Search results for "δ"
showing 10 items of 315 documents
Geochemical characterisation of the thermo-mineral waters of Greece
2021
AbstractGeothermal areas of Greece are located in regions affected by recent volcanism and in continental basins characterised by elevated heat flow. Many of them are found along the coast, and thus, water is often saline due to marine intrusion. In the current study, we present about 300 unpublished and literature data from thermal and cold mineral waters collected along Greece. Samples were analysed for major ions, Li, SiO2 and isotopes in water. Measured temperatures range from 6.5 to 98 °C, pH from 1.96 to 11.98, while Total Dissolved Solutes (TDS) from 0.22 to 51 g/L. Waters were subdivided into four main groups: (1) thermal; (2) cold; (3) acidic (pH < 5); and (4) hyperalkaline (pH …
Life history, environment and extinction of the Scallop Carolinapecten Eboreus (Conrad) in the Plio-Pleistocene of the U.S. Eastern Seaboard
2019
Plio-Pleistocene mass extinction of marine bivalves on the U.S. eastern seaboard has been attributed to declines in temperature and primary production. We investigate the relationship of growth rate in the scallop Carolinapecten eboreus to variation in these parameters to determine which contributed to its extinction. We use ontogenetic profiles of shell δ18O to estimate growth rate and seasonal temperature, microgrowth-increment data to validate δ18O-based figures for growth rate, and shell δ13C to supplement assemblage evidence of production. Postlarval growth started in the spring/summer in individuals from the Middle Atlantic Coastal Plain but in the autumn/ winter in some from the Gulf…
An enormous sulfur isotope excursion indicates marine anoxia during the end-Triassic mass extinction
2020
The role of ocean anoxia as a cause of the end-Triassic marine mass extinction is widely debated. Here, we present carbonate-associated sulfate δ34S data from sections spanning the Late Triassic–Early Jurassic transition, which document synchronous large positive excursions on a global scale occurring in ~50 thousand years. Biogeochemical modeling demonstrates that this S isotope perturbation is best explained by a fivefold increase in global pyrite burial, consistent with large-scale development of marine anoxia on the Panthalassa margin and northwest European shelf. This pyrite burial event coincides with the loss of Triassic taxa seen in the studied sections. Modeling results also indica…
Osmium and lithium isotope evidence for weathering feedbacks linked to orbitally paced organic carbon burial and Silurian glaciations
2022
Abstract The Ordovician (∼487 to 443 Ma) ended with the formation of extensive Southern Hemisphere ice sheets, known as the Hirnantian glaciation, and the second largest mass extinction in Earth History. It was followed by the Silurian (∼443 to 419 Ma), one of the most climatically unstable periods of the Phanerozoic as evidenced by several large scale ( > 5 ‰ ) carbon isotope (δ13C) perturbations associated with further extinction events. Despite several decades of research, the cause of these environmental instabilities remains enigmatic. Here, we provide osmium (187Os/188Os) and lithium (δ7Li) isotope measurements of marine sedimentary rocks that cover four Silurian δ13C excursions. Osmi…
Use of stable isotope analysis to evaluate the possible impact of fish migration on a lake biomanipulation
2007
1. A lake restoration project involving mass fish removals was started to improve further the water quality of a lake recovering from severe eutrophication. The effectiveness of such biomanipulation as a lake management option could be compromised if removed fish are rapidly replaced by large-scale immigration from a connected lake. 2. Stable isotope analysis (SIA) was used to examine the migrations of perch (Perca fluviatilis L.) and roach (Rutilus rutilus (L.)) between two connected lakes in central Finland, Jyvasjarvi and the larger Paijanne. Baseline δ15N signatures in primary consumers were significantly higher in Jyvasjarvi and this difference was reflected further up the food chain i…
Cardinal Invariants for the $G_\delta$ topology
2017
We prove upper bounds for the spread, the Lindel\"of number and the weak Lindel\"of number of the $G_\delta$-topology on a topological space and apply a few of our bounds to give a short proof to a recent result of Juh\'asz and van Mill regarding the cardinality of a $\sigma$-countably tight homogeneous compactum.
Isotopic composition of dissolved sulphate and hydrogen sulphide from some thermal springs of Sicily
1982
Samples of some thermal springs from Sicily have been analysed for the isotopic composition of sulphur-bearing species. The values of δ34S(SO42− (range: +7.3, +31.7‰), δ34S(H2S) (range: −12.2, +27.8), δ34S(S°) (range: +1.9, +24.5) and δ18O(SO42−) (range: −2.5, +23.9) obtained show such a remarkable variability in data as to hypothesize different genetic processes concerning these species. Furthermore, from the available experimental data, the relationship between the isotopic composition of the sulphur in the dissolved sulphate and in the associated hydrogen sulphide (ΔSO42− - H2S = 25 – 30‰) seems to indicate the bacterial reduction of sulphate ion as one of the processes most significantl…
The geochemical riddle of “low-salinity gypsum” deposits
2022
International audience; Gypsum makes up about one fifth of giant salt deposits formed by evaporation of seawater throughout Earth’s history. Although thermodynamic calculations and precipitation experiments predict that gypsum precipitates when the salinity of evaporating seawater attains about 110 g kg-1, gypsum deposits of the Mediterranean Salt Giant often bear the geochemical signature of precipitation from less saline water masses. Addressing this geochemical riddle is important because marine gypsum deposition and continental gypsum erosion affect the global carbon cycle. We investigated gypsum deposits formed in the marginal basins of the Mediterranean Sea during the Messinian Salini…
Late Holocene Asian summer monsoon variability reflected byδ18O in tree-rings from Tibetan junipers
2011
[1] Recent warming in High Asia might have a strong impact on Asian summer monsoon variability with consequences for the hydrological cycle. Based on correlations between climate data, the tree-ring δ18O of high-elevation junipers is an indicator of August precipitation. Thus, our 800-year long annually resolved oxygen isotope series reflects long-term variations in summer monsoon activity on the southern Tibetan plateau. Summer precipitation was reduced during 13th–15th centuries and since the 19th century, whereas the Little Ice Age period (15th–19th century) was rather moist. The late 20th century was among the driest periods during the past 800 years, showing a tendency to slightly wett…
How dry was the Younger Dryas? Evidence from a coupled &lt;i&gt;δ&lt;/i&gt;&lt;sup&gt;2&lt;/sup&gt;H–&lt;i&gt…
2019
Abstract. Causes of the Late Glacial to Early Holocene transition phase and particularly the Younger Dryas period, i.e. the major last cold spell in central Europe during the Late Glacial, are considered to be keys for understanding rapid natural climate change in the past. The sediments from maar lakes in the Eifel, Germany, have turned out to be valuable archives for recording such paleoenvironmental changes. For this study, we investigated a Late Glacial to Early Holocene sediment core that was retrieved from the Gemündener Maar in the Western Eifel, Germany. We analysed the hydrogen (δ2H) and oxygen (δ18O) stable isotope composition of leaf-wax-derived lipid biomarkers (n-alkanes C27 an…