Search results for " isolation"
showing 10 items of 374 documents
2021
FTIR spectroscopy was combined with the matrix isolation technique and quantum chemical calculations with the aim of studying complexes of isocyanic acid with sulfur dioxide. The structures of the HNCO⋯SO2 complexes of 1:1, 1:2 and 2:1 stoichiometry were optimized at the MP2, B3LYPD3, B2PLYPD3 levels of theory with the 6-311++G(3df,3pd) basis set. Five stable 1:1 HNCO⋯SO2 complexes were found. Three of them contain a weak N-H⋯O hydrogen bond, whereas two other structures are stabilized by van der Waals interactions. The analysis of the HNCO/SO2/Ar spectra after deposition indicates that mostly the 1:1 hydrogen-bonded complexes are present in argon matrices, with a small amount of the van de…
Anharmonic Vibrational Spectrum and Experimental Matrix Isolation Study of Thioformic Acid Conformers -- Potential Candidates for Molecular Cloud and…
2021
Thioformic acid (TFA) is the sulfur analog of formic acid, the simplest organic acid. It has three analogues HCOSH, HCSOH, and HCSSH, each of them having two rotational isomeric (rotameric) forms: trans and cis where the trans form is energetically more stable. In this article, we study computational energetics and anharmonic vibrational spectrum of TFA including overtone and combination vibrations. We also studied experimental photoisomerization and photodecomposition channels of HCOSH molecules with different wavelengths. We suggest that TFA is a potential sulfur containing candidate molecule for interstellar and planetary observations and discuss these in a light of different radiation e…
On the design of a multiple-output DC/DC converter for the PHI experiment on-board of solar orbiter
2013
Power converters for experiments that have to fly on board space missions (satellite, launchers, etc.) have very stringent requirements due to its use in a very harsh environment. The selection of a suitable topology is therefore not only based on standard requirements but additional more strict ones have also to be fulfilled. This work shows the design procedure followed to build the Power Converter Module (PCM) for the Polarimetric and Helioseismic Imager (SO/PHI), experiment on board the Solar Orbiter Satellite. The selected topology has been a Push-Pull, for a power level of approximately 35 W and with seven output voltages. Galvanic isolation is needed from primary to secondary, but no…
Detecting Eccentricity and Demagnetization Fault of Permanent Magnet Synchronous Generators in Transient State
2019
Eccentricity and demagnetization fault of a four-pole 1.5 kW surface mounted permanent-magnet synchronous-generator (PMSG) were modelled by using time-discretised finite element analysis (FEA). Both fault types are caused by magnetic asymmetry in the generator. The faulty behaviour of a PMSG under transient operating condition is studied with FEA. Two search coils were wound around stator teeth on opposite sides of the rotor. The induced voltage from these coils will be equal in healthy case. A fault is detected when the induced voltages are non-identical. The simulation results revealed that the envelope of the induced search coil voltage had sinusoids during dynamic eccentricity and demag…
Optimum core dimension for minimizing proximity effect losses of an AC inductor for a galvanically isolated PV inverter
2012
In this paper, it is shown how winding proximity effect losses in an existing AC inductor can be reduced without changing the actual winding. Instead, the core dimensions are changed with significant effects. For this purpose, Maxwell (ANSOFT) electromagnetic software package is used to investigate flux patterns and their influence on eddy current losses in the windings. Various core dimensions are analyzed with respect to flux patterns, and a design where the flux encloses a minimum number of winding layers is found. This significantly reduces the high frequency resistance of the windings up to 62.2% in comparison with the original design. The results are also explained in terms of the win…
A compact system for high precision time measurements ( < 14 ps RMS) and integrated data acquisition for a large number of channels
2011
A high precision ( < 14 ps RMS time resolution) and high channel density ( ~ 256 channels) Time to Digital Converter (TDC) module (realized in FPGAs) with integrated DAQ is presented. The data is transported over up to 8 Gigabit-Ethernet or optical links with up to 3 Gb/s. Slow-Control information is transported over the same links. It can be attached directly to the detector, which allows the elimination of long cables and crate systems. The full 256 channel TDCs are expected to use approximately 30 W electrical power. The module size is 20 cm by 23 cm. Power is provided by a galvanically isolated 48 V low noise power supply. AddOn-boards adapt to the special needs of the detector to be re…
Hyperspectral image classification using CNN: Application to industrial food packaging
2021
Abstract During food tray packaging, some contamination may exist due to the presence of undesired objects. It is essential to detect anomalies during the packaging process in order to discard the faulty tray and avoid human consumption. This study demonstrates the on-line classification feasibility when using hyperspectral imaging systems for real-time food packaging control by using Convolutional Neural Networks (CNN) as a classifier in heat-sealed food trays. A hyperspectral camera is used to capture individual food tray information and fed to a CNN classifier to detect faulty food trays with object contamination. The proposed system is able to detect up to eleven different contamination…
COVID-19, A new challenge in the dental practice
2021
Background This review was conducted in order to learn the latest information about how to prevent cross-infection of COVID-19 in dentistry. The aim of this study is offer a clinical protocol to reduce the risk of infection of COVID-19 in dental settings. Material and methods We carried out a review based on the PRISMA guide (Preferred Reporting Items for Systematic Reviews and Meta-Analyses). We used the following three databases: PubMed, Embase and Scopus. The search strategy was performed in the three databases applying the search terms "COVID-19 AND dental", "COVID-19 AND dentistry", selecting human studies published from November 2019 to May 2020. English publications regarding COVID-1…
Social isolation and depression predict 12-month outcomes in the "waiting for a new heart study".
2009
Identification of modifiable psychosocial characteristics related to survival of heart transplant (HTx) candidates is needed to prevent clinical deterioration and improve prognosis.A multi-site, prospective study was conducted with 318 HTx candidates (18% female, 82% male; 53 +/- 11 years of age) newly listed at 17 hospitals in Germany and Austria. Baseline demographic and psychosocial characteristics were assessed by questionnaires. Indicators of disease severity (Heart Failure Survival Score, creatinine, cardiac index) and 12-month outcomes (death, high-urgency HTx, elective HTx, de-listing due to deterioration or improvement) were provided by Eurotransplant.By 12 months, 33 patients died…