Search results for " metal"
showing 10 items of 2159 documents
Alkali-Metal Azides Interacting with Metal–Organic Frameworks
2013
“Il Chisciotte in Spanglish tra riscrittura metatestuale e meticciamento metalinguistico: la sfida di Ilan Stavans".
2007
In un placete de La Mancha of which nombre no quiero remembrearme, vivía, not so long ago, uno de esos gentlemen… Così recita l’incipit del primo ed unico capitolo del Don Chisciotte, tradotto in Spanglish da Ilan Stavans con il titolo di Don Quixote de La Mancha. Lo Spanglish è un portmanteau dei termini Spanish (spagnolo) e English (Inglese), apparso per la prima volta tra il 1965 e il 1970 ed usato per riferirsi ad un fenomeno di contatto linguistico tipico, principalmente, della popolazione ispana in USA, la quale è esposta, parimenti, allo spagnolo e all’inglese. Lo Spanglish è il prodotto dell’interazione linguistica di comunità bilingue, si pensi a quelle stanziate presso il confine …
Effect of agricultural practices on soil microbial communities
2008
Soil carbon sequestration is an important and immediate sink for removing atmospheric carbon dioxide and slowing global warming. Agricultural practices strongly impact CO2 emission from the soil and the loss of soil organic matter is lower when “no-till” agriculture is practiced. The present work was performed in order to investigate effects of different agricultural practices on soil microbial communities. Field experiments took place at three Italian locations strongly differing in pedological, chemical and climatic characteristics: Naples, Turin and Piacenza. Soils were subjected to four management practices such as traditional (TRA), minimum tillage (MIN) and amendments with compost (CO…
Polymorphism and Metallic Behavior in BEDT-TTF Radical Salts with Polycyano Anions
2012
Up to five different crystalline radical salts have been prepared with the organic donor BEDT-TTF and three different polynitrile anions. With the polynitrile dianion tcpd2− (=C[C(CN)2]32−), two closely related radical salts: α'-(ET)4tcpd·THF (1) (THF = tetrahydrofurane) and α'-(ET)4tcpd·H2O (2) have been prepared, depending on the solvent used in the synthesis. With the mono-anion tcnoetOH− (=[(NC)2CC(OCH2CH2OH)C(CN)2]−) two polymorphs with similar physical properties but different crystal packings have been synthesized: θ-(ET)2(tcnoetOH) (3) and β''-(ET)2(tcnoetOH) (4). Finally, with the mono-anion tcnoprOH− (=[(NC)2CC(OCH2CH2CH2OH)C(CN)2]−) we have prepared a metallic…
A magnetic look into the protecting layer of Au25 clusters
2016
The field of molecular metal clusters protected by organothiolates is experiencing a very rapid growth. So far, however, a clear understanding of the fine interactions between the cluster core and the capping monolayer has remained elusive, despite the importance of the latter in interfacing the former to the surrounding medium. Here, we describe a very sensitive methodology that enables comprehensive assessment of these interactions. Pulse electron nuclear double resonance (ENDOR) was employed to study the interaction of the unpaired electron with the protons of the alkanethiolate ligands in four structurally related paramagnetic Au25(SR)0 18 clusters (R ¼ ethyl, propyl, butyl, 2-methylpro…
Molecular nanostructures on ferromagnetic metals for spintronics
2017
El objetivo principal de esta tesis ha sido el estudio de la funcionalización de superficies ferromagnéticas mediante la formación de monocapas moleculares autoensambladas, (SAMs, self-assembled monolayers) con el fin de conseguir procesos sencillos y fiables para la preparación de interfaces híbridas aplicables en dispositivos de espintrónica molecular. La investigación se ha centrado en la funcionalización de materiales ferromagnéticos, concretamente el cobalto y la aleación de níquel:hierro conocida como Permalloy. Las propiedades magnéticas y de polarización de espín de estos metales ferromagnéticos se mantienen a temperatura ambiente, lo que los hace muy interesantes para su aplicación…
Concentrations of metallothionein in the bivalve molluscsAnodonta spp.andUnio spp.from Latvian lakes with different anthropogenic pressure
2013
Concentrations of metallothioneins (MT) were analysed in bivalve molluscs Anodonta spp. and Unio spp. from 6 lakes and watercourses of Latvia with different anthropogenic pressure. The aim of the study was to find the relationship between MT in molluscs and concentrations of heavy metals in sediments. Unio spp. and Anodonta spp. showed no significant differences in the concentrations of MT. High concentrations of heavy metals (Cd, Pb, Hg, Cu, Zn) were detected in the deepest parts of polluted water bodies, however their concentrations significantly decreased in near shore sediments inhabited by molluscs. Only Zn tends to accumulate in the molluscs, reaching 2-7 times higher concentrations i…
Comparison of Exposure Techniques and Vitality Assessment of Mosses in Active Biomonitoring for Their Suitability in Assessing Heavy Metal Pollution …
2021
The most widespread and used technique is the moss-bag method in active biomonitoring of air pollution using mosses. In the literature, we can find various studies on the standardization of this method, including attempts to standardize treatments and preparation procedures for their universal application. Few works comprehensively focus on other methods or compare other techniques used in active biomonitoring with mosses, especially including measurements of their vital parameters. Our experiment aimed to assess air pollution by selected heavy metals (Cu, Zn, Cd, Pb, Mn, Fe, and Hg) using three moss species (Pleurozium schreberi, Sphagnum fallax, and Dicranum polysetum) during a 12-week ex…
Bioaccumulation of Trace Elements from Aqueous Solutions by Selected Terrestrial Moss Species
2022
The interrelationship between metal concentrations in mosses and their surroundings prompts research toward examining their accumulation properties, as it is particularly important for their usage in biomonitoring studies that use mosses. In this study, the kinetics of elemental sorption in three moss species (Pleurozium schreberi, Dicranum polysetum, and Sphagnum fallax) were investigated under laboratory conditions. Sorption from metal salt solutions was carried out under static conditions with decreasing elemental concentration. Functional groups responsible for binding metal cations to the internal structures of the mosses were also identified. It was shown that the equilibrium state wa…
Passive Biomonitoring of Influence of the Communication Traffic on Deposition the Pollution Near the Motorway
2019
W pracy przedstawiono wyniki badań, przeprowadzonych w ramach biomonitoringu pasywnego, polegających na ocenie depozycji metali ciężkich (Ni, Cu, Zn, Cd, Hg i Pb), wzbogacających lokalnie aerozol atmosferyczny w skutek ruchu komunikacyjnego na autostradzie A4 w pobliżu miejscowości Prószków (województwo opolskie). Do badań wykorzystano próbki mchów Pleurozium schreberi, które pobrano w pobliżu autostrady na dystansie 3000 m i w odległości od niej do 120 metrów. Przy wyborze punktów pomiarowych uwzględniono częstotliwość kierunku wiatru na tym terenie. Metale ciężkie oznaczono metodą absorpcyjnej spektometrii atomowej ze wzbudzaniem w płomieniu (F-AAS). Wyniki badań wskazują na to, iż ruch k…