Search results for " mineral"
showing 10 items of 541 documents
Sedimentology and isotope geochemistry of Carnian deep-water marl/limestone deposits from the Sicani Mountains, Sicily: Environmental implications an…
1995
Abstract The upper Triassic Halobia-bearing marl/limestone deposits from the Sicani Mountains (Sicily) record the sedimentary evolution of the Sicanian Basin through the middle and late Carnian time. Dark marls and interbedded grey calcilutites of Julian age are characterized by abundant pyrite, sparse bioturbation and negative carbonate carbon δ13C values. They accumulated in a basin with dominantly anoxic to dysaerobic bottom waters. Lower Tuvalian dark-grey pyritic marls and calcilutites, which contain carbonate minerals with relatively high Mn contents and widely fluctuating δ13C signatures, were deposited under dysaerobic conditions. Middle and upper Tuvalian cherty limestones show int…
The influence of natural trace element distribution on the mobility of radionuclides. The exemple of nickel in a clay-rock
2015
International audience; The natural distribution of nickel (Ni) in the Callovian–Oxfordian clay-rich rock of Bure (France) was investigated, together with that of cobalt (Co), zinc (Zn) and lead (Pb). The most Ni-enriched phases are pyrite (∼400 × 10−6 g g−1 Ni), sphalerite (∼300 × 10−6 g g−1), chlorite (∼285 × 10−6 g g−1), organic matter (∼300 × 10−6 g g−1), muscovite (100–200 × 10−6 g g−1) and possibly carbonate minerals (mainly calcite and minor dolomite, ∼10 × 10−6 g g−1). Despite their high abundance (up to ∼80% in the upper part of the formation), carbonate minerals are quantitatively a minor Ni reservoir; most of the Ni is borne by chlorite and pyrite, which are minor mineral phases.…
A new simple approach to evaluate pedogenic clay transformation in a Vertic Calcisol
2006
The aim of this study is to characterize the pedogenic clay minerals by using simple approach: Mixing mineralogical and geochemical findings. The fine clay fractions (< 0.1 μm) of a Vertic Cambisol profile were studied by means of X-ray diffraction (XRD), infrared spectroscopy (FTIR) and cation exchange capacity (CEC). Qualitative and quantitative mineralogical compositions of the clay mixture were determined. Moreover, chemical equilibria and thermodynamic stabilities of minerals (calcite, gypsum, kaolinite, smectites and illites) were studied using results of ionic activities obtained from total concentration of various aqueous species in water extracts from soil-saturated pastes. XRD ana…
Zirconium and hafnium fractionation and distribution of Rare Earth Elements in neutral–alkaline waters: Case study of Lake Van hydrothermal system, T…
2021
International audience; We investigated the distribution of Zr, Hf, and rare earth elements (REE) as the sum of lanthanides plus Y in the hydrothermal system in the Lake Van area of south-eastern Turkey. This system is characterised by water with variable pH in alkaline conditions resulting from hydrothermal CO2 upraise and neoformation of calcite minerals in near equilibrium with the interacting waters. Zr, Hf, and REE determinations were carried out for aqueous phases and suspended solids in lake water and surrounding thermal springs. We found that dissolved Hf is partitioned relative to Zr during calcite formation and that such fractionation is a function of the Ca2+ activity in warm wat…
Influence of humic acid on neptunium(V) sorption and diffusion in Opalinus Clay
2013
SummaryThe influence of14C-labeled M42 humic acid (HA) on the interaction between neptunium(V) and natural clay rock (Opalinus Clay (OPA), Switzerland) has been investigated in batch sorption and diffusion experiments under ambient air conditions. The effect of 10 mg/L HA on the diffusion of 8 μM Np(V) in OPA has been investigated in synthetic OPA pore water (pH 7.6, I = 0.4M) for the first time. Batch sorption experiments as a function of solid-to-liquid ratio (4-20 g/L) were performed under same experimental conditions to compare distribution coefficients obtained from both diffusion and sorption experiments. These experiments showed only a slight influence of HA on Np(V) uptake by OPA in…
Dissolution and precipitation of gypsum and carbonate minerals in soils on evaporite deposits, central Sicily: isotope geochemistry and microfabric a…
1993
Abstract Soil profiles developed from carbonate- and sulphate-rich deposits of the Gessoso-Solfifera Formation (Miocene) were sampled in central Sicily (544 mm annual precipitation and a strongly seasonal rainfall regime). Carbon and oxygen isotope data supported by mineralogical and thin section investigations indicate that meteoric waters and groundwaters dissolve and repricipitate carbonates and gypsum in the soil profiles. The boundary between the C horizon and the overlying one is the formation site of 18O depleted carbonates (calcite and/or dolomite) presumably precipitated from percolating waters during wet periods. Greater δ18O values of carbonates in the shallower horizons suggest …
Hydrogeochemistry and fractionation pathways of Mg isotopes in a continental weathering system: Lessons from field experiments
2012
Abstract The potential of magnesium isotope records from cave carbonate archives (speleothems) has been documented but remains underexplored. This is due to the limited knowledge regarding the complex suite of physico-chemical and biological disequilibrium fractionation processes affecting meteoric fluids in the soil zone, the carbonate hostrock and calcite precipitation in the cave. This study presents δ 26 Mg data from a monitored cave in Germany (Bunker Cave) including rain water (δ 26 Mg: − 0.70 ± 0.14‰), soil water (δ 26 Mg: − 0.51 ± 0.10‰) and drip waters (δ 26 Mg: − 1.65 ± 0.08‰) sampled between November 2009 and May 2011. Field precipitation experiments, i.e., calcite precipitat…
The effects of drip rate and geometry on the isotopic composition of speleothems: Evaluation with an advection-diffusion-reaction model
2022
Abstract The curvature and slope of speleothem surfaces have been shown to affect the reaction rates in the aqueous carbonate system by altering the thickness of the CaCO3-precipitating solution. However, the effects of speleothem geometry and drip rate on the speleothem’s carbon and oxygen isotopic composition have yet to be investigated. Over more strongly sloping surfaces, solutions are thinner and flow faster. The effects of thinner and faster-flowing solutions on the isotopic composition of carbonate minerals precipitated from these solutions are of opposite sense. Thinner solutions enhance rates of CO2 degassing and mineral formation, increasing the degree of isotopic distillation of …
Origin of clay minerals in soils on pyroclastic deposits in the island of Lipari (Italy)
2005
The island of Lipari (Italy) is characterized by calc-alkaline to potassic volcanism and a Mediterranean-type climate. The mineralogical and chemical features of two different soil profiles with ages of 92,000 and 10,000–40,000 y, respectively, have been investigated. There were no Andisols, but Vitric and Vertic Cambisols have developed at both sites. Although the morphology of the soils was similar, remarkable differences in the clay mineralogy between the two sites were observed. The site with the Vitric Cambisol was associated with the weathering sequence: glass → halloysite → kaolinite or interstratified kaolinite-2:1 clay minerals. Both sites had smectite in the clay fraction and, to …
Isotope ratios of nonexchangeable hydrogen in soils from different climate zones
2010
Abstract The fractionation of H isotopes in global precipitation leads to a continuous decrease in 2 H concentrations of precipitation with increasing latitude, altitude and continentality. Thus, the local precipitation, soil and ground water used by plants for photosynthesis or consumed during neoformation of pedogenic clay minerals often have a spatially diagnostic δ 2 H value. We hypothesize that the δ 2 H value of isotopically nonexchangeable H in bulk soil (composed of C-bonded H in soil organic matter (SOM) and the nonexchangeable fraction of O-bonded H in pedogenic clay minerals) is correlated with the mean δ 2 H value of local precipitation water at the place and time of biomass pro…