Search results for " heterogeneous"

Photocatalytic oxidation of nitrobenzene and phenylamine: Pathways and kinetics

2007

WOS: 000245150800018

Effective electrical conductivity of microstructural patterns of binary mixtures on a square lattice in the presence of nearest-neighbour interactions

2018

Abstract The effective conductivity and percolative behaviour of microstructural patterns of binary mixtures are studied. Microstructure patterns are not entirely random, but result from the presence of attractive or repulsive interactions and thermal fluctuations. The interactions of the particles with one another lead to the formation of correlations between particle positions, while thermal fluctuations weaken these correlations. A simple lattice model is used, where each site is occupied by a single particle, and interactions can occur only between the nearest neighbours. The Kawasaki algorithm is adopted to create 2D microstructure samples. The microstructure is treated as a continuous…

Preface

2019

Preface of the book "Heterogeneous Photocatalysis Relationships with Heterogeneous Catalysis and Perspectives"

COMPARISON OF THE PHOTOCATALYTIC DEGRADATION OF 2-PROPANOL IN GAS-SOLID AND LIQUID-SOLID SYSTEMS BY USING TiO2 – LnPc2 HYBRID POWDERS

2009

Photocatalytic degradation of 2-propanol was carried out as a probe reaction both in gas–solid and in liquid–solid systems in the presence of TiO2 both bare and impregnated with lanthanide (Sm, Gd, Ho) bis-phthalocyanines (LnPc2) used as sensitizers. Continuous and batch photo-reactors, irradiated with an equal flux of photons, were used in gas–solid and in liquid–solid systems, respectively. Propanone and acetaldehyde were the main intermediates found in both systems during 2-propanol oxidation, whereas carbon dioxide and water were the final oxidation products exclusively in the gas–solid regime. The photocatalysts exhibited significantly higher activity in the liquid–solid system than in…

Green Oxidation of Alcohols to Carbonyl Compounds by Heterogeneous Photocatalysis

2010

Photocatalytic oxidation of acetonitrile in gas–solid and liquid–solid regimes

2005

Il programma NON mi ha consentito di scaricare il PDF di questo articolo. Se lo volete ditemi come inviarlo ABSTRACT Photocatalytic degradation of acetonitrile was carried out in both gas–solid and liquid–solid regimes using two commercial TiO2 catalysts (Merck and Degussa P25). For the gas–solid regime, a continuous annular photoreactor was used. The influence on photodegradation kinetics of the gas flow rate and concentrations of acetonitrile, oxygen, and water was investigated. Acetonitrile degradation products detected in the gas phase included carbon dioxide and hydrogen cyanide. The same photoactivity was exhibited in the presence and in the absence of water vapour. The liquid–solid reg…

AN EFFICIENT SOLUTION OF HETEROGENEOUS ANISOTROPIC CONVECTION/DIFFUSION TRANSPORT PROBLEMS

2012

EFFICIENT SOLUTION OF HETEROGENEOUS ANISOTROPIC DIFFUSION PROBLEMS

2012

Imidazolium-Functionalized Carbon Nanohorns for the Conversion of CO2 Unprecedented Increase of Catalytic Activity after Recycling

2017

Carbon nanohorns (CNHs) were selected as a novel catalytic platform for the design of imidazolium based hybrid materials able to promote the conversion of carbon dioxide into cyclic carbonates. Several heterogeneous catalysts were prepared using a one-step procedure based on the radical polymerization of various bis-vinylimidazolium salts in the presence of pristine CNHs. The as-synthesized materials were tested for the fixation of CO2 into epoxides. The excellent catalytic performances were evaluated in terms of turnover number and productivity. The versatility of the above hybrids was proved using several epoxides as substrate. Catalysts recyclability was successfully verified for several…

Effect of Pre-Reduction on the Properties and the Catalytic Activity of Pd/Carbon Catalysts: A Comparison with Pd/Al2O3

2013

The effect of pre-reduction in solution with chemical reagents on the catalytic performance and catalyst properties of Pd/carbon catalysts was systematically investigated with a multitechnique approach. The results are critically discussed in comparison to those recently obtained on analogous Pd/alumina catalysts. It was proved that the Pd phase on the carbon surface is characterized by a high mobility, opposite to what occurs on alumina. As a result, the Pd particles on carbon aggregate together during pre-reduction, with a consequent decrease in available metal surface. Pd particles remain aggregated also in reaction conditions; the decreased Pd dispersion negatively affects the catalyst …