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showing 10 items of 161 documents
Boron-Doped Diamond Electrodes for Electroorganic Chemistry
2011
Boron-doped diamond (BDD) electrodes provide an unusually wide electrochemical window in protic media, since there exist large offset potentials for the evolution of molecular hydrogen and oxygen, respectively. At the anode, alcohols are specifically converted to alkoxyl radicals. These can be used for chemical synthesis. When the enormous reactivity of such intermediate spin centers is not controlled, mineralization or electrochemical incineration dominates. Efficient strategies include either high substrate concentrations or fluorinated alcohols which seem to stabilize the spin centers in the course of reaction.
Addressing subphthalocyanines and subnaphthalocyanines features relevant to fluorescence imaging
2018
International audience; A series of new synthetic subphthalocyanines bear structural features aimed at allowing either fluorescence activation or a bathochromic shift of the absorption band towards the near-infrared window, relevant to optical imaging. X-ray diffraction studies of four subphthalocyanines are reported. Spectrofluorimetric studies on subnaphthalocyanines and activatable subphthalocyanine pro-fluorophores are reported.
Is the tourism–economic growth nexus time-varying? Bootstrap rolling-window causality analysis for the top 10 tourist destinations
2017
This article explores the time-varying causal nexus between tourism development and economic growth for the top 10 tourist destinations in the world, namely China, France, Germany, Italy, Mexico, t...
An Effective Multirestart Deterministic Annealing Metaheuristic for the Fleet Size and Mix Vehicle-Routing Problem with Time Windows
2008
This paper presents a new deterministic annealing metaheuristic for the fleet size and mix vehicle-routing problem with time windows. The objective is to service, at minimal total cost, a set of customers within their time windows by a heterogeneous capacitated vehicle fleet. First, we motivate and define the problem. We then give a mathematical formulation of the most studied variant in the literature in the form of a mixed-integer linear program. We also suggest an industrially relevant, alternative definition that leads to a linear mixed-integer formulation. The suggested metaheuristic solution method solves both problem variants and comprises three phases. In Phase 1, high-quality init…
Self-piercing riveting for aluminium alloys-composites hybrid joints
2008
In the paper, the growing interest on hybrid joints developed between composite panels and aluminium alloys blanks is focused. The self-piercing riveting operation is considered and its feasibility for the proposed joints verified. The most relevant process parameters were investigated in order to determine a suitable process window and, what is more, the mechanical performances of the developed joints were investigated in order to determine process parameters aimed to maximise them. Finally, the failure mechanics of the obtained joints were considered in order to highlight the mechanisms which occur and determine the lost of the load carrying capability of the joints. The developed experim…
Optimal Blankholder Force Path in Sheet Metal Forming Processes: An Al Based Procedure
1999
Abstract Blankholder force plays a fundamental role in the deep drawing process mechanics since it controls, by friction, the material flow into the die cavity. The availability of computer controlled hydraulic presses in the industries promoted a new research field focused on the definition of optimal BHF histories, function of the punch displacement; such studies were aimed to the determination of the so called “process window”, i.e. the BHF path which permits to obtain the maximum height sound component avoiding both wrinkling and tearing. In the paper a design procedure is proposed in order to determine the optimal BHF path in an axisymmetric deep drawing process: in particular, a close…
Estimation of Daily Solar Radiation from Measured Air Temperature Extremes in the Mid-Mediterranean Area
2012
AbstractDaily solar radiation Rs at ground level is a necessary input variable required for the evaluation of evapotranspiration and crop growth, development, and yield-simulation models. Nevertheless, it is measured in few weather stations and at many locations it is not observed; also, available Rs temporal series are generally no longer than a few years. A valid surrogate of Rs measurement is the diurnal air-temperature range (ΔT); indeed, ΔT is inversely proportional to cloudiness and therefore could be a good indicator of atmospheric transmittance. As opposed to Rs, daily maximum and minimum air temperatures are measured at many locations and their observations in developed countries b…
Joint route planning under varying market conditions
2007
PurposeTo provide empirical evidence on the level of savings that can be attained by joint route planning and how these savings depend on specific market characteristics.Design/methodology/approachJoint route planning is a measure that companies can take to decrease the costs of their distribution activities. Essentially, this can either be achieved through horizontal cooperation or through outsourcing distribution to a logistics service provider. The synergy value is defined as the difference between distribution costs in the original situation where all entities perform their orders individually, and the costs of a system where all orders are collected and route schemes are set up simulta…
Multicomponent polymeric micelles based on polyaspartamide as tunable fluorescent pH-window biosensors
2010
Abstract PHEA-PEG 5000 -C 16 is a polyaspartamide polymer with appended hydrophilic PEG 5000 functions and hydrophobic n-C 16 units forming biocompatible micelles with a CAC as low as 1.8 × 10 −7 M. The protonation and acidity constants of the polymer's amino and carboxylic groups have been determined by potentiometric titrations at five different concentrations higher than CAC, finding concentration-independent values. Viscosity and polarity of the micellar core have been investigated by means of fluorescent probes, finding local values comparable to those of pure toluene and to the core of sodium dodecyl sulphate micelles, independently on the protonation degree of the polymer. The fluor…
A micellar multitasking device: sensing pH windows and gauging the lipophilicity of drugs with fluorescent signals.
2010
A multitasking fluorescent device can be obtained by forming micelles of Triton X-100, containing a lipophilic macrocyclic Cu(2+) complex and the coordinating fluorophore Coumarin 343 (C343), which features a COOH moiety. At low pH the two micellised components do not interact, and the fluorescence of Courmarin 343 (C343) is intense. At intermediate pH, C343 is deprotonated and coordinates to the Cu(2+) centre in its apical position, with fluorescence quenching. At higher pH the deprotonated C343 is displaced from Cu(2+) by the formation of an OH(-) complex, and the fluorescence is revived. This allows the system to carry out its first task as it behaves as an "on-off-on" fluorescent sensor…