Search results for " impianti nucleari"
showing 10 items of 413 documents
Process modelling of a novel acid-base flow battery based on bipolar-membranes
2021
The storage of electrical energy is crucial for a deeper penetration of renewable energies with intermittent nature, e.g. solar and wind energy. The Acid/Base Flow Battery (AB-FB) is a novel, sustainable, environmental-friendly storage technology with high energy density of the electrolyte solutions. The process is based on reversible electrodialytic techniques with bipolar membranes, which convert the electrical energy in the chemical energy associated to pH gradients and vice versa. The charge phase is a bipolar membrane electrodialysis process, while the discharge phase is a bipolar membrane reverse electrodialysis process. The stack consists of several repetitive units, called triplets,…
A parametric CFD study of hollow fiber membrane modules for hemodialysis
2022
Hemodialysis is a membrane-based process in which solute transport from the patient’s blood to a rinsing solution (dialysate) occurs by diffusion and ultrafiltration. Devices used in hemodialysis are cylindrical modules filled with hollow-fiber membranes which allow the removal of toxic substances and metabolic wastes from the blood, but inhibit the passage of proteins and cells to the dialysate. A predictive porous-media model of hemodialysis was developed and validated against experimental data. Unlike previous literature models, it requires only basic membrane properties (hydraulic and diffusive permeabilities and reflection coefficients) instead of relying on empirically adjusted global…
On the simulation of stirred tank reactors via computational fluid dynamics
2000
Abstract Predictions of flow fields in a stirred tank reactor, obtained by computational fluid dynamics, were used for the simulation of a mixing sensitive process consisting of two parallel reactions competing for a common reagent: A + B → Prod .1 A + C → Prod .2. Experimental data were obtained for A = OH − , B = 1 2 Cu ++ and C=ethyl-chloroacetate. For this reaction scheme the final selectivity of the process, easily measured by a simple colorimetric analysis of the residual Cu++, was found to depend on agitation speed and therefore on the mixing history during the batch process. The flow field-based three-dimensional simulations performed here led to predictions that compared very well …
A porous media CFD model for the simulation of hemodialysis in hollow fiber membrane modules
2022
A computational model was developed to predict the performance of hollow fiber membrane hemodialyzers. Blood and dialysate were modelled as fluids flowing through two interpenetrating porous media. Concerning hydrodynamics, experimental Darcy permeabilities measured for commercial hemodialyzers were used for both compartments. Concerning mass transfer, both diffusion and ultrafiltration were simulated. On the blood side theoretical Sherwood numbers for parallel flow in pipes were adopted. On the dialysate side Sherwood numbers were derived from CFD predictions for regular hexagonal fiber bundles. Solute concentrations on the two sides were alternatively computed in an iterative way and were…
Performance Comparison of Alternative Hollow-Fiber Modules for Hemodialysis by Means of a CFD-Based Model
2022
Commercial hemodialyzers are hollow-fiber cylindrical modules with dimensions and inlet–outlet configurations dictated mostly by practice. However, alternative configurations are possible, and one may ask how they would behave in terms of performance. In principle, it would be possible to depart from the standard counter-flow design, while still keeping high clearance values, thanks to the increase in the shell-side Sherwood number (Sh) due to the cross-flow. To elucidate these aspects, a previously developed computational model was used in which blood and dialysate are treated as flowing through two interpenetrating porous media. Measured Darcy permeabilities and mass transfer coefficients…
Investigation of Reverse ElectroDialysis Units by Multi-Physical Modelling
2016
Reverse electrodialysis (RED) is an electrochemical membrane process that converts the salinity gradient energy between two solutions into electric current, by using ion exchange membranes. A novel multi-physical approach for RED modelling is proposed. 2-D simulations of one cell pair with tertiary current distribution (Nernst–Plank equation and local electroneutrality) were performed. Moreover, the Donnan exclusion theory was implemented for simulating double layer phenomena. Transport phenomena and electrochemical behavior were well described. The influence of membrane/channel configuration, dilute concentration and feeds velocity on the process performance was assessed. For a dilute conc…
Flow and mass transfer in spacer-filled channels for reverse electrodialysis: a CFD parametrical study
2016
Abstract In reverse electrodialysis (RED) concentration polarization phenomena and pressure drop affect strongly the power output obtainable; therefore the channel geometry has a crucial impact on the system optimization. Both overlapped and woven spacers are commonly commercialised and adopted for RED experiments; the latter exhibit some potential advantages, such as better mixing and lower shadow effect, but they have been poorly investigated in the literature so far. In this work, computational fluid dynamics was used to predict fluid flow and mass transfer in spacer-filled channels for RED applications. A parametric analysis for different spacer geometries was carried out: woven (w) and…
CFD analysis of the fluid flow behavior in a reverse electrodialysis stack
2012
Salinity Gradient Power by Reverse Electrodialysis (SGP-RE) technology allows the production of electricity from the different chemical potentials of two differently concentrated salty solutions flowing in alternate channels suitably separated by selective ion exchange membranes. In SGP-RE, as well as in conventional ElectroDialysis (ED) technology, the process performance dramatically depends on the stack geometry and the internal fluid dynamics conditions: optimizing the system geometry in order to guarantee lower pressure drops (DP) and uniform flow rates distribution within the channels is a topic of primary importance. Although literature studies on Computational Fluid Dynamics (CFD) a…
Pressure drop in woven-spacer-filled channels for reverse electrodialysis: CFD prediction and experimental validation
2015
Reverse electrodialysis (RED) is a promising technology for electric power generation by the chemical potential difference of two salt solutions within a stack equipped by selective ionexchange membranes (salinity gradient energy). Mechanical energy is required for pumping the feed solutions, which can reduce dramatically the net power output. In this work Computational Fluid Dynamics (CFD) simulations of spacer-filled channels for RED were carried out in parallel with an experimental campaign focused on the collection of data for model validation.
CFD simulations of early- to fully-turbulent conditions in unbaffled and baffled vessels stirred by a Rushton turbine
2021
Abstract Laboratory scale unbaffled tanks provided with a top cover and a baffled tank both stirred by a Rushton turbine were simulated by carrying out RANS simulations. Three different turbulence models were adopted (k- ω SST, k- e and the SSG Reynolds stress model) to predict the flow field and the relevant performance parameters (power and pumping numbers) of the tank operated from early to fully turbulent conditions. CFD results were compared with literature experimental data and DNS simulation results to validate and properly compare the models. In the range of Reynolds numbers investigated, results showed that, for the unbaffled tank, the SSG model based on Reynolds stresses is a bett…