Search results for " niobate"
showing 10 items of 101 documents
Relaxation of Polarization at the Broad Phase Transition in Modified PMN Ferroelectric Ceramics
2013
The reported study is focused on effects of relaxation of polarization within the range of the broad phase transition at strong sinusoidal measuring fields in modified lead magnesium niobate ceramics. The obtained results reveal an essential thermal broadening of the ϵ′(E) spectra specific to relaxor ferroelectrics. Temperature dependence of ϵ′ eff (T) at medium fields shows two broad maximums – at Tm and at 40°C. On the basis of analysis of the experimental data, admixture of lithium is suggested to promote formation of domains in lead magnesium niobate ceramics.
Comparative studies of ferroelectric and magnetic phase transitions in Pb(Fe1/2Nb1/2)O3-PbMO3 (M-Ti, Zr) multiferroic solid solutions
2015
Some peculiar features of magnetic x,T-phase diagram of (1-x)PbFe1/2Nb1/2O3- xPbTiO3 system at x ≈ 0.1 have been ascribed previously to the change of the lattice symmetry from rhombohedral to tetragonal or to the decrease of the lattice parameter with x. We carried out structural, dielectric, magnetization, and Mossbauer studies of (1-x)PbFe1/2Nb1/2O3-xPbZrO3 system, where the symmetry remains rhombohedral, while the lattice parameter increases with x. However, the magnetic x,T-phase diagram of (1-x)PbFe1/2Nb1/2O3-xPbZrO3 appeared to be very similar to that of (1-x) PbFe1/2Nb1/2O3-xPbTiO3. Anomalies of composition dependence of magnetic phase transition temperatures at x ≈ 0.1 are supposed …
Quantum chemical modelling of perovskite solid solutions
2000
In line with our previous study (Eglitis R I et al 1998 J. Phys.: Condens. Matter 10 6271) for a single Nb impurity and Nb clusters in KTaO3 we present here the results of calculations for a series of perovskite KNbx Ta 1−x O3 (KTN) solid solutions (x = 0, 0.125, 0.25, 0.75, and 1). The quantum chemical method of the intermediate neglect of the differential overlap (INDO) combined with the large unit cell (LUC) periodic model is used. According to the INDO calculations, Nb impurity becomes off-centre in KTaO3 already at the lowest studied Nb concentration. Its off-centre displacement is in a good agreement with XAFS measurements. We compare our results with previous FP-LMTO calculations. Pe…
Vibrational Analysis of Paraelectric–Ferroelectric Transition of LiNbO3: An Ab-Initio Quantum Mechanical Treatment
2021
FSG acknowledges the CINECA award under the ISCRA initiative (HP10BJO47B) for the availability of high-performance computing resources and support.
Multi-line NIR-RGB emission in Nd:LiNbO3 RPE optical waveguides
2007
Simultaneous generation of four spectral emission lines has been achieved in Nd-doped lithium niobate reverse proton exchange optical waveguide cavities. Using a pump at 800 nm, the four lines were found and they are due to lasing at 1.3735 combined with parametric conversion at 0.687, 0.574 and 0.4 mum.
Bi-color spatial solitons in linearly uncoupled planar waveguides
2004
We report on the observation of spatial optical simultons in a novel geometry consisting of two partially overlapped, linearly uncoupled planar waveguides in lithium niobate obtained by reverse proton exchange. Two orthogonally polarized modes are coupled through an off-diagonal tensor element of the quadratic nonlinearity, giving rise to second harmonic generation and mutual trapping via cascading. This phenomenon demonstrates a balance between diffraction and self-focusing for two orthogonal modes of different waveguides, and occurs at room temperature in longitudinally uniform waveguides.
Second harmonic generation in multimode graded-index fibers: spatial beam cleaning and multiple harmonic sideband generation
2017
We study experimentally and numerically the spectral and spatial dynamics of second harmonic generation in an all-optically poled multimode graded-index fiber. In contrast with poled single-mode fibers, in a multimode graded-index fiber a pump can generate a series of sharp sidebands around its second harmonic (SH) that originate from the sub-millimetric periodic evolution of the intensity at the fundamental frequency. The mutual interaction between the fundamental and its SH may also strongly affect the spatial distribution of guided light for both colors: when increasing the pump power, both fundamental and SH output beams evolve from disordered multimode speckles into two bell-shaped bea…
Spatial Soliton Dynamics in Two-Dimensional Quadratic Photonic Crystals
2007
We present a theoretical and experimental investigation of soliton dynamics associated to twin-beam second harmonic generation in a purely nonlinear two-dimensional planar photonic lattice in LiNbO3.
Quadratic solitons in 2D nonlinear photonic crystals
2007
We report on the first observation of spatial solitons in a 2D nonlinear photonic crystal. The experiments were performed in an hexagonally poled LiNbO3 waveguide designed for second harmonic generation from ~1.55 micron.
Parametric solitons in nonlinear photonic crystals
2007
We present theoretical and experimental investigations on the soliton dynamics associated to multiple second harmonic generation resonances in two-dimensional nonlinear photonic crystals, highlighting a wealth of new possibilities for soliton management in such structures.