Search results for "13. Climate action"
showing 10 items of 2386 documents
Palladium-Catalyzed Direct Arylation of Heteroaromatics with Activated Aryl Chlorides Using a Sterically Relieved Ferrocenyl-Diphosphane
2012
International audience; The palladium-catalyzed direct arylations at C3 or C4 positions of heteroaromatics are known to be more challenging than at C2 or C5 positions. Aryl chlorides are also challenging substrates for direct arylation of heteroaromatics. We observed that in the presence of a palladium-catalyst combining only 0.5 mol % of Pd(OAc)2 with the sterically relieved new ferrocenyl diphosphane Sylphos, the direct arylation at C3 or C4 of oxazoles, a benzofuran, an indole, and a pyrazole was found to proceed in moderate to high yields using a variety of electron deficient aryl chlorides. Turnover numbers up to 176 have been obtained with this catalyst. Assessment of the electron-don…
Temperature effects explain continental scale distribution of cyanobacterial toxins
2018
Insight into how environmental change determines the production and distribution of cyanobacterial toxins is necessary for risk assessment. Management guidelines currently focus on hepatotoxins (microcystins). Increasing attention is given to other classes, such as neurotoxins (e.g., anatoxin-a) and cytotoxins (e.g., cylindrospermopsin) due to their potency. Most studies examine the relationship between individual toxin variants and environmental factors, such as nutrients, temperature and light. In summer 2015, we collected samples across Europe to investigate the effect of nutrient and temperature gradients on the variability of toxin production at a continental scale. Direct and indirect…
Recent changes in chironomid communities and hypolimnetic oxygen conditions relate to organic carbon in subarctic ecotonal lakes
2018
A key question in aquatic elemental cycling is related to the influence of bottom water oxygen conditions in regulating the burial and release of carbon under climate warming. In this study, we used head capsules of Chironomidae larvae to assess community and diversity change between the past (estimated as Pre-Industrial Period) and present and to reconstruct changes in hypolimnetic oxygen conditions from 30 subarctic ecotonal lakes (northeastern Lapland) using the top-bottom paleolimnological approach applying surface sediment (topmost 0-2 cm) and reference (4-5 cm) samples. Subsequently, we tested the findings against dissolved organic carbon (DOC) concentration of the sites. We found tha…
Accounting for littoral primary production by periphyton shifts a highly humic boreal lake towards net autotrophy
2016
1. The prevailing view that many humic lakes are net heterotrophic is commonly based on pelagicmeasurements alone. Poor light conditions in humic lakes are assumed to constrain littoral primaryproduction (PP), such that the littoral zone has been considered an insignificant contributor towhole-lake PP. However, that assumption is based on models and inferences from pelagic processeswhich do not take littoral zone structure into account. Many lakes have an extensive ring of aquaticvegetation lying near the water surface, which provides substratum for epiphytic algae under well-illuminated conditions.2. We measured both pelagic and littoral PP and community respiration (CR) in Mekkoj€arvi, a s…
Increasing temperature and productivity change biomass, trophic pyramids and community‐level omega‐3 fatty acid content in subarctic lake food webs
2021
Climate change in the Arctic is outpacing the global average and land-use is intensifying due to exploitation of previously inaccessible or unprofitable natural resources. A comprehensive understanding of how the joint effects of changing climate and productivity modify lake food web structure, biomass, trophic pyramid shape and abundance of physiologically essential biomolecules (omega-3 fatty acids) in the biotic community is lacking. We conducted a space-for-time study in 20 subarctic lakes spanning a climatic (+3.2 degrees C and precipitation: +30%) and chemical (dissolved organic carbon: +10 mg/L, total phosphorus: +45 mu g/L and total nitrogen: +1,000 mu g/L) gradient to test how temp…
Carbon dynamics in highly heterotrophic subarctic thaw ponds
2015
Abstract. Global warming has accelerated the formation of permafrost thaw ponds in several subarctic and arctic regions. These ponds are net heterotrophic as evidenced by their greenhouse gas (GHG) supersaturation levels (CO2 and CH4), and generally receive large terrestrial carbon inputs from the thawing and eroding permafrost. We measured seasonal and vertical variations in the concentration and type of dissolved organic matter (DOM) in five subarctic thaw (thermokarst) ponds in northern Quebec, and explored how environmental gradients influenced heterotrophic and phototrophic biomass and productivity. Late winter DOM had low aromaticity indicating reduced inputs of terrestrial carbon, wh…
Autochthonous organic matter promotes DNRA and suppresses N2O production in sediments of the coastal Baltic Sea
2021
Coastal environments are nitrogen (N) removal hot spots, which regulate the amount of land-derived N reaching the open sea. However, mixing between freshwater and seawater creates gradients of inorganic N and bioavailable organic matter, which affect N cycling. In this study, we compare nitrate reduction processes between estuary and offshore archipelago environments in the coastal Baltic Sea. Denitrification rates were similar in both environments, despite lower nitrate and carbon concentrations in the offshore archipelago. However, DNRA (dissimilatory nitrate reduction to ammonium) rates were higher at the offshore archipelago stations, with a higher proportion of autochthonous carbon. Th…
Biogenic Fenton process - A possible mechanism for the mineralization of organic carbon in fresh waters.
2020
To explore the mechanisms that mineralize poorly bioavailable natural organic carbon (OC), we measured the mineralization of OC in two lake waters over long-term experiments (up to 623 days) at different pH and iron (Fe) levels. Both the microbial and photochemical mineralization of OC was higher at pH acidified to 4 than at the ambient pH 5 or an elevated pH 6. During 244 days, microbes mineralized up to 60% of OC in the 10-mu m filtrates of lake water and more than 27% in the 1-mu m filtrates indicating that large-sized microbes/grazers enhance the mineralization of OC. A reactivity continuum model indicated that the acidification stimulated the microbial mineralization of OC especially i…
Major loss of coralline algal diversity in response to ocean acidification
2021
[Abstract] Calcified coralline algae are ecologically important in rocky habitats in the marine photic zone worldwide and there is growing concern that ocean acidification will severely impact them. Laboratory studies of these algae in simulated ocean acidification conditions have revealed wide variability in growth, photosynthesis and calcification responses, making it difficult to assess their future biodiversity, abundance and contribution to ecosystem function. Here, we apply molecular systematic tools to assess the impact of natural gradients in seawater carbonate chemistry on the biodiversity of coralline algae in the Mediterranean and the NW Pacific, link this to their evolutionary h…
Natural acidification changes the timing and rate of succession, alters community structure, and increases homogeneity in marine biofouling communiti…
2017
Ocean acidification may have far-reaching consequences for marine community and ecosystem dynamics, but its full impacts remain poorly understood due to the difficulty of manipulating pCO2 at the ecosystem level to mimic realistic fluctuations that occur on a number of different timescales. It is especially unclear how quickly communities at various stages of development respond to intermediate-scale pCO2 change and, if high pCO2 is relieved mid-succession, whether past acidification effects persist, are reversed by alleviation of pCO2 stress, or are worsened by departures from prior high pCO2 conditions to which organisms had acclimatized. Here, we used reciprocal transplant experiments al…