Search results for " tension"
showing 10 items of 270 documents
How surface tension matters in polymer-free graphene transfer
2020
Abstract The main goal of this work is to achieve a direct transfer of graphene and examine the exact effect of surface tension (ST) on graphene during this type of transfer. To reach this target, we designed a specific transfer container with two-sided ports to facilitate replacing liquids underneath graphene and monitor the effect of ST. We prepared liquids with various STs by mixing pure deionized-water with different ratios of isopropanol (IPA). Our results indicate that high ST does not break the graphene structure if graphene has good quality. Besides, a ST gap (STG) can be applied to graphene at a specific level without damaging the graphene monolayer. Comparing those results to the …
Evaluation of interfacial stress transfer efficiency by coating fragmentation test
2007
Probabilistic model of coating fragmentation under uniaxial tensile loading is developed. Analytical expressions of the crack spacing evolution are obtained for small-strain and large-strain fragmentation regimes. The model is applied for coating and interface property identification of several thin brittle coating/polymer substrate systems. An estimate of the stress transfer length, derived from the fragmentation data, is found to correlate with the interfacial shear strength thus suggesting that both parameters reflect an intrinsic property related to the mechanical efficiency of coating/substrate interface.
Hard sphere fluids at a soft repulsive wall: A comparative study using Monte Carlo and density functional methods
2011
Hard-sphere fluids confined between parallel plates at a distance D apart are studied for a wide range of packing fractions including also the onset of crystallization, applying Monte Carlo simulation techniques and density functional theory. The walls repel the hard spheres (of diameter σ) with a Weeks-Chandler-Andersen (WCA) potential V(WCA)(z) = 4ε[(σ(w)/z)(12) - (σ(w)/z)(6) + 1/4], with range σ(w) = σ/2. We vary the strength ε over a wide range and the case of simple hard walls is also treated for comparison. By the variation of ε one can change both the surface excess packing fraction and the wall-fluid (γ(wf)) and wall-crystal (γ(wc)) surface free energies. Several different methods t…
Phase behaviour and interfacial tension of polysiloxane blends
1998
Abstract The cloud point curve for blends of poly(dimethyisiloxane) (PDMS, M w = 2.5kg mol −1 ) and poly(hexylmethylsiloxane) (PHMS, M w = 113kg mol − ] was determined turbidimetrically. The system demixes upon cooling and the UCST amounts to 36°C. The interfacial tension γ was determined at the critical composition for three temperatures by means of a spinning drop tensiometer. The dependence of γ on the reduced critical temperature can be described within experimental error by both the mean field theory and the Ising-3D theory.
Artificial neural network based particle size prediction of polymeric nanoparticles.
2017
Particle size of nanoparticles and the respective polydispersity are key factors influencing their biopharmaceutical behavior in a large variety of therapeutic applications. Predicting these attributes would skip many preliminary studies usually required to optimize formulations. The aim was to build a mathematical model capable of predicting the particle size of polymeric nanoparticles produced by a pharmaceutical polymer of choice. Polymer properties controlling the particle size were identified as molecular weight, hydrophobicity and surface activity, and were quantified by measuring polymer viscosity, contact angle and interfacial tension, respectively. A model was built using artificia…
Testing the concentric-disk tension infiltrometer for field measurement of soil hydraulic conductivity
2010
Abstract The concentric-disk tension infiltrometer (CDTI) may be used to simultaneously measure the confined ( K c ) and the unconfined ( K u ) soil hydraulic conductivity, but it has received little testing. Comparison between K c and K u can be affected by the calculation approach applied to analyze unconfined steady-state infiltration rates. The objectives of this investigation were to: i) establish the effect of the calculation approach on the estimates of K u ; and ii) compare the K c and K u values measured by the CDTI. A clay soil, a structureless sandy loam soil, and a sandy loam soil with a relatively high gravel content were sampled using a disk of radius equal to 107.5 mm, compri…
Classical nucleation theory for the crystallization kinetics in sheared liquids
2019
While statistical mechanics provides a comprehensive framework for the understanding of equilibrium phase behavior, predicting the kinetics of phase transformations remains a challenge. Classical nucleation theory (CNT) provides a thermodynamic framework to relate the nucleation rate to thermodynamic quantities such as pressure difference and interfacial tension through the nucleation work necessary to spawn critical nuclei. However, it remains unclear whether such an approach can be extended to the crystallization of driven melts that are subjected to mechanical stresses and flows. Here, we demonstrate numerically for hard spheres that the impact of simple shear on the crystallization rate…
Interfacial energy effects within the framework of strain gradient plasticity
2009
AbstractIn the framework of strain gradient plasticity, a solid body with boundary surface playing the role of a dissipative boundary layer endowed with surface tension and surface energy, is addressed. Using the so-called residual-based gradient plasticity theory, the state equations and the higher order boundary conditions are derived quite naturally for both the bulk material and the boundary layer. A phenomenological constitutive model is envisioned, in which the bulk material and the boundary layer obey (rate independent associative) coupled plasticity evolution laws, with kinematic hardening laws of differential nature for the bulk material, but of nondifferential nature for the layer…
Spherical microparticles production by supercritical antisolvent precipitation: Interpretation of results
2008
Abstract Supercritical antisolvent micronization has been the subject of many works aimed at the production of precipitates with controlled particle size and morphology. Several morphologies have been observed; but, the production of spherical micrometric particles has been the major objective of most of the studies performed. Therefore, in this work, literature data analysis on spherical and related morphologies has been performed. The ranges of process conditions at which spherical microparticles have been obtained have been listed and discussed. A possible formation mechanism is proposed that is based on the competition between jet break-up and liquid surface tension vanishing characteri…
A new nature of microporous architecture with hierarchical porosity and membrane template via high strain rate collision
2019
Abstract This paper presents the formation of an unusual porous structure at Al/Al interface joined by magnetic pulse welding. The porous structure consists of a hierarchical microporous architecture with pore size of less than 2 µm that represents more than 80% over the whole area, in which 38% of them are sub-micron size pores. It also exhibits ultra-thin wall, sufficiently thin enough to behave as an electron-transparent material with a wall thickness of 50 nm. The formation of this porous structure is attributed to a cavitation process of a molten material in three stages including, (1) nucleation, (2) growth and coalescence and (3) solidification. Further analysis of this cavitation pr…