Search results for " interfaces"

Laser-induced damage in cold-sprayed composite coatings

2011

International audience; Ag-Ni composite coatings were achieved using the cold spray process. In this work, two blends were sprayed to lead to coatings with different mechanical properties, which corresponded to either a fine or a coarse microstructure. These coatings were studied using SEM and X-ray microtomography (XMT) to determine the best coating quality through characterization of particle-to-particle bonding. The fine microstructure showed better properties than the coarse microstructure. To avoid time-consuming characterization techniques such as SEM and XMT, an innovative laser characterization test was developed. The principle of this test is based on the thermal shock-induced by a…

WITHDRAWN: Ab initio calculations of SrZrO3 and PbZrO3 (001) surfaces

2010

Recrystallization in subsurface zone seen by positron annihilation

2010

Abstract The paper presents studies of the defect distribution, detected by the positron annihilation method in the subsurface zone (SZ) of copper samples after dry sliding wear. It takes advantage of a new experimental technique based on scanning of the positron implantation profile. It allowed us to detect the defect profile in copper to the depth of 200 μm in a nondestructive way and study isochronal annealing behavior of this profile. We determined that annealing induces a recrystallization process which runs faster close to the surface than in deeper regions. After sliding, the complete recrystallization of the substructure takes place at temperature c.a. 600 °C. Some changes in the de…

Atomistic simulation of the [001]surface structure in BaTiO3

1997

Abstract We simulate the effect of the surface relaxation on the polarization of the layers of paraelectric phase in the vicinity of the [001] surface in BaTiO 3 in the framework of the shell-model potentials. We observe large polarization of ions in the first two layers of the surface. Our simulations confirm the possibility of existence of Ti- and Ba-containing top layers in [001] BaTiO 3 surfaces.

Giant piezoelectricity in B/N doped 4,12,2-graphyne

2020

Abstract The effects of boron (B) and nitrogen (N) substitutions in 4,12,2-graphyne on its geometric structure and mechanical as well as electronic properties have been systematically investigated with the aid of density functional theory (DFT). The trend in the elastic properties of the substituted systems is determined by the doping positions and the type of the dopants. The Bader charge analysis reveals that the N dopant at the sp-site destroys the acetylenic linkage in 4,12,2-graphyne, but instead tends to form a polar bond, or even possibly a charge-shift bond. In particular, an obvious in-plane piezoelectricity is induced by foreign atom substitutions owing to the deformation of the p…

An Ising ferromagnet with an antiferromagnetic surface layer: A simple model for magnetic surface reconstruction

1985

Simple cubic Ising lattices are studied by Monte Carlo simulation, using a thin film geometry (usually 40 atomic layers thick), with nearest neighbour ferromagnetic exchange J in the bulk and nearest neighbour antiferromagnetic interaction Js between surface spins. Applying a technique of preferential sampling in the surface layers, we investigate the ordering for a variety of values of JsJ and for various temperatures. For JsAF < Js < − 0.25J (where JsAF ≈ − 2.01J) ferromagnetic ordering occurs at a higher temperature than the antiferromagnetic surface ordering, while for − 0.25J < Js no antiferromagnetic long range order is possible. For Js < JsAF the surface transition occurs at a higher…

Reconstructed bcc Co films on the surface

2007

Abstract Ultrathin epitaxial Co films on Cr ( 1 1 0 ) are examined by scanning tunneling microscopy and spectroscopy (STM and STS). At room temperature Co grows as pseudomorphic bcc layers for the first two monolayers and forms close-packed Co layers with stacking faults for thicker coverages. A periodic lattice distortion appears in two equivalent (3 × 1) reconstruction domains in combination with a regular lattice of dislocation lines oriented along the in-plane close-packed row directions bcc [ 1 1 ¯ 1 ] and bcc [ 1 ¯ 1 1 ] . The reconstruction and the occurrence of dislocation lines are caused by the epitaxial strain. The local density-of-states function is mapped by scanning tunneling …

Strain effects and phonon-plasmon coupled modes in Si-doped AlN

2009

The E 2h and A 1 (LO) phonon modes of AlN films grown on sapphire are analyzed by Raman scattering as a function of silicon doping for concentrations covering from 5.5 x 10 19 cm ―3 to 5.2 x 10 21 cm ―3 . For high doping levels the appearance of a mode around 520 cm ―1 indicates the precipitation of crystalline silicon in the samples and its inhomogeneous incorporation to the AlN layer. The frequency of this mode shifts to lower energies with doping, indicating that the silicon crystals are embedded in the AlN lattice and under tensile strain. On the other hand, the AlN phonon modes are blue-shifted due to the compressive strain as a result of the silicon incorporation. This strain is parti…

Experimental investigation of the influence of adhesion on the frictional conditions in the cutting process

1999

Abstract This paper presents the results of an experimental study on the influence of adhesion on the tribological characteristics of the tool-chip interface. It was established that under orthogonal cutting conditions both the high interface temperature and severe plastic deformation result in relatively strong adhesion between steel and uncoated carbide. In particular, the molecular–mechanical theory of friction was applied to estimate the shear strength of the local adhesive junction, and to divided the rake face friction into two terms—an adhesion term (the interfacial coefficient of friction) and the deformation term. It should be pointed out that the data obtained provide a new approa…

Study and evaluation of fretting critical slip conditions by applying the design of experiments method

2006

Tribological systems are complex systems that require a multi-disciplinary (mechanical, material, physico-chemical) approach where numerous influence factors can be involved. To characterize a contact couple, the intrinsic parameters of the materials as well as the parameters related to the contact loading and the surrounding environment need to be taken into account. Fretting analysis, by means of running condition-fretting maps (RCFM), allows the behavior of the contact couple to be taken into account and to predict the boundary between partial slip and gross slip conditions. This article presents the study of a steel/polycarbonate couple during fretting tests. The study was carried out b…