Search results for "13C"
showing 10 items of 194 documents
Dissolution mechanism of crystalline cellulose in H3PO4 as assessed by high-field NMR spectroscopy and Fast Field Cycling NMR relaxometry
2009
Many processes have been proposed to produce glucose as a substrate for bacterial fermentation to obtain bioethanol. Among others, cellulose degradation appears as the most convenient way to achieve reliable amounts of glucose units. In fact, cellulose is the most widespread biopolymer, and it is considered also as a renewable resource. Due to extended intra- and interchain hydrogen bonds that provide a very efficient packing structure, however, cellulose is also a very stable polymer, the degradation of which is not easily achievable. In the past decade, researchers enhanced cellulose reactivity by increasing its solubility in many solvents, among which concentrated phosphoric acid (H(3)PO…
Comparison of isotope ratio mass spectrometry and nondispersive isotope-selective infrared spectroscopy for 13C-urea breath test.
1999
The 13C-urea breath test (UBT) is a sensitive and noninvasive method to diagnose Helicobacter pylori infection, but mass spectrometry (IRMS) is very expensive. The aims of this study were to compare the new low-priced infrared spectroscopy with IRMS in detecting the infection and to assess the influence of feeding on test accuracy.One hundred thirty-four patients with dyspeptic symptoms were recruited. Of these, 74 were infected and 60 uninfected on the basis of both CLO-test and histology. A subgroup of 37 patients (22 H. pylori-positive and 15 H. pylori-negative) was studied under fasting and nonfasting conditions on two different days. Duplicate breath samples were analyzed with two IRMS…
Lombards on the move--an integrative study of the migration period cemetery at Szólád, Hungary.
2014
In 2005 to 2007 45 skeletons of adults and subadults were excavated at the Lombard period cemetery at Szólád (6th century A.D.), Hungary. Embedded into the well-recorded historical context, the article presents the results obtained by an integrative investigation including anthropological, molecular genetic and isotopic (δ(15)N, δ(13)C, (87)Sr/(86)Sr) analyses. Skeletal stress markers as well as traces of interpersonal violence were found to occur frequently. The mitochondrial DNA profiles revealed a heterogeneous spectrum of lineages that belong to the haplogroups H, U, J, HV, T2, I, and K, which are common in present-day Europe and in the Near East, while N1a and N1b are today quite rare.…
Maximal Cohen-Macaulay Modules over the Affine Cone of the Simple Node
2005
A concrete description of all graded maximal Cohen-Macaulay modules of rank one and two over the affine cone of the simple node (a non-isolated singularity) is given. For this purpose we construct an alghoritm that provides extensions of MCM modules over an arbitrary hypersurface.
Carbonate precipitation in the alkaline lake Specchio di Venere (Pantelleria Island, Italy) and the possible role of microbial mats
2016
Abstract Alkaline lakes like the hydrothermally affected lake Specchio di Venere (Pantelleria Island, Central Mediterranean) are typical geological settings harbouring calcified microbial mats. The present work is focused on the discrimination between biotic and abiotic processes driving carbonate precipitation in this lake, using hydrochemical, mineralogical and isotopic data. Hydrochemical analyses demonstrate that the lake is nearly 10−fold supersaturated with regard to aragonite and seasonally reaches hydromagnesite supersaturation. Microscopic observations depict organosedimentary laminated structures consisting of microbial communities and aragonitic precipitates, which are rather dis…
Reconstruction of the paleoenvironmental changes around the Miocene-Pliocene boundary along a W-E transect across the Mediterranean
2006
Abstract In order to reconstruct the environmental changes at the end of the Messinian salinity crisis, a multidisciplinary study has been carried out with a high sampling resolution of the late Messinian–early Zanclean (Zone MPl 1) sediments along a West–East Mediterranean transect. The studied examples comprise sections from southern Spain (Vera/Almanzora), Balearic Basin (ODP Site 975), Tyrrhenian Basin (ODP Site 974), Sicily (Eraclea Minoa), Zakynthos (Kalamaki), Corfu (Aghios Stefanos), Crete (Aghios Vlasis). Previously analyzed sections from the Levantine Basin (Cyprus and ODP Sites 968 and 969) are used for comparison. The sections have been correlated using planktonic foraminiferal …
Ostracod palaeolimnological analysis reveals drastic historical changes in salinity, eutrophication and biodiversity loss in a coastal Mediterranean …
2013
The Albufera of Valencia, one of the largest oligohaline coastal lagoons of the Iberian Peninsula, has suffered hydrological and landscape modifications since medieval times. This paleolimnological study clears up the controversy about the factors, which drove the lake to its present state. Lithological descriptions, ostracod paleoassemblages and Cyprideis torosa (Jones, 1850) shell morphological variations and geochemistry (δ18O, δ13C and Sr/Ca) have been used to reconstruct the lake ecosystem evolution during the last two centuries. The sandy sediments at the bottom of L’Antina core (63 cm) presented a typical assemblage of brackish water ostracods, with shell-derived δ18O values, inferre…
Speleothem δ13C record suggests enhanced spring/summer drought in south-eastern Spain between 9.7 and 7.8 ka – A circum-Western Mediterranean anomaly?
2019
South-eastern Spain is one of the driest regions in Europe and thus, prone to drought. Terrestrial climate records covering the late Glacial and Holocene from this area are sparse. Here, we present a flowstone record from Cueva Victoria, south-eastern Spain, which covers the late Glacial (15 ka) to the mid-Holocene (7 ka) including the Younger Dryas (YD). Between the onset of the Bølling/Allerød (B/A) and the early Holocene, flowstone δ18O values progressively decrease in accordance with sea-surface temperatures in the Alboran Sea, indicating an increase in precipitation in south-eastern Spain and a supra-regional signal of North Atlantic temperature change. At the same time, decreasing δ13…
Holocene paleoclimate inferred from salinity histories of adjacent lakes in southwestern Sicily (Italy)
2016
Marked uncertainties persist regarding the climatic evolution of the Mediterranean region during the Holocene. For instance, whether moisture availability gradually decreased, remained relatively constant, or increased during the last 7000 years remains a matter of debate. To assess Holocene limnology, hydrology and moisture dynamics, the coastal lakes Lago Preola and Gorgo Basso, located in southwestern Sicily, were investigated through several stratigraphic analyses of ostracodes, including multivariate analyses of assemblages, transfer functions of salinity, and biochemical analyses of valves (Sr/Ca, δ18O and δ13C). During the early Holocene, the Gorgo Basso and Lago Preola ostracode rec…
Hydrodynamic effects on the origin and quality of organic matter for bivalves: an integrated isotopic, biochemical and transplant study
2006
Different hydrodynamic conditions can affect both the origin and the quality of organic matter available to bivalve molluscs. I chose 2 environments with very different hydrodynamics (a Mediterranean lagoon open to flow and a closed pond), but similar with regard to temperature, salinity, depth, wind exposure and algae coverage, to investigate this. The lagoon was characterised by active flow and bivalve molluscs, whereas the pond was closed off from the lagoon’s main flow but characterised by mussel beds of the highest density ever observed in the western Mediterranean. Biochemical features, 13C and 15N contents of particulate and sedimentary organic matter, and isotopic signatures of domi…