Search results for "010401 analytical chemistry"
showing 10 items of 1284 documents
An Advanced Sensor for Particles in Gases Using Dynamic Light Scattering in Air as Solvent
2021
Dynamic Light Scattering is a technique currently used to assess the particle size and size distribution by processing the scattered light intensity. Typically, the particles to be investigated are suspended in a liquid solvent. An analysis of the particular conditions required to perform a light scattering experiment on particles in air is presented in detail, together with a simple experimental setup and the data processing procedure. The results reveal that such an experiment is possible and using the setup and the procedure, both simplified to extreme, enables the design of an advanced sensor for particles and fumes that can output the average size of the particles in air.
Resonance laser ionization spectroscopy of tellurium
2019
Abstract Resonance ionization schemes for tellurium are investigated with a resonance ionization laser ion source and Ti:Sapphire lasers for fundamental research applications. We present the first three-step resonance ionization spectra of atomic Te. Several autoionizing Rydberg series converging to the first excited state of Te+ are observed and assigned to 5p3 (2Do3/2) ns and nd configurations. Our results include confirmation and significant expansion of the Rydberg series previously reported as well as observation of three new series. From the series convergence limits the ionization potential of tellurium is revised to be 72,669.006(42)stat(20)sys cm−1.
Research Regarding the Influence of Raw Material and Knitted Fabric Geometry on the Tensile Strength and Breaking Elongation
2016
Abstract The main purpose of this research paper is to increase the performance of knitting process during socks manufacturing by choosing the right knitted fabric geometry and raw material. On the other side, tests results show the wear resistance regarding mechanical properties like tensile strength and breaking elongation of knitted fabrics for socks. To obtain samples knitted fabric were used several types of some classic yarns, which already use to obtain socks organic also another type of yarns less used: cotton, organic cotton, bamboo viscose, soy + cotton, Tencel. From these yarns the following knitted fabric geometry were obtained: plated single jersey, plated ribb 4:2 and plated p…
Wireless partial discharge tracking on cross-linked polyethylene MV and HV cables
2018
Medium voltage (MV)/high voltage (HV) cable lines are high-value assets and require substantial costs for their installation or replacement. For this reason, the capability to assess the condition of cable lengths and accessories on site is of great importance. Cross-linked polyethylene (XLPE) insulation is extensively used for MV, HV, and extra-high voltage (EHV) class cables [1] thanks to its excellent voltage-endurance and thermomechanical properties. In particular, XLPE-insulated cables feature substantially lower losses, easier manufacturing and jointing procedures, better environmental compatibility, and higher operating temperature compared with impregnated paper cables, which lead t…
Raman spectrum of the high pressure phase of polyethylene
1982
The Raman spectrum of the hexagonal high pressure phase of polyethylene was measured at 5.2 kbar and 240 °C, using a hydrostatic high pressure cell. The spectrum is largely identical to that obtained for the melt. This result indicates that the conformational short range order in the hexagonal phase remains melt —like and is not modified by the overall straightening of chains.
Singular value decomposition approach to the yttrium occurrence in mineral maps of rare earth element ores using laser-induced breakdown spectroscopy
2017
Laser-induced breakdown spectroscopy (LIBS) has been used in analysis of rare earth element (REE) ores from the geological formation of Norra Kärr Alkaline Complex in southern Sweden. Yttrium has been detected in eudialyte (Na15 Ca6(Fe,Mn)3 Zr3Si(Si25O73)(O,OH,H2O)3 (OH,Cl)2) and catapleiite (Ca/Na2ZrSi3O9·2H2O). Singular value decomposition (SVD) has been employed in classification of the minerals in the rock samples and maps representing the mineralogy in the sampled area have been constructed. Based on the SVD classification the percentage of the yttrium-bearing ore minerals can be calculated even in fine-grained rock samples. peerReviewed
Enhanced quantification of wollastonite and calcite in limestone using fluorescence correction based on continuous wavelet transformation for Raman
2020
Raman spectroscopy offers a nondestructive means to identify minerals in rocks, but the ability to use the technology for quantitative mineralogical analysis is limited by fluorescence that can mask the spectral features of minerals. In this paper we apply continuous wavelet transformation (CWT) to remove fluoresence from Raman data acquired from 26 carbonate rock samples. We then record the intensity values of individual spectral features, proxies for mineral abundances, using the original Raman data and the thus inferred CWT data. The intensity values are then compared against the known mineral abundances determined using the scanning electron microscope (SEM) technology. This comparison …
Robotic path planning for non-destructive testing – A custom MATLAB toolbox approach
2016
AbstractThe requirement to increase inspection speeds for non-destructive testing (NDT) of composite aerospace parts is common to many manufacturers. The prevalence of complex curved surfaces in the industry provides motivation for the use of 6 axis robots in these inspections. The purpose of this paper is to present work undertaken for the development of a KUKA robot manipulator based automated NDT system. A new software solution is presented that enables flexible trajectory planning to be accomplished for the inspection of complex curved surfaces often encountered in engineering production. The techniques and issues associated with conventional manual inspection techniques and automated s…
Effect of Different Green Extraction Methods and Solvents on Bioactive Components of Chamomile (Matricaria chamomilla L.) Flowers
2020
Chamomile (Matricaria chamomilla L.) dried flowers contain a group of interesting biologically active compounds such as sesquiterpenes, flavonoids, coumarins, vitamins, phenolic acids and glucosides. Therefore, the aim of the present study was to characterize the composition in bioactive compounds (specialized metabolites) present in water and ethanol extracts of chamomile flowers, together with monitoring the impact of different extraction techniques (conventional vs. ultrasound-assisted extraction (UAE)) on the parameters under investigation. UAE treatment significantly decreased the extraction time of bioactive compounds from herbal material. Polyphenolic compounds content and antioxidan…
Demultiplexing Visible and Near-Infrared Information in Single-Sensor Multispectral Imaging
2016
In this paper, we study a single-sensor imaging system that uses a multispectral filter array to spectrally sample the scene. Our system captures information in both visible and near-infrared bands of the electromagnetic spectrum. Due to manufacturing limitations, the visible filters in this system also transmit the NIR radiation. Similarly, visible light is transmitted by the NIR filter, leading to inaccurate mixed spectral measurements. We present an algorithm that resolves this issue by separating NIR and visible information. Our method achieves this goal by exploiting the correlation of multispectral images in both spatial and spectral domains. Simulation results show that the mean squa…