Search results for " hysteresis"
showing 8 items of 98 documents
Sorption of n-hexane in amorphous polystyrene
2014
Sorption properties of pure n-hexane vapor in amorphous polystyrene (PS) were studied at 298 K by thermogravimetry under controlled vapor pressure. Two sorption-desorption cycles were performed by varying the relative pressure between 0 and 0.91. Mixing of PS with n-hexane resulted in a strong plasticization, which was evidenced by quite significant depression in the glass transition temperature of the polymer as shown by differential scanning calorimetry. Maximum quantity of n-hexane sorbed in the PS at 298 K and at a pressure close to saturation was about 12.4 wt %. The thermogravimetry yielded an isotherm with a strong hysteresis loop, explanation of which was hypothesized with the help …
Spin-crossover iron(ii) complex showing thermal hysteresis around room temperature with symmetry breaking and an unusually high T(LIESST) of 120 K.
2019
We report a Fe(II) complex based on 4′,4′′ carboxylic acid disubstituted dipyrazolylpyridine that shows a spin-crossover close to room temperature associated to a crystallographic phase transition and the LIESST effect with a high T(LIESST) of 120 K.
Size-Dependent Spin Switching in Robust Fe-triazole@SiO2 Spin-Crossover Nanoparticles with Ultrathin Shell
2019
<p>A familly of chemically robust hybrid [Fe(Htrz)2(trz)](BF4)@SiO2nanoparticles (NPs) presenting different sizes (from ca. 90 to 28 nm) and an ultrathin silica shell (< 3 nm) have been prepared. All NPs present a characteristic abrupt spin transition with a subsequent decrease in the width of the thermal hysteresis upon reducing the NP size.<br></p>
An Efficient Damping Technique for the Unstable Hysteretic Rotor Whirl by Proper Suspension Systems
2009
This paper shows as the destabilising influence of the shaft hysteresis on the supercritical rotor whirl can be efficiently counterbalanced by external dissipative sources. After calculating the steady whirling paths of the rotor and the bearing due to unbalance, the stability is checked by the Routh-Hurwitz procedure, investigating the influence of the stiffness anisotropy of the supports. A fairly interesting result is that the instability phenomena can be conveniently prevented by different suspension stiffness in the horizontal and vertical planes.
Modificación de la histéresis corneal y su influencia en la cirugía de glaucoma y en la biomecánica del nervio óptico
2013
El principal factor de riesgo para el desarrollo de la neuropatía óptica glaucomatosa y el único en el que podemos actuar hoy en día es la elevación de la presión intraocular, por lo que cobra extrema importancia la exquisitez en la determinación del parámetro en el que va a girar nuestra actitud. Sin embargo, existen múltiples situaciones donde los pacientes, a pesar de tener la PIO en límites normales, continúan progresando. Se han apuntado múltiples causas para este fenómeno como la fluctuación de la PIO o el aumento nocturno de la PIO por el decúbito supino; pero la aparición del concepto de histéresis ocular planteó nuevos interrogantes desde 2 puntos de vista principalmente. El primer…
Softening of Silica Filled Styrene-Butadiene Rubber under Uniaxial Cyclic Loading
2016
Stress-strain behaviour of silica filled styrene-butadiene rubber showed strong hysteresis and cyclic softening, while these effects were almost negligible for the neat rubber. Significant Mullins effect occurs between the first and second loading cycles, whereupon samples reach their steady state after four repeated cycles. The degree of softening increases with volume content of silica characterizing the softening effect as a breakdown of the filler-formed microstructure defined by both, specific interactions in the filler associations and between the filler and rubber matrix. Contribution of different damage mechanisms to the total energy losses on different stages of extension was estim…
Rare‐earth cyclobutadienyl sandwich complexes: Synthesis, structure and dynamic magnetic properties
2018
The potassium cyclobutadienyl [K2{η4‐C4(SiMe3)4}] (1) reacts with MCl3(THF)3.5 (M=Y, Dy) to give the first rare‐earth cyclobutadienyl complexes, that is, the complex anions [M{η4‐C4(SiMe3)4}{η4‐C4(SiMe3)3‐κ‐(CH2SiMe2}]2−, (2M), as their dipotassium salts. The tuck‐in alkyl ligand in 2M is thought to form through deprotonation of the “squarocene” complexes [M{η4‐C4(SiMe3)4}2]− by 1. Complex 2Dy is a single‐molecule magnet, but with prominent quantum tunneling. An anisotropy barrier of 323(22) cm−1 was determined for 2Dy in an applied field of 1 kOe, and magnetic hysteresis loops were observed up to 7 K. nonPeerReviewed
Asymmetric hysteresis for probing Dzyalohsinskii-Moriya interaction
2016
The interfacial Dzyaloshinskii-Moriya interaction (DMI) is intimately related to the prospect of superior domain-wall dynamics and the formation of magnetic skyrmions. Although some experimental efforts have been recently proposed to quantify these interactions and the underlying physics, it is still far from trivial to address the interfacial DMI. Inspired by the reported tilt of the magnetization of the side edge of a thin film structure, we here present a quasi-static, straightforward measurement tool. By using laterally asymmetric triangular-shaped microstructures, it is demonstrated that interfacial DMI combined with an in-plane magnetic field yields a unique and significant shift in m…