Search results for " hydrothermal"

The selective oxidative dehydrogenation of ethane over hydrothermally synthesised MoVTeNb catalysts

2002

Mo–V–Te–Nb metal oxide catalysts prepared by hydrothermal synthesis and heat-treated in N2 at high temperatures (600–700 °C) show high activity and selectivity for the oxidative dehydrogenation of ethane to ethene. Yields of ethene of 75% have been obtained at 400 °C on the best catalysts. Dejoz Garcia, Ana Maria, Ana.M.Dejoz@uv.es

Microbial Biofilms Along a Geochemical Gradient at the Shallow-Water Hydrothermal System of Vulcano Island, Mediterranean Sea

2022

Shallow water hydrothermal vents represent highly dynamic environments where strong geochemical gradients can shape microbial communities. Recently, these systems are being widely used for investigating the effects of ocean acidification on biota as vent emissions can release high CO2 concentrations causing local pH reduction. However, other gas species, as well as trace elements and metals, are often released in association with CO2 and can potentially act as confounding factors. In this study, we evaluated the composition, diversity and inferred functional profiles of microbial biofilms in Levante Bay (Vulcano Island, Italy, Mediterranean Sea), a well-studied shallow-water hydrothermal ve…

EFFECTS OF SHALLOW WATER HYDROTHERMAL VENTS ON PHYTOBENTHIC COMMUNITIES

2012

Metallic nanoparticle enrichment at low temperature, shallow CO2 seeps in Southern Italy

2012

We report on metal enrichment along a natural pH gradient owing to increased CO2 degassing at cold, shallow seeps of Vulcano Island in the Mediterranean Sea, off Sicily. We assessed composition of unfiltered and filtered seawater (<100 nm) along acidic zones ranging between ambient and pH 5, and showed that most seep derived elements are present as nanoclusters which then aggregate into larger colloids while mixing with ambient seawater along a pH gradient. Size and elemental composition of such naturally occurring nanoparticles assessed by modern characterisation methods were in good agreement with the results from conventional analytical methods. We provide analytical evidence for the pre…

CHLORITE/SMECTITE - ALKALI FELDSPAR METASOMATIC XENOLITHS FROM HYBLEAN MIOCENIC DIATREMES (SICILY, ITALY): EVIDENCE FOR EARLY INTERACTION BETWEEN HYD…

2006

Upper-Miocene tuff-breccia pipes from the Hyblean area (south-eastern Sicily) bear a number of ultramafic and mafic xenoliths (spinel-peridotites, pyroxenites, gabbroic rocks) whose study has led to conclude that the Meso-Caenozoic carbonatic and volcanic succession stands upon a fossil oceanic core-complex, probably connected with the adjacent Ionian crust. Evidence for hydrothermal metasomatism is common in the Hyblean ultramafic and mafic xenoliths. In some cases, extreme metasomatic transformation and shearing have deleted original mineralogy and textures yielding unusual rocks, hereafter called “metasomatites”. These rocks generally exhibit cataclastic texture, their hydrothermal miner…

Syntheses of TiO2 anatase nanocrystals with controlled size distribution. Influence of the crystallites size on the Raman spectrum and investigation …

2006

The determination of the size and the size distribution of anatase TiO2 nanopowders using Raman spectroscopy is presented. Several synthesis methods (soft chemistry, water-in-oil microemulsion, continuous hydrothermal synthesis) are used in order to control the size (from 3 to 20 nm), shape, phase and size distribution. The shift and width of the anatase Eg peak are often used to obtain the nanoparticles size. Homever, this peak is also sensitive to nonstoichiometry and others parameters. Low-frequency Raman scattering does not suffer from this problem. Size distibutions obtained by Raman spectroscopy and MET micrographs are compared. Finally, in situ Raman spectroscopy is used to study the…

The community of Cystoseira brachycarpa J. Agardh emend. Giaccone (Fucales, Phaeophyceae) in a shallow hydrothermal vent area of the Aeolian Islands …

2014

A Cystoseira brachycarpa community from a vent area off Panarea Island (Italy) was investigated in two sites at different pH values. At low pH, species richness and coverage were low and the community displayed a reduced reproductive capacity. Conversely, at normal pH, dense canopies of fertile C. brachycarpa were found.

Hydrothermal liquefaction of waste biomass in stirred reactors: One step forward to the integral valorization of municipal sludge

2020

Abstract Hydrothermal liquefaction (HTL) of municipal sludge (MS) was performed at 350 °C for 30 min (subcritical water) and at 400 °C for 0 min (supercritical water) at fixed kinetic severity (LogR0 = 8.9) in static and stirred batch reactors to study the effect of the flow regime on the energy recovery (ER) of the process and on the quality of the products. With adopted experimental procedures it was possible to reduce to less than 10% the yield of lost organic compounds, termed volatiles (VT), and to collect and quantify a liquid hydrocarbon fraction (HC) separated from the biocrude (BC). The highest value of the HC yield, 25% w/w, was obtained in supercritical conditions. The C content …

Hydrothermal ageing of radiation cured epoxy resin-polyether sulfone blends as matrices for structural composites

2010

Abstract The hydrothermal ageing of epoxy–thermoplastic blends, used as matrices for carbon fibre composites, cured by electron beam, has been studied. Two different thermoplastic percentages have been adopted. A suitable choice of both curing process and formulation parameters allows to carry out irradiation at mild temperature with several advantages, coming from a “non thermal” process, for both the final properties of the materials and the environment. Nevertheless the occurring of vitrification phenomena needs the use of a short thermal treatment after irradiation on the already solid materials, in order to complete the cure reactions. Radiation cured epoxy based matrices have been sub…

Mode I fracture toughness behavior of hydro-thermally aged carbon fibre reinforced DGEBA-HHPA-PES systems

2012

In this work the Mode I fracture toughness behavior of unidirectional CFRP laminates is investigated by means of Double Cantilever Beam (DCB) tests. The composite samples were manufactured by thermal curing after impregnation of a Carbon fabric with a DGEBA epoxy and anhydride HHPA curing agent. One resin batch was also mixed with a PES thermoplastic monomer to enhance the matrix toughness. Two lots of samples, toughened and un-toughened, were then left to soak in hot water to achieve various degrees of aging. The influence of matrix toughening and hydrothermal aging on the delamination behavior of the composite have then been assessed and correlated with characterization data from Dynamic …