Search results for " microscopy"
showing 10 items of 1617 documents
Investigation of phthalocyanine crystals exposed to NO2 ambient gas
2002
Crystals of free base phthalocyanine (H2pc) and its unsubstituted metal derivatives Mpc (where M=Ni, Cu, Zn, Pb, and pc=C32H16N8 2−=phthalocyanine ligand) were examined after being exposed to NO2 ambient gas. Scanning electron microscopy (SEM) supported by X-ray microprobe analysis (EDAX), UV–Vis and FTIR spectroscopy as well as X-ray powder diffractometry (XRD) were applied to study the crystals chemistry and surface morphology. The NO2 molecules were found to penetrate the crystal unit which led to the breakdown of the phthalocyanine macrocycle. The surface of the doped crystals has been scaled and covered by a layer composed predominantly of phthalimide. Despite vacuum desorption, it has…
Characterization of prehispanic cosmetics found in a burial of the ancient city of Teotihuacan (Mexico)
2012
The present paper reports the chemical data obtained on samples of pigmenting materials contained in 31 miniature vessels found in a burial found in Teopancazco, a multiethnic neighborhood center located in the southeastern sector of the archaeological site of Teotihuacan (Central Mexico) and the analytical protocol established for the complete characterization of these archaeological materials. For this purpose a multi-technique approach based on the combination of several non destructive and micro-destructive instrumental techniques, namely, light microscopy (LM), scanning electron microscopy-X-ray micro-analysis (SEMe EDX), transmission electron microscopy (TEM), voltammetry of micropart…
Mechanical characterization of TiO2 nanofibers produced by different electrospinning techniques
2015
Abstract In this work TiO2 nanofibers produced by needle and needleless electrospinning processes from the same precursor were characterized and compared using Raman spectroscopy, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and in situ SEM nanomechanical testing. Phase composition, morphology, Young's modulus and bending strength values were found. Weibull statistics was used to evaluate and compare uniformity of mechanical properties of nanofibers produced by two different methods. It is shown that both methods yield nanofibers with very similar properties.
Flash synthesis of zirconia nanoparticles by microwave forced hydrolysis
2001
Forced hydrolysis preparation of zirconia sols and powders by microwave heating of zirconium tetrachloride solutions at temperatures equal to 180 °C leads in a few minutes to monodispersed nanoscale zirconia particles. Synthesis was performed in a microwave reactor called the RAMO system. This microwave reactor was designed by the authors. This flash-synthesis process combines the advantages of forced hydrolysis (homogeneous precipitation) and microwave heating (very fast heating rates). The sols and powders were characterized by x-ray diffraction,photon correlation spectroscopy (PCS), small-angle x-ray scattering, and transmission electron microscopy. Sols are colloidally stable, which mea…
Facile synthesis and characterization of monocrystalline cubic ZrO2 nanoparticles
2007
Abstract Crystalline ZrO2 nanoparticles were prepared from zirconium isopropoxide by slow hydrolysis and subsequent hydrothermal treatment of solutions containing various amounts of sodium hydroxide at 180 °C. Whereas moderately basic solutions lead to the formation of nanoparticles of monoclinic ZrO2 with plate-like morphology, and nanoparticles of the cubic ZrO2 high-temperature polymorph with diameters of approx. 5 nm were obtained from strongly basic solutions. The morphology, structure and properties of as-synthesized nanoparticles were characterized using HRTEM, XRD, Raman spectroscopy, UV–vis, PL spectroscopy and BET measurements. The formation of both, the monoclinic and the cubic p…
ChemInform Abstract: Facile Synthesis and Characterization of Monocrystalline Cubic ZrO2Nanoparticles.
2008
Abstract Crystalline ZrO2 nanoparticles were prepared from zirconium isopropoxide by slow hydrolysis and subsequent hydrothermal treatment of solutions containing various amounts of sodium hydroxide at 180 °C. Whereas moderately basic solutions lead to the formation of nanoparticles of monoclinic ZrO2 with plate-like morphology, and nanoparticles of the cubic ZrO2 high-temperature polymorph with diameters of approx. 5 nm were obtained from strongly basic solutions. The morphology, structure and properties of as-synthesized nanoparticles were characterized using HRTEM, XRD, Raman spectroscopy, UV–vis, PL spectroscopy and BET measurements. The formation of both, the monoclinic and the cubic p…
Identification of the contaminants present on the surface of lactose for pharmaceutical use and analysis of the impact of their presence on the inter…
2018
The discovery of the problem will go through training techniques at the nanoscale characterization and chemical analysis, the discovery of the industrial problem in society Armor Proteins, the validation of a pharmaceutical lactose. With the aim to increase our knowledge on powders for food or pharmaceutical use, we propose to study the effect of manufacturing processes, shaping, granulation on the reactivity of powders. The first part is devoted to the effect of purity on interactions-Lactose Lactose and Lactose-API measured / quantified by near-field techniques (AFM, SMM, MSAFM) under ambient atmosphere and under stressful conditions storage. Deriving a second portion of the preceding par…
Surface plasmon polaritons on metal cylinders with dielectric core
2001
International audience; Metal-cladded dielectric cylinders with submicron diameters may serve to model coated tips used in nearfield scanning optical microscopy. The signal measured may be greatly influenced by resonance effects due to eigenmodes of the probe. Especially, using a photon scanning tunneling microscope setup, gold-coated tips have been found to detect a signal proportional to the magnetic field distributions [E. Devaux et al.. Phys. Rev. B 62, 10 504 (2000)]. This effect is attributed to cylindrical surface plasmons. We present here fully retarded calculations of the dispersion and field patterns of the nonradiative plasmon modes in cylindrical geometry. We study the effect of…
Near-field observation of subwavelength confinement of photoluminescence by a photonic crystal microcavity
2006
We present a direct, room-temperature near-field optical study of light confinement by a subwavelength defect microcavity in a photonic crystal slab containing quantum-well sources. The observations are compared with three-dimensional finite-difference time-domain calculations, and excellent agreement is found. Moreover, we use a subwavelength cavity to study the influence of a near-field probe on the imaging of localized optical modes. © 2006 Optical Society of America.
Excitation and characterization of dielectric-loaded surface plasmon-polariton waveguides at telecommunication wavelengths - art. no. 69880T
2008
International audience; The excitation of surface plasmon-polariton (SPP) waveguide modes in 500-nm-wide and 550-nm-high dielectric ridges deposited on a thin gold film is characterized at telecommunication wavelengths, by application of a scanning near-field optical microscope (SNOM), and by utilizing the finite element method (FEM). Different tapering structures for coupling in SPPs, excited at the bare gold-air interface, are investigated with a SNOM, and the dependence of in coupling efficiency on tapering length is characterized by means of FEM calculations. The performance of this in coupling method is compared to an alternative excitation scheme, where the effective index of SPPs in …