Search results for " s.p.a."
showing 10 items of 253 documents
Assembly and encapsulation of coordination tectons driven by hydrogen-bondingand space-filling
2001
[FR] Le composé ¿Fe(LI)3¿2¿Fe(H2O)6¿(ClO4)6 (2), LI = 1,10-phénanthroline-5,6-dione, a été synthétisé et caractérisé. La structure cristalline 2 est définie par un assemblage bidimensionnel non covalent, peu commun, constitué par des tectons chiraux ¿Fe(LI)3¿2+, assemblés par des cations ¿Fe(H2O)6¿2+ encapsulés dans des cages. Ces cages sont formées par 12 liaisons hydrogène établies entre les molécules d¿eau coordinées et les groupes dione appartenant à six molecules chirales ¿Fe(LI)3¿2+ ¿, ¿ alternées.
Idrogel fluorescenti per applicazioni biomediche
2019
Lo studio di idrogel supramolecolari da utilizzare in ambito biomedico è in continua espansione. Questo è dovuto al fatto che, così come gli idrogel polimerici, mostrano eccellenti proprietà meccaniche, ma possono anche essere sottoposti reversibilmente a rigonfiamento o a transizioni gel-sol in risposta a stimoli esterni (temperatura, pH, enzimi, agenti redox).1Ad esempio, la buona risposta degli idrogel supramolecolari agli stimoli fisiologici, insieme alla loro elevata biodegradabilità e biocompatibilità, ne ha permesso l’utilizzo per la diagnosi tumorale. Solitamente, questi materiali sono facilmente assimilati dalle cellule e hanno la funzione di carrier per le molecole attive nel bioi…
Riusi creativi e sezioni complesse: spazi infrastrutturali per il riempimento di relazione
2017
Il saggio affronta una riflessione sulle pratiche della creatività tese a fertilizzare i tessuti urbani in termini di iper-relazionalità sociale, prendendo in considerazione gli assi sopraelevati di attraversamento in disuso, allo scopo di proporre soluzioni di socio-architettura che consentano una rivisitazione in termini slow spaces e favoriscano una riappropriazione vissuta basata su relazioni sociali dense. Da tempo gli spazi aperti di attraversamento sono i luoghi dove si possono sperimentare assetti variabili delineando insieme al disegno delle maglie infrastrutturali nuovi equilibri e nuove configurazioni urbane a percorso lento. Il riuso dei cavalcavia e degli assi sopraelevati sott…
Septal complex of the telencephalon of lizards: III. Efferent connections and general discussion.
1998
The projections of the septum of the lizard Podarcis hispanica (Lacertidae) were studied by combining retrograde and anterograde neuroanatomical tracing. The results confirm the classification of septal nuclei into three main divisions. The nuclei composing the central septal division (anterior, lateral, medial, dorsolateral, and ventrolateral nuclei) displayed differential projections to the basal telencephalon, preoptic and anterior hypothalamus, lateral hypothalamic area, dorsal hypothalamus, mammillary complex, dorsomedial anterior thalamus, ventral tegmental area, interpeduncular nucleus, raphe nucleus, torus semicircularis pars laminaris, reptilian A8 nucleus/ substantia nigra and cen…
Pas de titre
2011
A number of phonetic and phonological changes have lately been observed in most geographical varieties of British English. This phenomenon seems to have been accelerated by increasing social and geographical mobility in the past decades. Based on a corpus mainly consisting of several hours of spontaneous interaction between a number of native NW Yorkshire speakers divided into different age groups, this research identifies and analyses several segmental and suprasegmental innovations observed in apparent time in a set of accents associated with a circumscribed geographical area. This thesis discusses the motivation behind some of these changes and addresses the question of whether the same …
Spurectomy: A novel modification of non-penetrating deep sclerectomy.
2020
To evaluate the outcomes of a novel modification of the non-penetrating deep sclerectomy (NPDS) approach for glaucoma management called spurectomy.Observational comparative non-randomized retrospective study including 98 glaucomatous eyes of 76 patients operated on with the spurectomy technique consisting of the combination of the excision of the scleral spur with NPDS (groupA). A control group (groupB) including 53 glaucomatous eyes of 43 patients operated on with classical NPDS was also included. Changes in intraocular pressure (IOP) and medications required as well as complications were recorded in a 12-month follow-up.Mean IOP decreased from 25.69±8.11 preoperatively to 15.73±4.16mm Hg …
The importance of supramolecular reaction media in catalysis
White light emitting silsesquioxane based materials: the importance of a ligand with rigid and directional arms
2022
The synthesis of a novel polyhedral oligomeric silsesquioxane functionalized with eight rigid and directional terpyridine-based arms (Ter-POSS) was successfully achieved via a Sonogashira reaction. The POSS based ligand was extensively characterized using different techniques including 1H, 13C and 29Si NMR as well as UV-Vis and fluorescence spectroscopies. The assembly of these nano-caged units in the presence of different transition metal ions (Fe2+, Zn2+ and Cu2+) as well as of a cation from the lanthanides (Eu3+) was investigated using absorption and emission spectroscopies. The final materials display an evident emission in different regions of the visible spectrum as a function of the …
DCTN1 mutation analysis in Italian patients with PSP, MSA, and DLB
2020
Abstract DCTN1 encodes the largest subunit of dynactin complex essential in the retrograde axonal transport and cytoplasmic transport of vesicles; mutations in DCTN1 have been reported predominantly in individuals with Perry syndrome and, recently, in patients with progressive supranuclear palsy. Our genetic screening of DCTN1 in 79 patients with progressive supranuclear palsy, 100 patients with multiple system atrophy, and 28 patients with dementia with Lewy bodies from Italy revealed only synonymous and intronic variants, suggesting that DCTN1 mutations do not have a key role in the development of atypical parkinsonism in the Italian population.
Corrispondere al limite. Simone Weil: il pensiero e la luce
2002
La ricerca presentata nel volume si concentra sulle riflessioni più strettamente filosofiche di Simone Weil, lasciando sullo sfondo quelle politiche, nel tentativo di proporre un’ermeneutica originale degli scritti meno strutturati di Weil. A partire dai Primi scritti filosofici fino all’opera più frammentaria, ma teoreticamente più densa, i Quaderni, si vuole offrire una lettura dettagliata e unitaria di alcune nozioni cardine del pensiero weiliano, nella convinzione che il contributo teoretico da esse aperto sia tra quelli più acuti e fecondi della Francia degli anni Trenta. Nel primo capitolo si rintracciano le linee della riflessione gnoseologica weiliana attraverso, da una parte, un po…