Search results for " homogeneity."
showing 3 items of 13 documents
Real-time observation of the charge transfer to solvent dynamics
2013
Intermolecular electron-transfer reactions have a crucial role in biology, solution chemistry and electrochemistry. The first step of such reactions is the expulsion of the electron to the solvent, whose mechanism is determined by the structure and dynamical response of the latter. Here we visualize the electron transfer to water using ultrafast fluorescence spectroscopy with polychromatic detection from the ultraviolet to the visible region, upon photo-excitation of the so-called charge transfer to solvent states of aqueous iodide. The initial emission is short lived (similar to 60 fs) and it relaxes to a broad distribution of lower-energy charge transfer to solvent states upon rearrangeme…
Sample allocation for efficient model-based small area estimation
2017
We present research results on sample allocations for efficient model-based small area estimation in cases where the areas of interest coincide with the strata. Although model-assisted and model-based estimation methods are common in the production of small area statistics, utilization of the underlying model and estimation method are rarely included in the sample area allocation scheme. Therefore, we have developed a new model-based allocation named g1-allocation. For comparison, one recently developed model-assisted allocation is presented. These two allocations are based on an adjusted measure of homogeneity which is computed using an auxiliary variable and is an approximation of the int…
PRELIMINARY ANALYSES FROM A HOSPITAL BASED STUDY ON 3154 WESTERN SICILIAN PATIENTS WITH ORAL MUCOSAL LESIONS
2010
Objectives: Diagnosis of the wide variety of lesions that occur in the oral cavity is an essential part of dental practice. The objective of this study was to explore the demographic and behavioural profiles of patients affected by oral cavity diseases on a wide spectrum. Methods: Demographic and behavioural data of 3154 patients with at least one oral cavity disease among those consecutively visited between 2004 and 2009 at the Unit of Oral Medicine, were recorded: gender, age, smoking status, alcohol consumption, drugs use. Analysis was restricted to the eleven more frequent oral cavity diseases. Firstly, Multiple Correspondence Analysis (MCA) was applied as a descriptive tool to geometri…