Search results for " thinning"

1983

The viscosity of solutions of poly(decyl methacrylate)s, PDMA, in 1-pentanol (thermodynamically poor solvent) and in toluence or isooctane (good solvents) was measured up to shear rates of 3 · 104s−1 by means of rotational viscosimeters. The observed pronounced shear thinning is for all solutions well described by the theory of Graessley, with the extension, introduced by Ito. Two parameters, resulting from the evaluation of the flow curves on the basis of the above theory, are discussed: τ0, a characteristic relaxation time of the polymer chain, is found to be in the range of ms. ηfric, a frictional parameter, independent of shear rate, amounts upto 50% of the zero-shear viscosity for the …

Consistency of Carbopol 971-P NF gels and influence of soluble and cross-linked PVP.

2002

A study is made of the polymerization process of polyacrylic acid, commercially known as Carbopol® 971 NF, assessing its consistency as a function of the degree of neutralization at pH values from 3 to 12, approximately. Percentage concentrations ranging from 0.1 to 1.4% (w/w) were studied. The gels obtained were non-Newtonian, and pseudoplastic. As concentration and pH rise, the consistency of the gels increase to a maximum, which appears between pH 6 and 8, allowing their use as vehicles in bioadhesive formulations for mucosal application. Over the increasing viscosity interval, functions were obtained to indicate the consistency of the gel as a function of pH and concentration. Since the…

1993

The viscosities of moderately concentrated solutions of poly(butyl methacrylate)—Mw = 1820 kg/mol–in the thermodynamically good solvent toluene and in the theta solvent 2-propanol were measured up to pressures of 2000 bar as a function of shear rate in the temperature interval from 40 to 70°C. Both systems obey Graessley's equation so that it is possible to obtain the following rheological parameters in addition to the zero-shear viscosity η0 from the dependences . η can be split into an entanglement part ηent plus a frictional contribution ηfric, and the characteristic viscometric relaxation time τ0 becomes accessible. The present results demonstrate that the application of pressure raises…

RHEOLOGICAL BEHAVIOUR OF MICROCRYSTALLINE CELLULOSE HYDROGELS

1992

ABSTRACT An extensive study was made of the rheological behaviour of microcrystal1ine cellulose-sodium carboxymethyl cellulose (MCC-NaCMC) gels at six different concentrations. The effect of agitation time, storage time, shear rate and temperature on the viscosity of these thixotropic gels was analysed, over 7200 resulting values of being available to this effect The pseudoplastic and thixotropic characteristics of the gels was established and a progressive decrease in gel viscosity with increasing storage time was observed, although retaining stability. On the other hand, constant agitation for five minutes was found to reduce gel viscosity by 40 to 50%, regardless of concentration.

Thixotropic Behavior of Salad Dressings Stabilized with Modified Starch, Pectin, and Gellan Gum. Influence of Temperature

2008

The thixotropy of low‐oil salad dressing has been analyzed at different temperatures (8–26°C). The usual formulation containing modified starch (4%) was compared with others in which part of the starch had been substituted by pectin (0.5%) or different concentrations of gellan (0.1 and 0.5%). Up and down flow curves were measured, showing in all cases shear thinning behavior and fitting the Herschel‐Bulkley model. Thixotropic areas enclosed by the up curve and the corresponding different down curves, STh, were obtained. With the aim of establishing comparative results, and since the viscosities were quite different, the parameter considered was relative thixotropic area, SR (%)=100 (STh/Sup…

Viscoelastic properties of concentrated dispersions in water of soy lecithin

2003

Abstract Viscoelastic properties of soy lecithin dispersions at 60, 120, 180 and 240 g l−1 in water have been studied as a function of ionic strength (NaCl concentrations in the range 10−5–10−2 mol l−1) and of preparation method (sonication, freezing–unfreezing). Viscosity measurements of sonicated dispersions in a rotatory viscometer show Newtonian and plastic (Bingham) behavior, whereas the frozen–unfrozen dispersions show a spectacular change in their viscoelastic properties, that is, a non-Newtonian behavior with pseudoplastic characteristics and rheopexy. These properties have been related to electrokinetic characteristics of the segregated vesicles in each case. A decrease in ζ-potent…

Frictional drag between polymer bearing surfaces

2002

Some fundamental features of friction between two polymer bearing surfaces in relative sliding motion are investigated by molecular dynamics simulations. End-tethered and adsorbed polymers are considered under good and poor solvent conditions. The shear stress is measured while varying the solvent's viscosity, surface separation, degree of polymerization and grafting density. For all systems we observe shear thinning that is attributed to the orientation of the chains along the shear direction. This effect is particularly strong for brushes, for which the shear stress during the steady sliding state is mainly determined by the degree of overlap between the brushes.

Frictional Drag Mechanisms between Polymer-Bearing Surfaces

2001

The fundamental features of friction between two polymer-bearing surfaces in relative sliding motion are investigated by molecular dynamics simulation. Adsorbed and grafted polymers are considered in good and bad solutions. The solvent is not treated explicitly but indirectly in terms of a Langevin thermostat. In both systems, we observe shear thinning that is attributed to an orientation of the radius of gyration along the sliding direction. This effect is particularly strong for surfaces bearing polymer brushes. In this case, the shear stresses are mainly determined by the degree of the interpenetration of brushes.

Interrelation between the thermodynamic and viscometric behaviour of aqueous solutions of hydrophobically modified ethyl hydroxyethyl cellulose

2000

Abstract Aqueous solutions of a commercial sample of hydrophobically modified ethyl hydroxyethyl cellulose (HC, Mw=100 kg/mol, nonylphenol substitution ca. 1.7 mol%) were studied with respect to their demixing behaviour and flow characteristics. Phase separation temperatures were measured turbidimetrically and by determining the first discernible macroscopic phase separation. In some cases demixing was also monitored viscometrically. Phase volume ratios yielded a critical polymer concentration of 1.87 wt.% HC (displaced considerably out of the minimum of the demixing curve towards higher polymer concentrations) and a lower critical solution temperature of 47°C. Model calculations of the spi…

Influence of xanthan gum and locust bean gum upon flow and thixotropic behaviour of food emulsions containing modified starch

2007

Abstract Low oil content mayonnaises are food emulsions which exhibit shear thinning and thixotropic behaviour. They include generally modified starch in their formulation. In this work we study the effect of substituting part of this starch with other natural gums, such as xanthan gum or locust bean gum, upon the consistency and stability of the emulsions in relation to stirring. The gels prior to final emulsification have also been analyzed. Steady flow curves of all systems are well described by the Carreau model. The emulsions containing the greatest percentage of gums presented significantly higher viscosity than the reference emulsion and the emulsions containing the synergistic mixtu…