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showing 10 items of 15512 documents
Thermodynamics: Classical Framework
2016
This chapter starts with a summary of the thermodynamic potentials and the relationships between them which are obtained from Legendre transformation. This is followed by an excursion to some important global properties of materials such as specific heat, expansion coefficients and others. The thermodynamic relations provide the basis for a discussion of continuous changes of state which are illustrated by the Joule-Thomson effect and the Van der Waals gas. These are models which are more realistic than the ideal gas. The discussion of Carnot cycles leads to and illustrates the second and third laws of thermodynamics. The chapter closes with a discussion of entropy as a concave function of …
Remembering an Era: Roger Penrose’s Paper on “Gravitational Collapse: The Role of General Relativity”
2018
Back in the 1960s, Einstein’s theory of general relativity re-emerged as a field of important research activity. Much of the impetus behind this resurgence came from powerful new mathematical ideas that Roger Penrose and Stephen Hawking applied to prove general singularity theorems for global space-time structures. Their results stirred the imaginations of astrophysicists and gave relativistic cosmology an entirely new research agenda. A decade later, black holes and the big hang model were on the tongues of nearly everyone who followed recent trends in science. As popular expositions dealing with quasars, pulsars, and the geometry of black holes began to appear in magazines and textbooks, …
Anomaly-free scale symmetry and gravity
2023
In this Letter, we address the question of whether the conformal invariance can be considered as a global symmetry of a theory of fundamental interactions. To describe Nature, this theory must contain a mechanism of spontaneous breaking of the scale symmetry. Besides that, the fundamental theory must include gravity, whereas all known extensions of the conformal invariance to the curved space-time suffer from the Weyl anomaly. We show that conformal symmetry can be made free from the quantum anomaly only in the flat space. The presence of gravity would reduce the global symmetry group of the fundamental theory to the scale invariance only. We discuss how the effective Lagrangian respecting …
Solving Conflicts among Conservation, Economic, and Social Objectives in Boreal Production Forest Landscapes: Fennoscandian Perspectives
2018
This chapter discusses challenges and possibilities involved in preserving biological diversity and the diversity of ecosystem services in the boreal zone and yet at the same time maintaining intensive timber extraction in boreal forests. Our focus is on Fennoscandian forests at the landscapes level, and we consider economic, social and ecological in the sustainability of forest management. We provide an outlook to boreal forest ecosystems and their history, and an overview of the forestry practices and policies that aim to ensure multi-functionality of Fennoscandian forests, i.e. diversity of efforts on sustaining biodiversity, timber production and other ecosystem services from forest lan…
Wh-Relative Clauses and Left Periphery from Latin to some Romance Languages
2011
The paper is organized as follows: after an introduction of the issue we will examine, in the first section we shall discuss the theory of the antisymmetry of syntax as specifically concerns relative clauses, evidencing also problems linked to the application of this theory to the syntax of relative clauses in Latin and in other Indo-European languages; the second section will present our first attempt at some analysis of the left periphery of the Proto-Indo-European sentence; in the third section we shall discuss the categorial status of the relative pronoun in Latin and we shall produce a model of the left periphery of the Latin subordinate clause, supplying examples taken from literary a…
Synthesis and Structure-Affinity Relationships of Spirocyclic Benzopyrans with Exocyclic Amino Moiety
2019
σ1 and/or σ2 receptors play a crucial role in pathological conditions such as pain, neurodegenerative disorders, and cancer. A set of spirocyclic cyclohexanes with diverse O-heterocycles and amino moieties (general structure III) was prepared and pharmacologically evaluated. In structure-activity relationships studies, the σ1 receptor affinity and σ1:σ2 selectivity were correlated with the stereochemistry, the kind and substitution pattern of the O-heterocycle, and the substituents at the exocyclic amino moiety. cis-configured 2-benzopyran cis-11b bearing a methoxy group and a tertiary cyclohexylmethylamino moiety showed the highest σ1 affinity ( Ki = 1.9 nM) of this series of compounds. In…
Systematic conformational search analysis of the SRR and RRR epimers of 7-hydroxymatairesinol
2010
An extensive and systematic conformational search was performed on the two epimers of the natural lignan 7-hydroxymatairesinol (HMR), by means of a home-made Systematic Conformational Search Analysis (SCSA) code, designed to select more and more stable conformers through sequential geometry optimization of trial structures at increasing levels of calculation theory. In the present case, the starting molecular structures were selected by the semi-empirical AM1 method and filtered – i.e. decreased in number by choosing the more stable species – on the basis of their energy calculated by the HF method and the 6-31G(d) basis set. The geometries obtained were further refined by performing densit…
Simultaneous optimization of harvest schedule and measurement strategy
2013
In many recent studies, the value of forest inventory information in the harvest scheduling has been examined. Usually only the profitability of measuring simultaneously all the stands in the area is examined. Yet, it may be more profitable to concentrate the measurement efforts to some subset of them. In this paper, the authors demonstrate that stochastic optimization can be used for defining the optimal measurement strategy simultaneously with the harvest decisions. The results show that without end-inventory constraints, it was most profitable to measure the stands that were just below the medium age. Measuring the oldest stands was not profitable at all. It turned out to be profitable t…
Employees’ adherence to information security policies: An exploratory field study
2014
The key threat to information security comes from employees who do not comply with information security policies. We developed a new multi-theory based model that explained employees' adherence to security policies. The paradigm combines elements from the Protection Motivation Theory, the Theory of Reasoned Action, and the Cognitive Evaluation Theory. We validated the model by using a sample of 669 responses from four corporations in Finland. The SEM-based results showed that perceived severity of potential information security threats, employees' belief as to whether they can apply and adhere to information security policies, perceived vulnerability to potential security threats, employees…
Citizens' Communication Habits and Use of ICTs During Crises and Emergencies
2014
In this article, citizens’ communication habits and use of information and communication technologies during crises and emergencies are discussed from the perspective of community resilience. The topic is approached qualitatively by exploring citizens’ perceptions, and the data were gathered by means of focus groups in storm-prone and flood-prone areas in Finland. The results indicate that citizens consider emergency communication to be mostly unidirectional: from authorities to the public. However, because crises are often complex and fast developing, cooperation among response organizations and citizen groups is needed to coproduce safety and in adapting to changing situations. Organizati…