Search results for "40"

showing 10 items of 17345 documents

Binding abilities of polyaminocyclodextrins: polarimetric investigations and biological assays.

2017

Three polyaminocyclodextrin materials, obtained by direct reaction between heptakis(6-deoxy-6-iodo)-β-cyclodextrin and the proper linear polyamines, were investigated for their binding properties, in order to assess their potential applications in biological systems, such as vectors for simultaneous drug and gene cellular uptake or alternatively for the protection of macromolecules. In particular, we exploited polarimetry to test their interaction with some model p-nitroaniline derivatives, chosen as probe guests. The data obtained indicate that binding inside the host cavity is mainly affected by interplay between Coulomb interactions and conformational restraints. Moreover, simultaneous i…

nitroanilineaminocyclodextrins; binding properties; nitroanilines; pDNA; polarimetry; supramolecular chemistrySupramolecular chemistryaminocyclodextrins010402 general chemistry01 natural sciencesFull Research Papersupramolecular chemistryaminocyclodextrinlcsh:QD241-441lcsh:Organic chemistrypDNABioassaybinding propertielcsh:Sciencepolarimetry010405 organic chemistryChemistryBinding propertiesOrganic ChemistryCationic polymerizationnitroanilines0104 chemical sciencesChemistrybinding propertiesPolynucleotideBiophysicslcsh:QpUC19Direct reactionMacromoleculeBeilstein journal of organic chemistry
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The interactive effects of various nitrogen fertiliser formulations applied to urine patches on nitrous oxide emissions in grassland

2017

AbstractPasture-based livestock agriculture is a major source of greenhouse gas (GHG) nitrous oxide (N2O). Although a body of research is available on the effect of urine patch N or fertiliser N on N2O emissions, limited data is available on the effect of fertiliser N applied to patches of urinary N, which can cover up to a fifth of the yearly grazed area. This study investigated whether the sum of N2O emissions from urine and a range of N fertilisers, calcium ammonium nitrate (CAN) or urea ± urease inhibitor ± nitrification inhibitor, applied alone (disaggregated and re-aggregated) approximated the N2O emission of urine and fertiliser N applied together (aggregated). Application of fertili…

nitrous oxide emission factors[ SDV.SA.SDS ] Life Sciences [q-bio]/Agricultural sciences/Soil studychemistry.chemical_elementUrine010501 environmental sciences01 natural sciencesGrasslandurease inhibitorchemistry.chemical_compoundPlant sciencelcsh:Agriculture (General)0105 earth and related environmental sciencesgeographygeography.geographical_feature_categoryEcology[ SDV.SA.STA ] Life Sciences [q-bio]/Agricultural sciences/Sciences and technics of agriculture04 agricultural and veterinary sciencesNitrous oxideequipment and suppliesNitrogenlcsh:S1-972urineAgronomyInteractive effectschemistry040103 agronomy & agriculture0401 agriculture forestry and fisheriesEnvironmental sciencenitrification inhibitorAnimal Science and Zoologynitrogen fertiliserAgronomy and Crop ScienceFood ScienceIrish Journal of Agricultural and Food Research
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Vibrational Spectrum of HXeSH revisited : Combined computational and experimental study

2020

Vibrational spectrum of HXeSH embedded in low-temperature matrix is experimentally studied. To support the spectrum interpretation, anharmonic vibrational analysis is performed using different models and basis sets and the data is compared with previous experimental and theoretical analyses. Computations of overtones and combination modes allowed for new band assignments. The HXeSH molecule exhibits high anharmonicity similarly as other molecules from the noble-gas hydride family. Comparison of the employed computational methods shows once again that the modelling of the noble-gas compounds faces theoretical challenges to yield quantitatively reliable results. peerReviewed

noble gasXenonInfraredspektroskopiaGeneral Physics and AstronomyInfrared spectroscopyksenonhydride02 engineering and technology010402 general chemistry01 natural sciencesMolecular physicsMatrix (mathematics)värähtelytinfrapunasäteilyMoleculePhysical and Theoretical ChemistryPhysics::Chemical PhysicsPhysicsBasis (linear algebra)anharmonicityAnharmonicityMatrix isolationmatrix isolationjalokaasut021001 nanoscience & nanotechnologylaskennallinen kemiacomputational chemistryvibrational spectroscopy0104 chemical sciencesinfrared spectrumYield (chemistry)hydridit0210 nano-technology
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Computational Structures and SAPT Interaction Energies of HXeSH···H2Y (Y=O or S) Complexes

2018

Ab initio calculations of the structures, vibrational spectra and supermolecular and symmetry-adapted perturbation theory (SAPT) interaction energies of the HXeOH and HXeSH complexes with H2O and H2S molecules are presented. Two minima already reported in the literature were reproduced and ten new ones were found together with some transition states. All complexes show blue shift in Xe&ndash

noble gasvuorovaikutusAb initiointeraction02 engineering and technology010402 general chemistry01 natural sciencesSpectral lineInorganic ChemistryAb initio quantum chemistry methodslcsh:Inorganic chemistryPhysics::Atomic and Molecular ClustersMoleculePhysics::Chemical PhysicsPerturbation theoryta116Astrophysics::Galaxy Astrophysicshydrogen bondSAPTChemistryHydrogen bondkompleksiyhdisteetnon-covalent021001 nanoscience & nanotechnologylcsh:QD146-197Transition state0104 chemical sciencesChemical physicsAb initio0210 nano-technologyDispersion (chemistry)complexInorganics
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Generalized Noise Study of Solid-State Nanopores at Low Frequencies.

2017

Nanopore technology has been extensively investigated for analysis of biomolecules, and a success story in this field concerns DNA sequencing using a nanopore chip featuring an array of hundreds of biological nanopores (BioNs). Solid-state nanopores (SSNs) have been explored to attain longer lifetime and higher integration density than what BioNs can offer, but SSNs are generally considered to generate higher noise whose origin remains to be confirmed. Here, we systematically study low-frequency (including thermal and flicker) noise characteristics of SSNs measuring 7 to 200 nm in diameter drilled through a 20-nm-thick SiNx membrane by focused ion milling. Both bulk and surface ionic curren…

noiseta221Analytical chemistryIonic bondingBioengineering02 engineering and technologyElectrolyte010402 general chemistry01 natural sciencesNoise (electronics)Flicker noiseInstrumentationFluid Flow and Transfer Processesta114ChemistryProcess Chemistry and TechnologyFlicker021001 nanoscience & nanotechnology0104 chemical sciencesNanoporenanopore technologyChemical physicssolid-state nanoporesIon milling machine0210 nano-technologyVoltageACS sensors
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Costrutti con 'c'è' e nome proprio in una telecronaca sportiva: configurazioni funzionali e valori testuali

2010

nomi propri costrutti esistenziali lingua parlata470 Latin & Italic languages460 Spanish & Portuguese languages410 Linguistics450 Italian Romanian & related languages800 Literature rhetoric & criticism440 French & related languages10103 Institute of Romance StudiesSettore L-LIN/01 - Glottologia E Linguistica
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Lajianalyysi 400 m aitajuoksusta ja valmennuksen ohjelmointi

2015

Pitkä aitajuoksumatka 400 m aidat on laji, jossa juostaan yksi aidattu ratakierros yleisurheilukentän juoksuradalla. Lähtö tapahtuu lähtötelineistä. Alkusileä on 45 m pitkä, aitoja on yhteensä 10 kappaletta, aitavälien pituus on 35 m ja loppusileä on 40 m. Biomekaniikka. Hyvässä pikajuoksussa lantio on ylhäällä ja edessä. Jalka painetaan kehon alle päkiä edellä, ja askelkontakti on pyyhkäisevä kuopaisu. Pikajuoksun askel kontakti- ja lentovaiheineen voidaan jakaa neljään osaan: 1) etummaiseen lentovaiheeseen, 2) jarrutusvaiheeseen, 3) työntövaiheeseen ja 4) takimmaiseen lentovaiheeseen. Juoksunopeus on askelpituuden ja askeltiheyden tulo. 400 m aitajuoksussa askelkontakti kestää keskimäärin…

nopeusliikkuvuusurheilupsykologiakuormitusfysiologia400 m aitajuoksuvoimakestävyysbiomekaniikkaohjelmointivalmennusoppi
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Precise Determination of the Unperturbed 8B Neutrino Spectrum

2012

The measurement was performed at the Kernfysisch Versneller Instituut (KVI) at the University of Groningen, The Netherlands.; A measurement of the final state distribution of the 8B $\beta$ decay, obtained by implanting a 8B beam in a double-sided silicon strip detector, is reported here. The present spectrum is consistent with a recent independent precise measurement performed by our collaboration at the IGISOL facility, Jyvâskylä [O. S. Kirsebom et al., Phys. Rev. C 83, 065802 (2011)]. It shows discrepancies with previously measured spectra, leading to differences in the derived neutrino spectrum. Thanks to a low detection threshold, the neutrino spectrum is for the first time directly ex…

nuclear spectroscopyneutrino oscillationsPhysics::Instrumentation and Detectorsaccelerator-based physics[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]kiihdytinpohjainen fysiikkaKVIydinrakenne8Bnuclear structureydinspektroskopiaimplantationydinfysiikka23.40.Bw 26.65.+t 27.20.+nbeta-decay
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Nutrient sensing: What can we learn from different tastes about the nutrient contents in today's foods?

2019

Abstract Tastes are often described as having a nutrient-signaling function eliciting expectations about the food and its nutrient content. The objectives of this work was to investigate correlations between taste intensity and nutrient content, to evaluate the impact of competing tastes on these relationships, and to know if the content in certain nutrients could be inferred from a combination of tastes. The Food Taste Database (Martin et al., 2014) and a French Food Composition table (ANSES-Ciqual) were used to obtain a dataset combining sensory and nutritional information for 365 foods. Our results confirm the existence of several taste-nutrient relationships previously suggested by othe…

nutrient sensingTaste030309 nutrition & dieteticsUmamiNutrient sensing03 medical and health sciences0404 agricultural biotechnologyNutrientFood sciencefood taste data baseMathematics0303 health sciencesnutrient contentNutrition and Dieteticsbusiness.industryFood composition dataSweet taste04 agricultural and veterinary sciences040401 food sciencetaste intensityTaste intensityFood processingrelationshipbusiness[SDV.AEN]Life Sciences [q-bio]/Food and NutritionFood Science
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Taikoja ja tenhoa Oxfordissa: raportti Living in a Magical World: Inner Lives -konferenssista ja Spellbound-näyttelystä

2018

Oxfordissa pidettiin 17.–19. syyskuuta kuluvan vuoden merkittävin magian, esoteeristen alojen ja taikauskon tutkimuksen kansainvälinen konferenssi Living in a Magical World: Inner Lives, 1300–1900. Samaan aikaan Oxfordin Ashmolean Museumissa pyörii yhteistyössä konferenssijärjestäjien kanssa kuratoitu näyttely Spellbound. Magic, Ritual, Witchcraft (31.8.2018 – 6.1.2019), jossa on esillä laaja valikoima magian ja taikauskon historiaa keskiajalta 1900-luvulle. Lyhyt reportaasi arvioi sekä konferenssin että näyttelyn antia.

näyttelytresearchkokouksetta6132meetings (arranged events)Kentältä & arkistostaexhibitionsart historytaidehistoriata616magiatutkimuslcsh:NX440-632Oxfordlcsh:History of the artsmagicTahiti
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