Search results for "41"

What determines the duration of a fiscal consolidation program?

2013

This paper assesses the determinants of the length of fiscal consolidation using annual data for 17 industrial countries over the period 1978-2009. Relying on a narrative approach to identify fiscal consolidation episodes, we show that fiscal variables (such as the budget deficit and the level of public debt) and economic factors (such as the degree of openness, the inflation rate, the interest rate and per capita GDP) are crucial for the fiscal consolidation process. Additionally, we employ duration analysis over a set of consolidation spells and find that, as time goes by, the likelihood of a fiscal consolidation ending is higher. However, the hazard function is not monotonic: indeed, it …

The Participation of 3,3,3-Trichloro-1-nitroprop-1-ene in the [3 + 2] Cycloaddition Reaction with Selected Nitrile N-Oxides in the Light of the Exper…

2021

The regioselective zw-type [3 + 2] cycloaddition (32CA) reactions of a series of aryl-substituted nitrile N-oxides (NOs) with trichloronitropropene (TNP) have been both experimentally and theoretically studied within the Molecular Electron Density Theory (MEDT). Zwitterionic NOs behave as moderate nucleophiles while TNP acts as a very strong electrophile in these polar 32CA reactions of forward electron density flux, which present moderate activation Gibbs free energies of 22.8–25.6 kcal·mol−1 and an exergonic character of 28.4 kcal·mol−1 that makes them irreversible and kinetically controlled. The most favorable reaction is that involving the most nucleophilic MeO-substituted NO. Despite P…

Metal-Organic Frameworks as Versatile Heterogeneous Solid Catalysts for Henry Reactions

2021

Metal–organic frameworks (MOFs) have become one of the versatile solid materials used for a wide range of applications, such as gas storage, gas separation, proton conductivity, sensors and catalysis. Among these fields, one of the more well-studied areas is the use of MOFs as heterogeneous catalysts for a broad range of organic reactions. In the present review, the employment of MOFs as solid catalysts for the Henry reaction is discussed, and the available literature data from the last decade are grouped. The review is organized with a brief introduction of the importance of Henry reactions and structural properties of MOFs that are suitable for catalysis. The second part of the review dis…

Restricting Magnetic Interaction Pathways in Polyoxometalate Salts of Cationic Nitronyl Nitroxide Free Radicals

2004

Abstract : Salts 1 and 2 that combine the [W 6 O 19 ] 2- Lindqvist anion with the cationic nitronyl nitroxide (NN) free radicals p -MepyNN + and n Bu 3 NCH 2 NN + , respectively, have been synthesized and their structural and magnetic properties have been studied. Keywords: Nitroxide radicals, polyoxometalates, magnetism. Introduction Ferromagnetism based on purely organic materials has raised a lot of interest during the last decade [1]. Most of the studies have been performed with nitronyl nitroxide (NN) radicals due to their persistence, stability and ease of functionalization [2]. Bulk ferromagnetism in these compounds arises from ferromagnetic interactions between open-shell molecules …

Oscillation theorems for second-order nonlinear neutral delay differential equations

2014

Published version of an article in the journal: Abstract and Applied Analysis. Also available from the publisher at: http://dx.doi.org/10.1155/2014/594190 Open Access We analyze the oscillatory behavior of solutions to a class of second-order nonlinear neutral delay differential equations. Our theorems improve a number of related results reported in the literature.

Promoting health in everyday settings: Opportunities and challenges

2014

Performance of a high repetition pulse rate laser system for in-gas-jet laser ionization studies with the Leuven laser ion source @ LISOL

2012

The Leuven Isotope Separator On-Line (LISOL) facility at the Cyclotron Research Center (CRC) Louvain-la-Neuve; The laser ionization efficiency of the Leuven gas cell-based laser ion source was investigated under on- and off-line conditions using two distinctly different laser setups: a low-repetition rate dye laser system and a high-repetition rate Ti:sapphire laser system. A systematic study of the ion signal dependence on repetition rate and laser pulse energy was performed in off-line tests using stable cobalt and copper isotopes. These studies also included in-gas-jet laser spectroscopy measurements on the hyperfine structure of 63Cu. A final run under on-line conditions in which the ra…

The utmost ends of the nuclear fuel cycle: Finnish perceptions of the risks of uranium mining and nuclear waste management

2013

There has been substantial social scientific research to determine how people perceive the risks of nuclear power, wastes, and waste management, but not much attention has been given to risk perceptions of other types of nuclear activities. Knowledge about attitudes towards uranium mining and exploitation is increasing, and more attention should be paid to how people perceive the risks of both ends of the nuclear fuel cycle. Therefore, the aim of this paper is to analyze the risk perceptions towards nuclear waste and uranium mining and how these perceptions relate to each other. The analysis is based on Finnish survey data (N = 1180) gathered in 2007. Renewed international interest in nucle…

Weak A-frames and weak A-semi-frames

2021

After reviewing the interplay between frames and lower semi-frames, we introduce the notion of lower semi-frame controlled by a densely defined operator $A$ or, for short, a weak lower $A$-semi-frame and we study its properties. In particular, we compare it with that of lower atomic systems, introduced in (GB). We discuss duality properties and we suggest several possible definitions for weak $A$-upper semi-frames. Concrete examples are presented.

Recent Advances in Biotechnological Methods for Wheat Gluten Immunotoxicity Abolishment – a Review

2021

Due to the increasing incidence of gluten intolerance, researchers are focusing on finding ways to eliminate immunotoxicity of wheat, this would allow the use of wheat products for gluten-intolerant consumers. The article reviews recent studies on biotechnological methods to eliminate and reduce the immunogenicity of wheat products. So far, many gluten removal methods have been proposed, but their efficacy levels were quite different. Enzymatic treatment of gluten fragments can be considered the simplest and non-invasive tool to eliminate the toxicity of gliadins and glutenins. For this purpose, various endogenous enzymes derived from cereals, and also those of bacterial, fungal, plant, and…