism of Two-Dimensional Halogen Bonded Supramolecular Networks on a Graphene/Iridium(111) Surface

2017

bibtex: ISI:000393443200020 bibtex\location:'1155 16TH ST, NW, WASHINGTON, DC 20036 USA',publisher:'AMER CHEMICAL SOC',type:'Article',affiliation:'Sicot, M (Reprint Author), Univ Lorraine, CNRS, Inst Jean Lamour, UMR 7198, BP 70239, F-54506 Vandoeuvre Les Nancy, France. Sicot, Muriel; Kierren, Bertrand; Fagot-Revurat, Yannick; Moreau, Luc; Granet, Julien; Malterre, Daniel, Univ Lorraine, CNRS, Inst Jean Lamour, UMR 7198, BP 70239, F-54506 Vandoeuvre Les Nancy, France. Tristant, Damien; Gerber, Iann C., Univ Toulouse, CNRS, INSA, LPCNO,UPS, 135 Ave Rangueil, F-31077 Toulouse, France. Tristant, Damien, Univ Toulouse, CNRS, CEMES, UPR 8011, 29 Rue Jeanne Marvig,BP 94347, F-31055 Toulouse, Fran…

Materials scienceSupramolecular chemistrychemistry.chemical_elementNanotechnology02 engineering and technology010402 general chemistry01 natural sciences[SPI.MAT]Engineering Sciences [physics]/Materialslaw.inventionHighly oriented pyrolytic graphitelawMonolayer[CHIM]Chemical SciencesMoleculeIridium[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/MicroelectronicsPhysical and Theoretical Chemistry[SPI.ACOU]Engineering Sciences [physics]/Acoustics [physics.class-ph][PHYS]Physics [physics]Graphene021001 nanoscience & nanotechnology0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral EnergychemistryChemical physicsDensity functional theoryScanning tunneling microscope0210 nano-technologyThe Journal of Physical Chemistry C
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The effect of annealing temperature and time on synthesis of graphene thin films by rapid thermal annealing

2015

In this paper, we performed synthesis of graphene thin films by rapid thermal annealing (RTA) of thin nickel copper (Ni/Cu) layers deposited on spectroscopic graphite as a carbon source. Furthermore, we investigated the effect of annealing temperature and annealing time on formation and quality of synthesized graphene films. Raman spectroscopy study showed that annealing at lower temperatures results in formation of monolayer graphene films, while annealing at higher temperatures results in formation of multilayer graphene films. We used Raman mapping to determine the distribution of graphene sheets. Surface morphology of graphene thin films was investigated by atomic force microscopy and s…

Materials scienceThin films.Annealing (metallurgy)Scanning electron microscopeThin filmsvirusesAnalytical chemistry02 engineering and technology010402 general chemistry01 natural scienceslaw.inventionsymbols.namesakelawMaterials ChemistryGraphiteThin filmGraphene; Graphite; Rapid thermal annealing; Thin films.Graphene oxide paperRapid thermal annealingGrapheneMechanical EngineeringMetals and Alloys021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesElectronic Optical and Magnetic MaterialsChemical engineeringMechanics of MaterialssymbolsGraphiteGraphene0210 nano-technologyRaman spectroscopyGraphene nanoribbonsSynthetic Metals
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Molecular dynamics of CH4/N2 mixtures on a flexible graphene layer: adsorption and selectivity case study

2019

We theoretically investigate graphene layers, proposing them as membranes of subnanometer size suitable for CH4/N2 separation and gas uptake. The observed potential energy surfaces, representing the intermolecular interactions within the CH4/N2 gaseous mixtures and between these and the graphene layers, have been formulated by adopting the so-called Improved Lennard-Jones (ILJ) potential, which is far more accurate than the traditional Lennard-Jones potential. Previously derived ILJ force fields are used to perform extensive molecular dynamics simulations on graphene's ability to separate and adsorb the CH4/N2 mixture. Furthermore, the intramolecular interactions within graphene were explic…

Materials scienceUNESCO::QUÍMICA02 engineering and technology010402 general chemistry01 natural sciences:QUÍMICA [UNESCO]law.inventionlcsh:ChemistryMolecular dynamicsAdsorptionlawAb initio quantum chemistry methodsFlexibility (engineering)Grapheneab initio calculationsIntermolecular forceGeneral Chemistryflexible graphene021001 nanoscience & nanotechnologyPotential energymolecular dynamics0104 chemical scienceslcsh:QD1-999adsorptionChemical physicsIntramolecular forceab-initio potential0210 nano-technologyAb initio calculations; Ab-initio potential; Adsorption; Flexible graphene; Molecular dynamics
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RGB imaging system for mapping and monitoring of hemoglobin distribution in skin

2011

A prototype R-G-B imaging system for mapping of skin hemoglobin distribution has been designed and tested. Device basically consists of a commercial RGB sensor (CMOS, max. frame rate 87 fps for VGA resolution), RGB LED ringlight illuminator and orthogonally orientated polarizers for reducing specular reflectance. The system was examined for monitoring of hemoglobin concentration changes during specific provocations - arterial/venous occlusions and heat test. Hemoglobin distribution maps of several skin malformations were obtained, as well.

Materials scienceVideo Graphics Arraybusiness.industryPolarizerFrame rateReflectivitylaw.inventionOpticslawRGB color modelComputer visionHemoglobinSpecular reflectionArtificial intelligencebusinessSPIE Proceedings
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The development of nature-inspired gripping system of a flat CFRP strip for stress-ribbon structural layout

2021

Abstract The elegant stress-ribbon systems are efficient in pedestrian bridges and long-span roofs. Numerous studies defined corrosion of the steel ribbons as the main drawback of these structures. Unidirectional carbon fiber-reinforced polymer (CFRP) is a promising alternative to steel because of lightweight, high strength, and excellent corrosion and fatigue resistance. However, the application of CFRP materials faced severe problems due to the construction of the anchorage joints, which must resist tremendous axial forces acting in the stress-ribbons. Conventional techniques, suitable for the typical design of the strips made from anisotropic material such as steel, are not useful for СF…

Materials sciencebusiness.industry0211 other engineering and technologiesComputational Mechanics02 engineering and technologyStructural engineering021001 nanoscience & nanotechnologyComputer Graphics and Computer-Aided DesignHuman-Computer InteractionStress (mechanics)Computational MathematicsModeling and Simulation021105 building & constructionRibbonDevelopment (differential geometry)Nature inspired0210 nano-technologybusinessEngineering (miscellaneous)Journal of Computational Design and Engineering
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Numerical Procedure For Residual Stresses Prediction In Friction Stir Welding

2011

The prediction of residual stresses is a relevant and, under many points of view, still open issue for a proper welding process design. In the present paper a 3D FE model, with general validity for different joint configurations, was used to simulate the Friction Stir Welding (FSW) process of butt joints through a single block approach. The model is able to predict the residual stresses by considering thermal actions only, thanks to a new time efficient approach. A good agreement between calculated and experimentally measured data was found; the effectiveness of the presented numerical procedure was evaluated by comparing the calculation times of the proposed method with the ones of already…

Materials sciencebusiness.industryFriction stirweldingresidual stressesFEMApplied MathematicsMetallurgyGeneral EngineeringProcess (computing)Structural engineeringComputer Graphics and Computer-Aided DesignFinite element methodResidual stressThermalButt jointFriction stir weldingbusinessJoint (geology)Settore ING-IND/16 - Tecnologie E Sistemi Di LavorazioneAnalysisBlock (data storage)
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Micro-photoluminescence of Carbon Dots Deposited on Twisted Double-Layer Graphene Grown by Chemical Vapor Deposition

2021

Carbon-based nanomaterials, such as carbon dots (CDs) and graphene (Gr), feature outstanding optical and electronic properties. Hence, their integration in optoelectronic and photonic devices is easier thanks to their low dimensionality and offers the possibility to reach high-quality performances. In this context, the combination of CDs and Gr into new nanocomposite materials CDs/Gr can further improve their optoelectronic properties and eventually create new ones, paving the way for the development of advanced carbon nanotechnology. In this work, we have thoroughly investigated the structural and emission properties of CDs deposited on single-layer and bilayer graphene lying on a SiO2/Si …

Materials sciencechemistry.chemical_element02 engineering and technologyChemical vapor deposition010402 general chemistry01 natural sciencesNanomaterialslaw.inventionsymbols.namesakemicro-photoluminescencelawcarbon dotsGeneral Materials ScienceNanocompositebusiness.industryGrapheneBilayer021001 nanoscience & nanotechnology0104 chemical scienceschemistryRaman spectroscopysymbolsOptoelectronicstwisted bilayer grapheneAFM0210 nano-technologybusinessRaman spectroscopyBilayer grapheneCarbon
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PANI-Based Wearable Electrochemical Sensor for pH Sweat Monitoring

2021

Nowadays, we are assisting in the exceptional growth in research relating to the development of wearable devices for sweat analysis. Sweat is a biofluid that contains useful health information and allows a non-invasive, continuous and comfortable collection. For this reason, it is an excellent biofluid for the detection of different analytes. In this work, electrochemical sensors based on polyaniline thin films deposited on the flexible substrate polyethylene terephthalate coated with indium tin oxide were studied. Polyaniline thin films were abstained by the potentiostatic deposition technique, applying a potential of +2 V vs. SCE for 90 s. To improve the sensor performance, the electronic…

Materials scienceelectrochemical sensor02 engineering and technologySubstrate (electronics)QD415-436wearable sensor010402 general chemistry01 natural sciencespH meterBiochemistryreduced graphene oxidepolyanilineAnalytical ChemistryContact anglechemistry.chemical_compoundPolyanilineSettore ING-IND/17 - Impianti Industriali MeccanicipH sensorPhysical and Theoretical ChemistryThin filmSettore ING-IND/34 - Bioingegneria Industriale021001 nanoscience & nanotechnology0104 chemical sciencesElectrochemical gas sensorIndium tin oxidesweatSettore ING-IND/23 - Chimica Fisica ApplicataChemical engineeringchemistryElectrode0210 nano-technologyChemosensors
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Substrate and atmosphere influence on oxygen p-doped graphene

2016

Abstract The mechanisms responsible for p-type doping of substrate supported monolayer graphene (Gr) by thermal treatments in oxygen ambient have been investigated by micro-Raman spectroscopy, atomic force microscopy (AFM) and X-ray Photoelectron Spectroscopy (XPS), considering commonly employed dielectric substrates, such as SiO 2 and Al 2 O 3 thin films grown on Si. While a high p-type doping (∼10 13  cm −2 ) is observed for Gr on SiO 2 , no significant doping is found for Gr samples on the Al 2 O 3 substrate, suggesting a key role of the Gr/SiO 2 interface states in the trapping of oxygen responsible for the Gr p-type doping. Furthermore, we investigated the doping stability of Gr on SiO…

Materials sciencegenetic structuresSettore FIS/01 - Fisica SperimentaleDopingAnalytical chemistrychemistry.chemical_element02 engineering and technologyGeneral ChemistrySubstrate (electronics)Dielectric010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesNitrogenOxygenGraphene doping substrate effects thermal effects Raman Spectroscopy0104 chemical sciencesp-type doped grapheneX-ray photoelectron spectroscopychemistryoxygen annealingGeneral Materials ScienceThin film0210 nano-technologySpectroscopyCarbon
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