Search results for " remediation"

Accumulation of Pb and Zn in Bidens triplinervia and Senecio sp. spontaneous species from mine spoils in Peru and their potential use in phytoremedia…

2012

Abstract Heavy metal toxicity has become a global concern due to the ever-increasing contamination of soil, water and crops. Until recent decades little has been known about the remediation of mining sites using spontaneous plants in Latin America. Soil and plant samples were taken in Peru, at a polymetallic mine (mainly silver, lead and copper) in Cajamarca Province, Hualgayoc district. Top soils (0–20 cm) were analyzed for physical and chemical properties by standard methods. Total Pb and Zn concentrations in top soils were determined by ICP-OES. Similar metals in plants were analyzed separately (aerial and root system). Ti content was used as an indicator for contamination of plant sampl…

Front Cover: Efficient Capture of Organic Dyes and Crystallographic Snapshots by a Highly Crystalline Amino-Acid-Derived Metal-Organic Framework (Che…

2018

Quantitative study of the capture of silver nanoparticles by several kinds of soils

2018

The capacity of different soils to capture silver nanoparticles (AgNPs) by measuring changes of an AgNP intrinsic property such as the plasmon for the first time, was studied. In-tube solid-phase microextraction (IT-SPME) coupled on-line to capillary liquid chromatography (CapLC) with diode array detection (DAD) was employed for measuring the interactions between soil and in-contact AgNP dispersions. Its achieved LOD 9 pM assures quantitative retention measurements and selectivity for soil lixiviation was suitable. Electronic microscopy was employed for corroborating the entrapped Ag into the soils. Capture % of AgNPs was calculated in compost (>99%), mountain (>99%), orchard (15±1%) and ur…

Modified Halloysite Nanotubes: Nanoarchitectures for Enhancing the Capture of Oils from Vapor and Liquid Phases

2013

We prepared hybrid halloysite nanotubes (HNT/sodium alkanoates) in which the inner cavity of the nanoclay was selectively modified. Physicochemical studies evidenced the interactions between HNT and sodium alkanoates, ruled out clay exfoliation, quantified the amount of the loaded substance, and showed an increase of the total net negative charge, allowing us to obtain rather stable aqueous nanoclay dispersions. These dispersions were exploited as inorganic micelles to capture hydrocarbon and aromatic oils in the vapor and liquid states and were revealed to be nonfoaming but very efficient in encapsulating oils. Here, we have fabricated biocompatibile and low-cost inorganic micelles that ca…

MODIFICATION OF HUMIC SUBSTANCES FOR DEVELOPMENT OF MATERIALS FOR ENVIRONMENTAL TECHNOLOGIES

2019

Humic substances are high molecular weight refractory polycationites formed during decay of living organic matter and through biosynthesis of low molecular weight organic substances (metabolites or decay products of living organisms). Presence of many functional groups in the structure of humic substances determines their ability to interact with metal ions forming stable complexes and influencing metal ion speciation in the environment and mobility, behaviour and speciation forms in the environment. Presently humic substances are a product of industrial scale and quantities in amounts of hundreds of tons are produced. The aim of this study is to analyse derivatization possibilities of humi…

Remediation of Soil Contamination with Heavy Metals by Using Zeolite and Humic Acid Additives

2012

- Soil remediation at contaminated sites very often needs customized approach, because of the different content of pollutants. Various technologies from simple soil excavation and transporting to hazardous waste landfills to different kinds of remediation by vitrification and the use of additives can be used for the treatment of soil. A series of remediation experiments using zeolites and humic acids were applied to soil contaminated with copper. Remediation can be performed with easily available additive materials of natural origin found near the place of application, in order to diminish the leaching of contaminants. Soils contaminated and spiked with copper were mixed with additives, and…

Carbon-based ionic liquid gels: alternative adsorbents for pharmaceutically active compounds in wastewater

2021

With the aim of obtaining adsorbent systems to be used for the removal of pharmaceutically active compounds (PhACs) from wastewater, some hybrid ionic liquid gels (HILGs) were obtained from the combination of ionic liquid-based supramolecular gels and carbon materials, like graphite, graphene and graphene oxide (graphene OX). The properties of HILGs were investigated by determining their gel–sol transition temperature and rheological features. They were tested for the removal of PhACs belonging to different pharmaceutical classes, like antibiotics, antidepressants, anti-inflammatory. In particular, the removal of carbamazepine (CBZ), diclofenac sodium salt (DCF), ciprofloxacin (CPX) and nal…

Ionic Liquid Gels: Tunable and Multifaceted Materials

Materials based on ionic liquids retain properties of solvent components, like low vapor pressure, high thermal stability and structure tunability. The latter allows changing properties of materials by making small variations in the cation or anion structure, opening the way to a plethora of different applications. In this context, ionic liquid gels can represent a challenge especially if they are obtained from gelation of ionic liquid binary mixtures or of organic salts in ionic liquids. In the framework of our interest in studying ionic liquids properties and applications, in the last few years, we have addressed our attention to the obtainment of ionic liquid gels.1 We have deeply invest…

La ri-mediazione digitale e la dissolvenza dell’io nel Photojournal di Annie Ernaux

2019

Scopo del contributo è l’analisi del Photojournal, un dispositivo fototestuale autobiografico che Annie Ernaux compone come premessa al volume delle sue opere, Écrire la vie (Gallimard, 2011). La sezione biografica del volume diventa una premessa autobiografica, dove l’autrice compone 70 foto e 100 brani dei suoi diari per spiegare le ragioni della sua scrittura. Le foto illustrano la realtà materiale e i diari esprimono la realtà soggettiva: le due condizioni che hanno permesso la scrittura delle opere dell’autrice. L’analisi della composizione fototestuale ha messo in rilievo due effetti di profondità: il palinsesto e il collage. Attraverso le sovrapposizioni degli strati dei documenti ri…

3D MICROSIZED PROTEIN AMYLOID PARTICULATES AS EFFECTIVE BIOADSORBERS FOR Pb2+ IONS

The production of new cost-effective biocompatible sorbent sustainable materials, with natural origins, able to remove heavy metals from water resources is nowadays highly desirable in order to reduce pollution and increase clean water availability. In this context, self-assembled protein materials with highly ordered amyloid structures, stabilised by H-bonds, seems to have a great potential as natural platform for a broader development of highly-tunable structures. By suitably varying solution conditions it is possible to tune aggregate size, surface area and morphologies as well as their physicochemical (hydrophobicity, hydrophilicity, swelling/deswelling properties) and mechanical proper…