Search results for "4-Triazole-3"

showing 4 items of 4 documents

Base-Controlled Regiospecific Mono-Benzylation/Allylation and Diallylation of 4-Aryl-5-indolyl-1,2,4-triazole-3-thione : Thio-Aza Allyl Rearrangement

2023

The regiospecific S-benzylation/allylation of two 4-aryl-5-indolyl-1,2,4-triazole-3-thione precursors was carried out using Et3N as a base. Allyl group migration from exocyclic sulfur to the triazole nitrogen (N3) was successfully achieved in a short time via thermal fusion without the need for any catalyst. The allylation of indole nitrogen, along with exocyclic sulfur or triazole nitrogen (N3), was carried out using K2CO3 as stronger base. S,N-Diallylated products were converted to N,N-diallylated analogues using a simple fusion approach. Structural analyses of the two newly synthesized hybrids 2b and 5b investigated via the X-ray diffraction of a single crystal combined with Hirshfeld ca…

124-triazole-3-thioneX-ray single-crystal analysisthio-aza allyl rearrangementheterosykliset yhdisteetallylationorgaaniset yhdisteetröntgenkristallografia
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CCDC 901545: Experimental Crystal Structure Determination

2014

Related Article: J.Hernandez-Gil,A.Ribes,L.Coga,S.Ferrer,A.Castineiras,M.Liu-Gonzalez,F.Llore,J.C.Mareque-Rivas|2014|Inorg.Chem.|53|578|doi:10.1021/ic4027249

Space GroupCrystallography(mu2-1H-124-Triazole-35-diamine)-diaqua-tetrakis(nitrato-O)-bis(110-phenanthroline)-di-copper(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 671724: Experimental Crystal Structure Determination

2008

Related Article: M.Viciano, M.Sanau, E.Peris|2007|Organometallics|26|6050|doi:10.1021/om7007919

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu2-chloro)-bis(mu2-124-trimethyl-124-triazole-35-diyl)-tetrakis(eta6-1-isopropyl-4-methylbenzene)-tetra-ruthenium tris(tetrafluoroborate) chlorideExperimental 3D Coordinates
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CCDC 907781: Experimental Crystal Structure Determination

2013

Related Article: Javier Hernández-Gil, Sacramento Ferrer, Nuria Cabedo, María Pilar López-Gresa, Alfonso Castiñeiras, Francesc Lloret|2013|J.Inorg.Biochem.|125|50|doi:10.1016/j.jinorgbio.2013.04.007

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstetrakis(mu~2~-acetato)-bis(1-(2-naphthylsulfonyl)-1H-124-triazole-35-diamine)-di-copper 1-(2-naphthylsulfonyl)-1H-124-triazole-35-diamineExperimental 3D Coordinates
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