Search results for " light"

Synthesis, characterization and study of covalently modified triazole LAPONITE® edges

2020

Abstract LAPONITE® (Lap) clay mineral was successful functionalized by triazole groups in a two steps procedure. First, the Lap edges were modified with 3-azidopropyltrimethoxysilane by traditional heating and microwave irradiation. Microwave irradiation allowed us to obtain high loading onto the Lap edges in lower times compared to those obtained through conventional method. Afterwards, the triazole moieties were obtained by reaction between azido functionalized Lap and propargyl alcohol. The successful functionalization of Lap was proved by thermogravimetric analysis, FT-IR spectroscopy, dynamic light scattering and ζ-potential measurements. Finally, the effects of the surface modificatio…

Modification of calix[4]arenes with CMPO-functions at the wide rim. Synthesis, solution behavior, and separation of actinides from lanthanides

2003

Two calix[4]arene tetraethers (Y = C5H11, C14H29) bearing on their wide rim four –N(Me)–CO–CH2–P(O)Ph2 residues were synthesized for the first time. Their ability to extract lanthanides and actinides from an acidic aqueous phase to organic phases (CH2Cl2, NPHE) was studied. In comparison to the corresponding –NH-analogs, they are less efficient extractants, the selectivity for the light over the heavy lanthanides is less pronounced, while there is still an interesting selectivity of Am3+ over Eu3+. Stability constants for selected lanthanide salts were determined also in homogenous phase (methanol, acetonitrile) but do not account for the different extraction results. The complexation of Gd…

Multicolor upconversion luminescence of GdVO4:Ln3+/Yb3+ (Ln3+ = Ho3+, Er3+, Tm3+, Ho3+/Er3+/Tm3+) nanorods

2016

Lanthanide-doped GdVO4 nanorods that exhibit upconversion emission under 982 nm excitation have been prepared by a facile room-temperature chemical co-precipitation method followed by a subsequent annealing at temperatures of 600 degrees C, 800 degrees C and 1000 degrees C. Multicolor upconversion emission, including white, was achieved by tuning the concentrations of dopant lanthanide ions (Ho3+, Er3+, Tm3+ and Yb3+) in GdVO4. It is found that four GdVO4 samples emit light with the white chromaticity coordinates of (0.326, 0.339), (0.346, 0.343), (0.323, 0327) and (0.342, 0.340) respectively, under a single-wavelength NIR excitation. These coordinates are very close to the standard equal e…

Search for superheavy elements in monazites using chemical enrichment

1982

Evidence for the existence of superheavy elements in monazite inclusions embedded in Madagascan mica and surrounded by giant radioactive haloes was given by Gentry et al.1 who observed photons with energies corresponding to predicted Lα1 X-ray energies of element 126 (at 27.25 keV) and also of elements 116, 124 and 127 in irradiations of such crystals with collimated proton beams. For an unambiguous identification, the detection of further members of the L X-ray series would be most important. In X-ray spectra of monazite samples these transitions are buried under the strong K X-ray peaks of the lanthanide elements. They should, however, become visible after chemical enrichment of the super…

Distillation and stripping pilot plants for the JUNO neutrino detector: Design, operations and reliability

2019

Abstract This paper describes the design, construction principles and operations of the distillation and stripping pilot plants tested at the Daya Bay Neutrino Laboratory, with the perspective to adapt these processes, system cleanliness and leak-tightness standards to the final full scale plants to be used for the purification of the liquid scintillator of the JUNO neutrino detector. The main goal of these plants is to remove radio impurities from the liquid scintillator while increasing its optical attenuation length. Purification of liquid scintillator will be performed with a system combining alumina oxide, distillation, water extraction and steam (or N 2 gas) stripping. Such a combined…

Generation of Structured Light via Nano Structures and Applications

2020

The generation of structured light by means of metasurfaces is presented and the applications in the characterizations of polarization rotation and Pancharatnam-Berry phase are discussed.

Humanities and Social Sciences Latvia, Vol. 26, N 1 (Spring-Summer)

2018

An Improved Empirical Relation to Determine the Particle Number Density of Fluid-Like Ordered Charge-Stabilized Suspensions

2001

Polystyrene as an archetypal charge-stabilized colloid model system was used in this work under well defined preparation conditions. A continuous preparation technique was used to control the suspension parameters salt concentration c and particle number density n. Measurements of n were performed using both conductivity in the completely deionized state and static light scattering. We found a significant deviation between the position of the first maximum of the static structure factor qmax=2π/L and an estimate identifying the relevant length scale L with the average inter-particle distance d¯=n−1/3. Instead, qmax was observed to follow the relation qmax=(2.20±0.03)π/d¯, which is equivalen…

Highly Stable Red-Light-Emitting Electrochemical Cells

2017

The synthesis and characterization of a series of new cyclometalated iridium(III) complexes [Ir(ppy) 2 (N ∧ N)][PF 6 ] in which Hppy = 2-phenylpyridine and N ∧ N is (pyridin-2-yl)benzo[ d ]thiazole ( L1 ), 2-(4-( tert -butyl)pyridin-2-yl)benzo[ d ]thiazole ( L2 ), 2-(6-phenylpyridin-2-yl)benzo[ d ]thiazole ( L3 ), 2-(4-( tert -butyl)-6-phenylpyridin-2-yl)benzo[ d ]thiazole ( L4 ), 2,6-bis(benzo[ d ]thiazol-2-yl)pyridine ( L5 ), 2-(pyridin-2-yl)benzo[ d ]oxazole ( L6 ), or 2,2′-dibenzo[ d ]thiazole ( L7 ) are reported. The single crystal structures of [Ir(ppy) 2 ( L1 )][PF 6 ]·1.5CH 2 Cl 2 , [Ir(ppy) 2 ( L6 )][PF 6 ]·CH 2 Cl 2 , and [Ir(ppy) 2 ( L7 )][PF 6 ] have been determined. The new com…

Light intensity preference of juvenile pikeperch Sander lucioperca (L.)

2006

Light intensity preference of the pikeperch was tested in 1-m2 tanks divided into four lateral compartments with a hole in the middle to allow the fish to move between compartments. Two experiments were carried out with both 0+ and 1+ pikeperch: one testing intensities from 25 to 300 lx and the other from 1 to 50 lx. Light preference was observed individually for 5 days at 8, 11, 14 and 17 h. On the first and fifth day, the preference was tested without differences in light intensity (control). In both experiments, both age groups showed preference for the lowest available light intensity. Preference for low light intensity in pikeperch may be related to innate activity and feeding behaviou…