Search results for " layer"

Hybrid Organic-Inorganic Nanostructures Fabricated from Layer-by-Layer Self-Assembled Multilayers of Hyperbranched Polyglycerols and Phosphorus Dendr…

2007

Multilayer thin films of cationic phosphorous dendrimers and anionic hyperbranched polyglycerols were fabricated by electrostatic layer-by-layer (LbL) self-assembly (SA). The film formation was monitored by surface plasmon resonance (SPR) spectroscopy and UV-visible spectroscopy, and it was found that the stepwise, alternating deposition results in a linear growth up to four bilayers. Hybrid organic-TiO2 nanostructures were generated by exposing the supramolecular multilayers to TiCl4 precursors. The amounts of TiO2 incorporated inside the scaffolds could be tuned by controlling the porosity of the multilayers with the addition of a small amount of salts. The resulting hybrid films exhibit …

Modeling of anisotropic grain growth in minerals

2001

The role of surface energy anisotropy during grain growth is investigated using both physical experiments on octachloropropane and numerical experiments using the Elle microstructural modelling system. In particular the effects of anisotropy on growth rates, grain shapes and lattice preferred orientations are analysed. Anisotropic growth in thin polycrystalline sheets of octachloropropane is found to systematically remove certain c-axis orientations from the sample, without obviously modifying the grain shapes. By comparison with equivalent numerical experiments, we can explain these observations with a simple boundary layer model that treats each side of each grain boundary as an independe…

Advances in Design, Simulation and Manufacturing IV

2021

This book reports on topics at the interface between mechanical and chemical engineering, emphasizing design, simulation, and manufacturing. Specifically, it covers recent developments in the mechanics of solids and structures, numerical simulation of coupled problems, including fatigue, fluid behavior, particle movement, pressure distribution. Further, it reports on developments in chemical process technology, heat and mass transfer, energy-efficient technologies, and industrial ecology. Based on the 4th International Conference on Design, Simulation, Manufacturing: The Innovation Exchange (DSMIE-2021), held on June 8-11, 2021, in Lviv, Ukraine, this second volume of a 2-volume set provide…

Group analysis and similarity solutions of the compressible boundary layer equations

1989

In this paper the application of Lie's methods to the equations of the laminar boundary layer is discussed. The momentum and energy equations in Prandtl's form are considered for a steady, viscous, compressible laminar flow with non zero pressure gradient, variable viscosity and thermal conductivity. Group analysis yields similarity solutions for given pressure distributions and particular values of the invariance group parameters (group classification). Crocco's transformation is obtained for the infinite-dimensional group of the Lie's algebra admitted by the equations.

Somatic embryogenesis and plant regeneration from pistil transverse thin cell layers of lemon (Citrus limon)

2008

Callus induction, somatic embryogenesis and plant regeneration were obtained in Citrus limon (L.) Burm. (cv. Femminello) from cultures of pistil transverse thin cell layer explants [(t)TCLs]. Explants were cultured on two different media, based on Murashige and Skoog salts and vitamins, supplemented with 500 mg l-1 malt extract (MSI), or 500 mg l-1 malt extract and 13.3 ¼M 6-benzylaminopurine (MSII). Sucrose (146 mM) was used as carbon source. Somatic embryos appeared 3 months after culture initiation from stigma and style (t)TCLs; they were observed at the surface of the (t)TCL-derived callus. Although ovary (t)TCLs showed the highest callus formation, they never differentiated somatic emb…

Severe Pollution in China Amplified by Atmospheric Moisture

2017

AbstractIn recent years, severe haze events often occurred in China, causing serious environmental problems. The mechanisms responsible for the haze formation, however, are still not well understood, hindering the forecast and mitigation of haze pollution. Our study of the 2012–13 winter haze events in Beijing shows that atmospheric water vapour plays a critical role in enhancing the heavy haze events. Under weak solar radiation and stagnant moist meteorological conditions in winter, air pollutants and water vapour accumulate in a shallow planetary boundary layer (PBL). A positive feedback cycle is triggered resulting in the formation of heavy haze: (1) the dispersal of water vapour is cons…

Mapping of activation frequencies during ventricular fibrillation in isolated perfused healthy human heart

2013

Development and Study of a Micromegas Pad-Detector for High Rate Applications

2015

In this paper, the design and the performance of two prototype detectors based on Micromegas technology with a pad readout geometry is discussed. In addition, two alternative implementations of a spark-resistent protection layer on top of the readout pads have been tested to optimize the charge-up behavior of the detector under high rates. The prototype detectors consist of 500 pads with a size of 5x4 mm, each connected to one independent readout channel, and cover an active area of 10x10 cm. The design of these prototypes and its associated readout infrastructure was developed in such a way that it can be easily adapted for large-size detector concepts.

Optimization of ZnO:Al/Ag/ZnO:Al structures for ultra-thin high-performance transparent conductive electrodes

2012

Al-doped ZnO (AZO)/Ag/AZO multilayer coatings (50-70 nm thick) were grown at room temperature on glass substrates with different silver layer thickness, from 3 to 19 nm, by using radio frequency magnetron sputtering. Thermal stability of the compositional, optical and electrical properties of the AZO/Ag/AZO structures were investigated up to 400 °C and as a function of Ag film thickness. An AZO film as thin as 20 nm is an excellent barrier to Ag diffusion. The inclusion of 9.5 nm thin silver layer within the transparent conductive oxide (TCO) material leads to a maximum enhancement of the electro-optical characteristics. The excellent measured properties of low resistance, high transmittanc…

In-situ annealing characterization of atomic-layer-deposited Al2O3 in N2, H2 and vacuum atmospheres

2019

Tarkista embargo, kun artikkeli julkaistu. Atomic-layer-deposited Al 2 O 3 films can be used for passivation, protective, and functional purposes in electronic devices. However, as-deposited, amorphous alumina is susceptible to chemical attack and corrosion during manufacturing and field-use. On the contrary, crystalline Al 2 O 3 is resistant against aggressive chemical treatments and corrosion. Here, high-temperature treatments in N 2 , H 2 , and vacuum were used to crystallize alumina which exhibited different crystalline phases. The annealing process was monitored continuously in situ by measuring the film temperature and surface reflectance to understand the crystallization kinetics. Ex…