Search results for " minerals"
showing 10 items of 137 documents
Adsorption of dissolved organic matter on clay minerals as assessed by infra-red, CPMAS 13C NMR spectroscopy and low field T1 NMR relaxometry
2011
Abstract Dissolved organic matter (DOM) is a very important environmental constituent due to its role in controlling factors for soil formation, mineral weathering and pollutant transport in the environment. Prediction of DOM physical–chemical properties is achieved by studying its chemical structure and spatial conformation. In the present study, dissolved organic matter extracted from compost obtained from the organic fraction of urban wastes (DOM-P) has been analysed by FT-IR, CPMAS 13C NMR spectroscopy and 1H T1 NMR relaxometry with fast field cycling (FFC) setup. While the first two spectroscopic techniques revealed the chemical changes of dissolved organic matter after adsorption eith…
Analysis of archaeological samples and local clays using ICP-AES, TGâDTG and FTIR techniques
2000
Abstract The spectrochemical and thermal analysis of different archaeological samples as bricks, terra-cotta and local clays were carried out. The concentration of major and minor elements of samples was determined by sequential inductively coupled plasma atomic emission spectrometry. The method was tested by determining Si, Al, Fe, Ca, Mg, Mn, Pb, Cu, Zn, Ti, Na and K in the standard solutions and reference material GXR-4. The precision of the determination (relative standard deviation) ranged from 0.4 to 1.54%. The clay minerals are the main materials for the production of bricks and terra-cotta figures. Thermogravimetric (TG) and differential (TG–DTG) analysis and Fourier transform infra…
The role of pedogenic overprinting in the obliteration of parent material in some polygenetic landscapes of Sicily (Italy)
2016
Abstract Many soils older than the Holocene have experienced several changes, and possess properties that may be due to the complex effect of several stages of soil development; these soils are called polygenetic. It is still rather unclear, however, if, as time elapses, pedogenic processes tend to diverge generating different soils, or converge towards increasingly similar soils. We studied five pedons (37°60′N, 13°90′E) exposed to present weathering simultaneously since the Holocene but located on Upper Miocene or Holocene parent material. Their XRD and FTIR clay mineralogy reveal an overall homogeneity; smectites, calcite and gypsum reach the thermodynamic equilibrium, a slight undersatu…
A simulation tool for ion exchange membrane crystallization of magnesium hydroxide from waste brine
2021
Abstract Increasing attention is nowadays paid to the management and valorisation of industrial waste brines aiming also at the recovery of raw materials. Magnesium has been listed as a Critical Raw Material by EU, prompting researchers to investigate novel routes for its recovery. Within this framework, a novel Crystallizer with Ion Exchange Membrane (CrIEM), is proposed as an innovative way to recover magnesium from industrial waste brines exploiting low-cost alkaline reactants. In the present work, a novel mathematical model of the CrIEM process is proposed to provide a useful tool for its design in different working conditions. Batch and feed & bleed continuous configurations have been …
CHLORITE/SMECTITE - ALKALI FELDSPAR METASOMATIC XENOLITHS FROM HYBLEAN MIOCENIC DIATREMES (SICILY, ITALY): EVIDENCE FOR EARLY INTERACTION BETWEEN HYD…
2006
Upper-Miocene tuff-breccia pipes from the Hyblean area (south-eastern Sicily) bear a number of ultramafic and mafic xenoliths (spinel-peridotites, pyroxenites, gabbroic rocks) whose study has led to conclude that the Meso-Caenozoic carbonatic and volcanic succession stands upon a fossil oceanic core-complex, probably connected with the adjacent Ionian crust. Evidence for hydrothermal metasomatism is common in the Hyblean ultramafic and mafic xenoliths. In some cases, extreme metasomatic transformation and shearing have deleted original mineralogy and textures yielding unusual rocks, hereafter called “metasomatites”. These rocks generally exhibit cataclastic texture, their hydrothermal miner…
The geochemistry of Tl and its isotopes during magmatic and hydrothermal processes: The peralkaline Ilimaussaq complex, southwest Greenland
2014
Abstract We use thallium (Tl) concentrations, K/Rb, K/Tl and Rb/Tl ratios and Tl isotopes in minerals from the alkaline to peralkaline Ilimaussaq complex (South Greenland) to trace magmatic differentiation, crustal assimilation, magmatic degassing, ore precipitation and hydrothermal metasomatism. Closed-system magmatic differentiation is marked by a coherent decrease of K/Tl- and K/Rb-ratios, whereas crustal assimilation results in a strong Tl-enrichment, causing low K/Tl-ratios compared to K/Rb-ratios. Thallium isotopes show only slight changes during orthomagmatic differentiation and the assimilation of crustal material cannot be traced, since the isotopic composition of the average crust…
Electrical treeing in EVA-bohemite and EVA-montmorillonite nanocomposites
2009
The present experimental work focuses on the growth of electrical treeing inside different Ethylene-vinyl acetate (EVA) nanocomposites containing Bohemite (an aluminum oxide hydroxide) and Montmorillonite (a phyllosilicate clay mineral) nanoparticles. Bohemite and Montmorillonite particles have different aspect ratios: the first one has a nanometric cube-like symmetry, while the latter has a typical layered structure. The results evidence that the growth of the electrical treeing inside the original polymer can be altered significantly by the dispersion of inorganic nanoparticles.
Sulfide mineral identification using laser-induced plasma spectroscopy
2003
Sulfide minerals in rock samples were identified with laser-induced plasma spectroscopy (LIPS) in the near vacuum ultraviolet spectral region. Reference spectra of pyrite, pyrrhotite, chalcopyrite, sphalerite, barite, calcite and dolomite were applied to classification of minerals in sulfur-bearing drill core samples. On the basis of the results mineral distributions in the sample were estimated. The potential of the LIPS method for in situ analysis is discussed.
Structural studies of adsorbed protein (betalactoglobulin) on natural clay (montmorillonite)
2014
International audience; In this work, the adsorption of a small globular protein (betalactoglobulin, BLG), on a natural montmorillonite clay (Mt) was investigated in acidic buffer (pH = 3). The combination of different characterization techniques such as zetametry, X-ray diffraction, transmission electronic microscopy, fluorescence and solid state nuclear magnetic resonance spectroscopies shed light on the interaction mechanism between the clay mineral and the proteins. For low BLG concentration, a slight increase of the interlayer spacing of the clay mineral was noticed as well as structural changes of the protein. In contrast, as the concentration of BLG increased, the adsorption led to a…
Synthesis and Characterization of the Hybrid Clay-Based Material Montmorillonite-Melanoidin: A Potential Soil Model
2010
The study of the interactions among metals, minerals, and humic substances is essential in understanding the migration of inorganic pollutants in the geosphere. A considerable amount of organic matter in the environment is associated with clay minerals. To understand the role of organic matter in the environment and its association with clay minerals, a hybrid clay-based material (HCM), montmorillonite (STx-1)-melanoidin, was prepared from L-tyrosine and L-glutamic acid by the Maillard reaction. The HCM was characterized by elemental analysis, nuclear magnetic resonance, x-ray photoelectron spectroscopy (XPS), scanning transmission x-ray microscopy (STXM), and thermal analysis. The presence…