Search results for " kinetic"
showing 10 items of 416 documents
Molecular determinants of large cargo transport into the nucleus
2020
Nucleocytoplasmic transport is tightly regulated by the nuclear pore complex (NPC). Among the thousands of molecules that cross the NPC, even very large (>15 nm) cargoes such as pathogens, mRNAs and pre-ribosomes can pass the NPC intact. For these cargoes, there is little quantitative understanding of the requirements for their nuclear import, especially the role of multivalent binding to transport receptors via nuclear localisation sequences (NLSs) and the effect of size on import efficiency. Here, we assayed nuclear import kinetics of 30 large cargo models based on four capsid-like particles in the size range of 17–36 nm, with tuneable numbers of up to 240 NLSs. We show that the requireme…
A theoretical study of the gas-phase chemi-ionization reaction between uranium and oxygen atoms
2005
The U+O chemi-ionization reaction has been investigated by quantum chemical methods. Potential-energy curves have been calculated for several electronic states of UO and UO+. Comparison with the available spectroscopic and thermodynamic values for these species is reported and a mechanism for the chemi-ionization reaction U+O -> UO++e(-) is proposed. The U+O and Sm+O chemi-ionization reactions are the first two metal-plus-oxidant chemi-ionization reactions to be studied theoretically in this way.
Effect of relativistic kinematics on the stability of multiquarks
2021
We discuss whether the bound nature of multiquark states in quark models could benefit from relativistic effects on the kinetic energy operator. For mesons and baryons, relativistic corrections to the kinetic energy lead to lower energies, and thus call for a retuning of the parameters of the model. For multiquark states, as well as their respective thresholds, a comparison is made of the results obtained with non-relativistic and relativistic kinetic energy. It is found that the binding energy is lower in the relativistic case. In particular, $QQ\bar q\bar q$ tetraquarks with double heavy flavor become stable for a larger ratio of the heavy to light quark masses; and the all-heavy tetraqua…
Non-isothermal crystallization kinetics of PET
2000
The crystallization kinetics of poly(ethylene terephthalate) was studied using constant cooling rate, isothermal and quenching experiments. A non-isothermal crystallization kinetics equation based on a single mechanism was used to analyze the data. Different mechanisms of crystallization at low, intermediate, and high cooling rates were hypothesized based on deviation of the experimental data from the single mechanism model.
Modeling the interactions between light and crystallizing polymer during fast cooling
2004
In this work, an experimental set-up able to quench thin polymer films whilst recording the sample thermal history as well as the overall and depolarized light intensities of a laser beam emerging from the sample is described. The interactions between the light beam and the crystallizing material have been modeled accounting for absorption and scattering phenomena. The proposed model was found to be able to reproduce the ex- perimentally observed behavior of light intensities and it was validated by comparison with conventional DSC analysis. On the basis of this model, a method to obtain crystallinity evo- lution is proposed and applied to some fast cooling runs. The method was applied to q…
Trap Spectroscopy by the Glow Rate Technique using Bleaching of Colour Centres
2002
An application of the glow rate technique (GRT) for analysis of the parameters of thermostimulated decay of colour centres is presented using the data on the decay of radiation defects in LiBaF 3 :Fe crystals created by X rays at 300 K. The GRT offers a procedure for evaluation of the mean activation energy as a function of temperature in the case of arbitrary thermostimulated relaxation kinetics represented by the trap distribution function. The experimental procedure involves at least two subsequent measurements of thermostimulated decay kinetics at different heating rates. It is shown that the decay of the F type centres is governed by interaction of mobile anion vacancies with F A and F…
Modeling Rainfall Erosivity by Measured Drop-Size Distributions
2015
AbstractThe study of the detachment of soil particles due to rainfall erosivity requires knowledge of the energetic characteristics of the precipitation. In this paper, following a review of both the drop-size distribution (DSD) proposed by one researcher and the corresponding relationship for evaluating the kinetic power of rainfall, the reliability of that researcher’s DSD using the size distributions of raindrops detected by an optical disdrometer installed at Palermo (Sicily) is experimentally tested. Finally, an experimental verification of both the relationship proposed by two separate research teams for evaluating the specific and unit rainfall kinetic energy is carried out.
A Check of Water Drop Impact Effects on Surface Soil Saturated Hydraulic Conductivity
2020
The post-tillage dynamics of the surface soil saturated hydraulic conductivity, Ks, was studied at the Masse experimental station (central Italy, silty-clay-loam soil). A sequence of experiments was performed by rainfall simulation on two replicated micro-plots (width 1 m, length 0.92 m, slope 16%) established on bare soil. Each high-intensity rainfall simulation was preceded by a low-intensity wetting phase. The soil water content, w, was measured before wetting and both before and after simulation. Runoff was measured at 5 min intervals. The infiltration rate was calculated as the difference between rainfall intensity and runoff rate. Finally, Ks was assumed to be equal to the infiltratio…
Kinetic Study of the Oxidation of n-Butane on Vanadium Oxide Supported on Al/Mg Mixed Oxide
1997
The reaction kinetics of the oxidative dehydrogenation (ODH) of n-butane over vanadia supported on a heat-treated Mg/Al hydrotalcite (37.3 wt % of V2O5) was investigated by both linear and nonlinear regression techniques. A reaction network including the formation of butenes (1-, 2-cis-, and 2-trans-butene), butadiene, and carbon oxides by parallel and consecutive reactions, at low and high n-butane conversions, has been proposed. Langmuir−Hinshelwood (LH) models can be used as suitable models which allows reproduction of the global kinetic behavior, although differences between oxydehydrogenation and deep oxidation reactions have been observed. Thus, the formation of oxydehydrogenation pro…
Initial reaction steps in the condensed-phase decomposition of propellants
2002
Understanding the reaction mechanisms for the decomposition of NO2-containing energetic materialsin the condensed phase is critical to our development of detailed kinetic models of these energetic materials in propellant combustion. To date, the reaction mechanisms in the condensed phase have been represented by global reactions. The detailed elementary reactions subsequent to the initial NO2 bond scissioning are not known. Using quantum chemical calculations, we have investigated the possible early steps in the decomposition of energetic materials that can occur in the condensed phase. We have used methylnitrate, methylnitramine, and nitroethane as prototypes for O−NO2, N−NO2 and C−NO2 nit…