Search results for " isola"

showing 10 items of 482 documents

Progressive Isolated Hypoglossal Nerve Palsy and Sudden Asphyzial Death

2008

Stab Wound Isolated Hypoglossal Nerve Palsy Sudden Death
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Matrix isolation studies on the co-condensation reactions of molecular SiO and GeO: the characterisation of the novel cyclic species SiGeO(2), Si(2)G…

2010

Matrix isolation IR studies, together with DFT calculations, have established that the co-condensation of molecular SiO and GeO in low temperature (12 K) nitrogen matrices leads to the formation of the novel silicon germanium oxide species SiGeO(2), Si(2)GeO(3) and SiGe(2)O(3) analogous to the known dimer and trimer species M(2)O(2) and M(3)O(3) (M = Si, Ge). Controlled diffusion studies in the temperature range 20-34 K result in a significant increase in trimer formation, which implies a very low activation energy for this oligomerisation step. Characteristic IR modes are assigned for all three novel mixed oxide molecules, and the DFT calculations establish that these species have cyclic C…

StereochemistryMatrix isolation new molecular species DFTMatrix isolationOxideGeneral Physics and AstronomyTrimerActivation energyAtmospheric temperature rangechemistry.chemical_compoundchemistryMoleculePhysical chemistryMixed oxidePhysical and Theoretical ChemistryGermanium oxidePhysical chemistry chemical physics : PCCP
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Rotational Isomerism in Acetic Acid: The First Experimental Observation of the High-Energy Conformer

2003

The high-energy conformer of acetic acid (cis-AA) is produced in an Ar matrix by vibrational excitation of the OH stretching overtone of the ground conformational state (trans-AA). IR-absorption spectroscopy provides a clear identification of the reaction product. cis-AA converts back to trans-AA in a time scale of minutes at 8 K by tunneling. http://dx.doi.org/10.1021/ja038341a

StereochemistryOvertoneMolecular ConformationInfrared spectroscopy010402 general chemistry01 natural sciencesBiochemistryCatalysisAcetic acidchemistry.chemical_compoundColloid and Surface ChemistryIsomerismAb initio quantum chemistry methods0103 physical sciencesSpectroscopy Fourier Transform InfraredSpectroscopyConformational isomerismAcetic Acid010304 chemical physicsChemistryMatrix isolationGeneral Chemistry3. Good health0104 chemical sciencesKineticsModels ChemicalPhysical chemistryExcitation
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Clerodane diterpenoids from Salvia splendens.

2006

Four new clerodane diterpenoids, salvisplendins A-D (1-4), have been isolated from an acetone extract of the flowers of SalVia splendens, together with an artifact (5), arising from salvisplendin D (4) by addition of diazomethane, and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and, in the case of salvisplendin A (1), by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6), not published hitherto, are also reported.

StereochemistryPharmaceutical ScienceFlowersSalviaAnalytical ChemistryDiterpenes Clerodanechemistry.chemical_compoundFour new clerodane diterpenoids salvisplendins A-D (1-4) have been isolated from an acetone extract of the flowers of SalVia splendens together with an artifact (5) arising from salvisplendin D (4) by addition of diazomethane and the already known clerodane olearin (6). The structures of the new compounds (1-5) were established mainly by 1D and 2D NMR spectroscopic studies and in the case of salvisplendin A (1) by chemical correlation with splenolide B (7). Complete 1H and 13C NMR assignments for olearin (6) not published hitherto are also reportedDrug DiscoveryOrganic chemistrySalviaNuclear Magnetic Resonance BiomolecularPharmacologychemistry.chemical_classificationPlants MedicinalbiologyMolecular StructureChemistryDiazomethaneOrganic ChemistryCarbon-13 NMRbiology.organism_classificationChemical correlationTerpenoidComplementary and alternative medicineItalyMolecular MedicineDiterpeneTwo-dimensional nuclear magnetic resonance spectroscopyLactoneJournal of natural products
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Does the addition of single joint exercises to a resistance training program improve changes in performance and anthropometric measures in untrained …

2018

The present study compared changes in muscle performance and anthropometric measures in young men performing resistance training (RT) programs composed of only multi joint (MJ) exercises, or with the addition of single joint (SJ) exercises (MJ+SJ). Twenty untrained men were randomized to MJ or MJ+SJ groups for 8 weeks. Both groups performed the same MJ exercises. The difference was that the MJ+SJ group added SJ exercises for upper and lower limbs. Participants were tested for 10 repetitions maximum (10RM), flexed arm circumference, and biceps and triceps skinfolds. Both groups significantly increased 10RM load for the bench press (MJ 38.5%, MJ+SJ 40.1%), elbow extension (MJ 28.7%, MJ+SJ 31.…

Strength traininglcsh:MedicineBench pressBicepslcsh:QM1-69503 medical and health sciences0302 clinical medicineMedicineOrthopedics and Sports MedicineTraining volumeIsolation exerciseLeg pressMolecular BiologyMulti jointbusiness.industrylcsh:RSignificant differenceResistance traininglcsh:Human anatomy030229 sport sciencesCell BiologyAnthropometryExercise selectionExercise selection; Isolation exercise; Muscle hypertrophy; Strength training; Training volume; Neurology (clinical); Orthopedics and Sports Medicine; Cell Biology; Molecular BiologyMuscle hypertrophyNeurology (clinical)Strength trainingbusinessNuclear medicine030217 neurology & neurosurgeryEuropean Journal of Translational Myology
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Diagnosis of inverter-fed induction motors in short time windows using physics-assisted deep learning framework

2019

This article presents a framework for accurate fault diagnostics in inverter-fed induction machinery operating under variable speed and load conditions within very short time windows. Condition indicators based on fault characteristic frequencies observed over the extended Park's vector modulus are fused with deep features extracted using stacked autoencoders to generate a multidimensional feature space for fault classification using support vector machine. The proposed approach is demonstrated in a laboratory setup to detect the most commonly occurring faults, namely, the stator turns fault, broken rotor bars fault and bearing fault with an accuracy > 98% within a short time window of 2–3 …

Support vector machineBearing (mechanical)Control theorylawRotor (electric)StatorFeature vectorFault (power engineering)Fault detection and isolationInduction motorlaw.invention2019 IEEE 12th International Symposium on Diagnostics for Electrical Machines, Power Electronics and Drives (SDEMPED)
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Hybridization in Calopteryx damselflies: the role of males

2008

Females are often considered responsible for hybridization between two species because usually they are the choosier sex and their cooperation is needed for successful copulation. However, males can also be responsible for hybridization, for example in species in which males are able to force copulation. We studied the pattern of hybridization in two congeneric damselfly species, Calopteryx splendens and Calopteryx virgo, and provide evidence that F1 hybrids between the two damselfly species occur in the wild. According to mitochondrial DNA analysis, hybridization is reciprocal: five of seven hybrids were sired by C. splendens and two by C. virgo males. We conducted an experiment that revea…

SympatryMitochondrial DNAbiologyEcologyZoologyReproductive isolationbiology.organism_classificationOdonataRAPDDamselflyCalopterygidaeAnimal Science and ZoologyEcology Evolution Behavior and SystematicsHybridAnimal Behaviour
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Species-specific sex pheromones secreted from new sexual glands in two sympatric fungus-growing termites from northern Vietnam, Macrotermes annandale…

2004

Reproductive isolation in termites is not well known. Our study carried out on two sympatric species from northern Vietnam, Macrotermes annandalei and M. barneyi, showed that dispersal flights and sex pheromones were two important factors in their reproductive isolation. These fungus-growing termites were isolated, partially due to the timing of their respective dispersal flights. M. annandalei flew the first day after rain, while the flights of M. barneyi occurred the second day after rain. However, the flights can also be simultaneous in the two species. Sex pheromones of M. annandalei and M. barneyi were shown to be species-specific. In both species, they were secreted by females from tw…

SympatryTermitidaeCourtship displayEcologySympatric speciationInsect ScienceSex pheromonePheromoneBiological dispersalReproductive isolationBiologybiology.organism_classificationEcology Evolution Behavior and SystematicsInsectes Sociaux
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Ecological differentiation and reproductive isolation of two closely related sympatric species of Oenanthe (Apiaceae)

2010

Oenanthe conioides is a lower Elbe endemic plant species growing in the freshwater tidal zone around Hamburg (Germany). Its closest relative Oenanthe aquatica is widely distributed in Eurasia and grows in calm and shallow freshwater. The two species differ in habitat requirements but are otherwise sympatrically distributed, suggesting that ecological divergence has to be maintained in the face of gene flow. In the present study, we investigated ecological differentiation and reproductive isolation in these two species. An amplified fragment length polymorphism analysis found clear genetic differentiation between the two species implying reproductive isolation. A reciprocal transplantation e…

SympatryTransplantationSpecies complexHabitatEcological selectionSympatric speciationEcologyIntroduced speciesReproductive isolationBiologyEcology Evolution Behavior and SystematicsBiological Journal of the Linnean Society
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What do we need to know about speciation?

2011

Speciation has been a major focus of evolutionary biology research in recent years, with many important advances. However, some of the traditional organising principles of the subject area no longer provide a satisfactory framework, such as the classification of speciation mechanisms by geographical context into allopatric, parapatric and sympatry classes. Therefore, we have asked where speciation research should be directed in the coming years. Here, we present a distillation of questions about the mechanisms of speciation, the genetic basis of speciation and the relationship between speciation and diversity. Our list of topics is not exhaustive; rather we aim to promote discussion on rese…

SympatrybiologyECOLOGICAL SPECIATIONHeteropatric speciationPOPULATION-SIZEDROSOPHILA-PSEUDOOBSCURAAllopatric speciationPOSTZYGOTIC ISOLATIONIncipient speciationParapatric speciationbiology.organism_classificationSEXUAL SELECTIONEcological speciationDrosophila pseudoobscuraADAPTIVE EVOLUTIONSpecies SpecificityEvolutionary biologyHYBRID INCOMPATIBILITIESGenetic algorithmGeneticsGENE FLOWDOBZHANSKY-MULLER INCOMPATIBILITIESREPRODUCTIVE ISOLATIONEcology Evolution Behavior and SystematicsTrends in Ecology and Evolution
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