Search results for " interface"
showing 10 items of 1741 documents
Atomic layer deposition of AlN from AlCl3 using NH3 and Ar/NH3 plasma
2018
The atomic layer deposition (ALD) of AlN from AlCl3 was investigated using a thermal process with NH3 and a plasma-enhanced (PE)ALD process with Ar/NH3 plasma. The growth was limited in the thermal process by the low reactivity of NH3, and impractically long pulses were required to reach saturation. Despite the plasma activation, the growth per cycle in the PEALD process was lower than that in the thermal process (0.4A ° vs 0.7A ° ). However, the plasma process resulted in a lower concentration of impurities in the films compared to the thermal process. Both the thermal and plasma processes yielded crystalline films; however, the degree of crystallinity was higher in the plasma process. The…
Hexagonal Microparticles from Hierarchical Self-Organization of Chiral Trigonal Pd3L6 Macrotetracycles
2021
Construction of structurally complex architectures using inherently chiral, asymmetric, or multi-heterotopic ligands is a major challenge in metallosupramolecular chemistry. Moreover, the hierarchical self-organization of such complexes is unique. Here, we introduce a water-soluble, facially amphiphilic, amphoteric, chiral, asymmetric, and hetero-tritopic ligand derived from natural bile acid, ursodeoxycholic acid. We show that via the supramolecular transmetalation reaction, using nitrates of Cu(II) or Fe(III), and subsequently Pd(II), a superchiral Pd3L6 complex can be obtained. Even though several possible constitutional isomers of Pd3L6 could be formed, because of the ligand asymmetry a…
Microscratch testing method for systematic evaluation of the adhesion of atomic layer deposited thin films on silicon
2016
The scratch test method is widely used for adhesion evaluation of thin films and coatings. Usual critical load criteria designed for scratch testing of coatings were not applicable to thin atomic layer deposition (ALD) films on silicon wafers. Thus, the bases for critical load evaluation were established and the critical loads suitable for ALD coating adhesion evaluation on silicon wafers were determined in this paper as LCSi1, LCSi2, LCALD1, and LCALD2, representing the failure points of the silicon substrate and the coating delamination points of the ALD coating. The adhesion performance of the ALD Al2O3, TiO2, TiN, and TaCN+Ru coatings with a thickness range between 20 and 600 nm and dep…
Effect of Molybdate on Corrosion Performance of Oxide Coating Produced on 7075 Al Alloy Using PEO
2022
In this research, plasma electrolytic oxidation (PEO) coatings were prepared on 7075 Al alloy in a silicate-based solution with Na2MoO4 additive using a unipolar waveform at constant current density. The coatings displayed micro-pores, micro-cracks, pancake-like and crater-like features, and also solidified molten oxide particles on the surface. The coatings were majorly composed of Al2O3 (γ, δ, and α), SiO2 (amorphous), and MoO3 phases, which confirms the incorporation of molybdenum in the case of additive-containing coatings. Molybdenum species were transported through cracks, channels, and micropores, as the ready access pathways into the coating and partly sealed the c…
Aluminum tri-isopropoxide as an alternative precursor for atomic layer deposition of aluminum oxide thin films
2019
Due to the safety challenges associated with the use of trimethylaluminum as a metal precursor for the deposition of alumina, different chemicals have been investigated over the years to replace it. The authors have investigated the use of aluminum tri-isopropoxide (TIPA) as an alternative alkoxide precursor for the safe and cost-effective deposition of alumina. In this work, TIPA is used as a stable Al source for atomic layer deposition (ALD) of Al2O3 when different oxidizing agents including water, oxygen plasma, water plasma, and ozone are employed. The authors have explored the deposition of Al2O3 using TIPA in ALD systems operating in vacuum and atmospheric pressure conditions. For the…
Fresh-Cut Mangoes: How to Increase Shelf Life by Using Neem Oil Edible Coating
2022
The mango is the most widely cultivated tropical fruit. Fresh-cut mango is very useful, but it is very perishable. The purpose of this study was to highlight the effects of neem oil on fresh-cut mango fruits kept for 9 days at 4 ± 1 °C and 80 ± 5% relative humidity. The neem plant (Azadirachta indica) has numerous antioxidant and antibacterial properties. Despite this, very few studies have been carried out on neem oil added to edible coatings (EC) to retard ripening processes. Two formulations were tested: EC1 (hydroxypropyl methylcellulose + CaCl2) and EC2 (hydroxypropyl methylcellulose + CaCl2 + neem oil), both compared with an untreated sample (control). Physicochemica…
Measurement and communication interfaces for distributed generation in smart grids
2013
The aim of this work is to perform a feasibility study on the measurement and communication strategies for the development of a new generation of interface devices for distributed generators and their integration on smart grids. The communication system can use one or more technologies, at the various levels, creating a low cost network infrastructure, in the framework of a SCADA (Supervisory Control and Data Acquisition) architecture. As regards the measurements, the attention is focused on the anti-islanding protection, based on a hybrid solution, which makes use of local measurements and communications with the grid, at both MV and LV level by employing the PLC technology. Some simulatio…
An interface protection system with power line communication for distributed generators remote control
2014
The aim of this work is to present a narrow band power line communication (NB-PLC) interface protection system (IPS) for distributed generators (DGs); it has been developed according to the current standard CEI 0-21 and the requirements for smart grid applications. For such applications, the new IPSs have to implement new intelligent functions such as remote monitoring and control of DGs and Energy Storage Systems (ESSs) inverters, not only in terms of disconnection but also of voltage regulation and power modulation by the utility control. The main feature of the developed IPS is the ability to interact with both the grid and the DG's and ESS's inverters. In fact, it can communicate with t…
Cambiamenti nell'uso dei soggetti clitici veneti: il ruolo del contatto con l'italiano
2018
This chapter discusses the results of a series of data on the syntax of subject clitic pronouns in Venetan dialects. The data were gathered through a crowdsourcing tool (google modules), and more than 700 participants took part in the inquiry. The data collection asked for grammaticality judgements on a series of contexts. The main research question was whether the syntax of subject clitics is changing in the language of the younger generation: this question is particularly important because the distribution of the Venetan varieties througout the Veneto region is changing, due to the increasing influence and presence of Italian, which is the L1 of most of the younger speakers. The results s…