Search results for "2-methylimidazole"
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Ferromagnetic coupling in the malonato-bridged copper(ii) chains [Cu(Im)2(mal)]nand [Cu(2-MeIm)2(mal)]n(H2mal = malonic acid, Im = imidazole and 2-Me…
2002
Two new malonato-bridged copper(II) complexes of formula [Cu(Im)2(mal)]n (1) and [Cu(2-MeIm)2(mal)]n (2) (Im=imidazole, 2-MeIm=2-methylimidazole and mal=malonate dianion) have been prepared and their structures solved by X-ray diffraction methods. The [Cu(Im)2(mal)] and [Cu(2-MeIm)2(mal)] neutral entities act as monodentate ligands towards the adjacent copper(II) units through one of the two carboxylate groups, the OCO bridge exhibiting an anti-anti conformation. The environment of each copper atom in 1 and 2 is distorted square pyramidal: two carboxylate oxygen atoms from a bidentate malonate and two nitrogen atoms from two imidazole (1) or 2-methylimidazole (2) ligands form the equatorial…
Crystal structure of bis-(2-methyl-1H-imidazole-κN (3))(meso-tetra-p-tol-ylporphyrinato-κ(4) N)iron(III) perchlorate tetra-hydro-furan sesquisolvate.
2016
The crystal structure of the six-coordinate, highly ruffled, ferric porphyrinate bis(2-methylimidazole)[meso-tetrakis(p-tolyl)porphyrinato]iron(III) perchlorate is reported.
CCDC 193605: Experimental Crystal Structure Determination
2003
Related Article: J.Sanchiz, Y.Rodriguez-Martin, C.Ruiz-Perez, A.Mederos, F.Lloret, M.Julve|2002|New J.Chem.|26|1624|doi:10.1039/b201849g