Search results for " sphere"

Microscopic dynamics of molecular liquids and glasses: Role of orientations and translation-rotation coupling

2001

We investigate the dynamics of a fluid of dipolar hard spheres in its liquid and glassy phase, with emphasis on the microscopic time or frequency regime. This system shows rather different glass transition scenarios related to its rich equilibrium behavior which ranges from a simple hard sphere fluid to a long range ferroelectric orientational order. In the liquid phase close to the ideal glass transition line and in the glassy regime a medium range orientational order occurs leading to a softening of an orientational mode. To investigate the role of this mode we use the molecular mode-coupling equations to calculate the spectra $\phi_{lm}^{\prime \prime}(q,\omega)$ and $\chi _{lm}''(q,\ome…

Localization vs. Delocalization in Molecules and Clusters: Electronic and Vibronic Interactions in Mixed Valence Systems

1996

The interplay between electron delocalization and magnetic interactions play a key role in areas as diverse as solid state chemistry (bulk magnetic materials, superconductors,...) [1] and biology (iron-sulfur proteins, manganese-oxo clusters ...) [2]. In molecular inorganic chemistry these two electronic processes have been traditionally studied independently. Thus, the electron dynamics has been extensively investigated in mixedvalence dimers [3] as exemplified by the Creutz-Taube complex [(NH3)5RuII(pyrazine)RuIII(NH3)5]. In this kind of molecular complexes one extra electron is delocalized over two diamagnetic metal sites. Therefore, they constitute model systems for the study of the ele…

A generalization of the Carnahan–Starling approach with applications to four- and five-dimensional hard spheres

2018

Abstract Development of good equations of state for hard spheres is an important task in the study of real fluids. In a way consistent with other theoretical results, we generalize the famous Carnahan–Starling approach for arbitrary dimensions and apply it to four- and five-dimensional hard spheres. We obtain simple and integer representations for virial coefficients of lower orders and accurate equations of state. Since theoretically and practically validated, these results improve understanding of hard sphere fluids.

The heavenly spheres regained

1993

London equation of state for a quantum-hard-sphere system

1994

The London analytical interpolation equation between zero and packing densities for the ground-state energy of a many-boson hard-sphere system is corrected for the reduced mass of a pair of particles in a ``sphere-of-influence'' picture. It is thus brought into good agreement with computer simulations and with experimental results extrapolated out to close packing.

Spacetime Foam Model of the Schwarzschild Horizon

2003

We consider a spacetime foam model of the Schwarzschild horizon, where the horizon consists of Planck size black holes. According to our model the entropy of the Schwarzschild black hole is proportional to the area of its event horizon. It is possible to express geometrical arguments to the effect that the constant of proportionality is, in natural units, equal to one quarter.

Fluids in extreme confinement.

2012

For extremely confined fluids with two-dimensional density $n$ in slit geometry of accessible width $L$, we prove that in the limit $L\to 0$ the lateral and transversal degrees of freedom decouple, and the latter become ideal-gas-like. For small wall separation the transverse degrees of freedom can be integrated out and renormalize the interaction potential. We identify $n L^2 $ as hidden smallness parameter of the confinement problem and evaluate the effective two-body potential analytically, which allows calculating the leading correction to the free energy exactly. Explicitly, we map a fluid of hard spheres in extreme confinement onto a 2d-fluid of disks with an effective hard-core diame…

Generalized Bloch spheres form-qubit states

2006

m-Qubit states are imbedded in $\mathfrak{Cl}_{2^m}$ Clifford algebras. Their probability spectra then depend on $O(2m)$ or $O(2m+1)$ invariants. Parameter domains for $O(2m(+1))-$ vector and tensor configurations, generalizing the notion of a Bloch sphere, are derived.

N-qubit states as points on the Bloch sphere

2009

We show how the Majorana representation can be used to express the pure states of an N-qubit system as points on the Bloch sphere. We compare this geometrical representation of N-qubit states with an alternative one, proposed recently by the present authors.

Polarimetric measurements of single-photon geometric phases

2014

We report polarimetric measurements of geometric phases that are generated by evolving polarized photons along non-geodesic trajectories on the Poincar\'e sphere. The core of our polarimetric array consists of seven wave plates that are traversed by a single photon beam. With this array any SU(2) transformation can be realized. By exploiting the gauge invariance of geometric phases under U(1) local transformations, we nullify the dynamical contribution to the total phase, thereby making the latter coincide with the geometric phase. We demonstrate our arrangement to be insensitive to various sources of noise entering it. This makes the single-beam, polarimetric array a promising, versatile t…