Search results for " sedi"

Holocene hydrological changes in south-western mediterranean as recorded by lake-level fluctuations at lago Preola, a coastal lake in southern Sicily…

2011

This paper presents a high-resolution lake-level record for the Holocene at Lago Preola (Sicily, southern Italy) based on a specific sedimentological approach, with a chronology derived from AMS radiocarbon dates. It gives evidence of three major successive palaeohydrological periods, with (1) a pronounced dryness during the early Holocene until ca 10300 cal BP, (2) a highstand from ca 10300 to 4500 cal BP, and (3) a marked lowstand from 4500 cal BP to present. Large amplitude lake-level fluctuations characterise two transition phases at ca 10300e9000 and 6400e4500 cal BP. Period 2 was interrupted between 8300 and 7000 cal BP by a dry phase that was punctuated to ca 7300 cal BP by the depos…

Measuring magnitude and rate of vertical movements in the offshore Capo Vaticano (W Calabria) using lowstand coastal prisms and wave-built terraces

2012

The magnitude and rate of vertical movements have been measured in the offshore Capo Vaticano (western Calabria) for the Late Pleistocene - Holocene on the basis of the depth of submerged coastal prism and associated wave-built terrace formed during the sea-level lowstand of the Last Glacial Maximum (LGM). Uplifted and submerged terraces have proved to be valuable recorders of vertical motion in many locations around the world (e.g. DICKINSON, 2001; WEBSTER et alii, 2004) as the depth of their tops appear to be controlled by the sea-level. In the eastern Tyrrhenian margins, depending on the hydraulic energy conditions (i.e. waves and wind-induced currents), the average water depth of terrac…

“Inner” and “outer” wedge-top sequences in the Late Miocene Sicilian Foreland Basin System; inferences from the Upper Tortonian – Lower Messinian Ter…

2010

Stable isotopic composition of three foraminifera species in ODP Hole 160-963D

2020

Carbon-rich layers exist at both sides of the Mediterranean Sea sedimentary record and are called sapropels and organic rich layers (ORLs), respectively in the eastern and western basins. They have different levels of organic carbon accumulation and seafloor oxygen deprivation. The most recent sapropel and ORL deposition have a different timing, 10.8-6.1 and 14.5-9.0 ka respectively. Here we investigate oxygen isotopic records of three foraminifera species that occupy different habitats within the Sicily Channel water column since ~ 12.0 ka, thus in the sill between the eastern and western Mediterranean basins. These data are ice volume-corrected, to get information on water masses density …

Partitioning of nanoparticle-originated dissolved silver in natural and artificial sediments

2017

Sediments are believed to be a major sink for silver nanoparticles (AgNPs) in the aquatic environment, but there is a lack of knowledge about the environmental effects and behavior of AgNPs in sediments. The release of highly toxic Ag+ through dissolution of AgNPs is one mechanism leading to toxic effects in sediments. We applied an ultrasound-assisted sequential extraction method to evaluate the dissolution of AgNPs and to study the partitioning of dissolved Ag in sediments. Silver was spiked into artificial and 2 natural sediments (Lake Hoytiainen sediment and Lake Kuorinka sediment) as silver nitrate (AgNO3 ), uncoated AgNPs, or polyvinylpyrrolidone-coated AgNPs (PVP-AgNPs). In addition,…

Predicting the bioaccumulation of polyaromatic hydrocarbons and polychlorinated biphenyls in benthic animals in sediments

2016

There were two main objectives in this study. The first was to compare the accuracy of different prediction methods for the chemical concentrations of polyaromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) in the organism, based on the measured chemical concentrations existing in sediment dry matter or pore water. The predicted tissue concentrations were compared to the measured ones after 28-day laboratory test using oligochaeta worms (Lumbriculus variegatus). The second objective was to compare the bioaccumulation of PAHs and PCBs in the laboratory test with the in situ bioaccumulation of these compounds. Using the traditional organic carbon-water partitioning model, tissue…

Effects of activated carbon ageing in three PCB contaminated sediments: Sorption efficiency and secondary effects on Lumbriculus variegatus.

2015

The sorption efficiency and possible secondary effects of activated carbon (AC) (o 63-200 μm) was studied with Lumbriculus variegatus in three PCB contaminated sediments applying long AC-sediment contact time (3 years). AC amendment efficiently reduced PCB bioavailability as determined with both, L. variegatus bioaccumulation test and passive samplers. However, dose related secondary effects of AC on egestion rate and biomass were observed (applied doses 0.25% and 2.5% sediment dry weight). The sorption capacity and secondary effects remained similar when the experiments were repeated after three years of AC-sediment contact time. Further, transmission electron microscopy (TEM) samples reve…

Bioaccumulation, bioavailability and environmental fate of chlorophenol impurities, polychlorinated hydroxydiphenylethers and their methoxy analogues.

2006

The bioaccumulation potential and environmental fate of polychlorinated hydroxydiphenyl ethers (HO-PCDEs; polychlorinated phenoxyphenols, PCPP), the major impurities of chlorophenol formulations and their methoxy analogues (MeO-PCDEs; polychlorinated methoxyanisoles, PCPAs) were investigated. Oligochaete worms (Lumbriculus variegatus) exposed to sediment spiked with a model substance of one HO-hexaCDE (4'-HO-PCDE 161) or its methoxy analogue (4'-MeO-PCDE 161) clearly accumulated the test compounds revealing the potential for environmental risk of HO-PCDEs and MeO-PCDEs. The HO-PCDE tested has earlier been reported as an abundant component in a Finnish chlorophenol formulation (Ky-5) and its…

Responses of Lumbriculus variegatus to Activated Carbon Amendments in Uncontaminated Sediments

2012

Activated carbon (AC) amendment is a recently developed sediment remediation method. The strong hydrophobic organic contaminant sorption efficiency of AC has been shown in several studies, but effects on benthic organisms require more investigation. The AC induced effects on egestion rate, growth and reproduction of Lumbriculus variegatus were studied by applying bituminous coal based AC in three different particle size fractions, namely <63 μm (90%, AC(p)), 63-200 μm (AC(m)) and 1000 μm (AC(g)), to natural uncontaminated (HS) and artificial sediment (AS). Egestion rate, growth and reproduction decreased with increasing AC concentration and finer AC particle fractions, effects being stronge…

Determination of organic and inorganic mercury species in water and sediment samples by HPLC on-line coupled with ICP-MS.

2009

This paper describes a preconcentration method for Hg(2+) and MeHg(+) in water samples using sodium diethyldithiocarbamate immobilized in polyurethane foam (PU-NaDDC) and an extraction method for several mercury species in sediment samples, including MeHg(+), EtHg(+) and PhHg(+), which is simple, rapid, and uses a single organic solvent. Separation and measurement were done by high-performance liquid chromatography on-line with inductively coupled plasma mass spectrometry (HPLC/ICP-MS). Initially, the test of recovery was applied using procedures compatible with HPLC. Under the optimum extraction conditions, recoveries of 96.7, 96.3 and 97.3% were obtained for MeHg(+), EtHg(+), and PhHg(+),…