Search results for "41"

showing 10 items of 3365 documents

Two-Dimensional Carbon: A Review of Synthesis Methods, and Electronic, Optical, and Vibrational Properties of Single-Layer Graphene

2019

Graphite has been widely used by humans for a large part of their history. Nevertheless, it has only recently been possible to isolate its basic unit: carbon atoms arranged in a honeycomb structure on a single plane, namely graphene. Since its discovery, many techniques have been developed and improved to properly synthesize graphene and its derivatives which are part of the novel class of two-dimensional materials. These advanced materials have imposed themselves in nanotechnology thanks to some outstanding physical properties due to their reduced dimensions. In the case of graphene, its reduced dimension gives rise to a high electrical mobility, a large thermal conductivity, a high mechan…

Solid-state physics2D materialNanotechnology02 engineering and technology010402 general chemistry01 natural sciencesNanomaterialslaw.inventionlcsh:QD241-441symbols.namesakeThermal conductivitylcsh:Organic chemistrylawGraphiteSpectroscopyGraphenecarbongrapheneGeneral Medicine021001 nanoscience & nanotechnologymaterial science0104 chemical sciencesHoneycomb structureRaman spectroscopysymbolsnanomaterial0210 nano-technologyRaman spectroscopy
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Host–guest complexes of conformationally flexible C-hexyl-2-bromoresorcinarene and aromatic N-oxides: solid-state, solution and computational studies

2018

Host–guest complexes of C-hexyl-2-bromoresorcinarene (BrC6) with twelve potential aromatic N-oxide guests were studied using single crystal X-ray diffraction analysis and 1H NMR spectroscopy. In the solid state, of the nine obtained X-ray crystal structures, eight were consistent with the formation of BrC6-N-oxide endo complexes. The lone exception was from the association between 4-phenylpyridine N-oxide and BrC6, in that case the host forms a self-inclusion complex. BrC6, as opposed to more rigid previously studied C-ethyl-2-bromoresorcinarene and C-propyl-2-bromoresorcinarene, undergoes remarkable cavity conformational changes to host different N-oxide guests through C–H···π(host) intera…

Solid-stateCrystal structure010402 general chemistry01 natural scienceslcsh:QD241-441lcsh:Organic chemistryPolarizabilitysupramolekulaarinen kemiaresorcinareneshost–guest chemistryHost–guest chemistrylcsh:Scienceta116Biochemistry Biophysics and Structural BiologyC–H···π Interactions010405 organic chemistryChemistryOrganic Chemistryendo/exo complexationSolution phaseditopic receptors0104 chemical sciencesaromatic N-oxidesChemistryCrystallographyProton NMRPolarlcsh:QSingle crystalBeilstein Journal of Organic Chemistry
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The Role of Eucalyptus Species on the Structural and Thermal Performance of Cellulose Nanocrystals (CNCs) Isolated by Acid Hydrolysis

2022

Cellulose nanocrystals (CNCs) are attractive materials due to their renewable nature, high surface-to-volume ratio, crystallinity, biodegradability, anisotropic performance, or available hydroxyl groups. However, their source and obtaining pathway determine their subsequent performance. This work evaluates cellulose nanocrystals (CNCs) obtained from four different eucalyptus species by acid hydrolysis, i.e., E. benthamii, E. globulus, E. smithii, and the hybrid En × Eg. During preparation, CNCs incorporated sulphate groups to their structures, which highlighted dissimilar reactivities, as given by the calculated sulphate index (0.21, 0.97, 0.73 and 0.85, respectively). Although the impact o…

Solucions polimèriquesQD241-441cellulose nanocrystals (CNC); eucalyptus; crystallinity; thermal stability; kinetic analysiseucalyptusPolymers and Plasticskinetic analysisOrganic chemistryCristallsGeneral Chemistrycellulose nanocrystals (CNC)Materialscrystallinitythermal stabilityPolymers
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Carbon Nanomaterial Doped Ionic Liquid Gels for the Removal of Pharmaceutically Active Compounds from Water.

2019

Due to large drug consumption, pharmaceutically active compounds (PhACs) can be found as water contaminants. The removal of PhACs is a significant issue, as they can easily overtake traditional purification methods. Because of their surface properties, carbon nanomaterials are among the most efficient materials able to adsorb PhACs. However, their limitation is their recovery after use and their possible leakage into the aquatic system. Consequently, new hybrid supramolecular ionic liquid gels (HILGs) have been designed for the adsorption of some antibiotic drugs (ciprofloxacin and nalidixic acid) from water. The chemical&ndash

SorbentSupramolecular chemistryPharmaceutical ScienceIonic Liquids02 engineering and technologyCarbon nanotube010501 environmental sciences01 natural sciencesWaste Disposal FluidArticleAnalytical Chemistrylaw.inventionWater Purificationlcsh:QD241-441chemistry.chemical_compoundColloidAdsorptionsupramolecular gelRheologylcsh:Organic chemistrylawDrug DiscoveryHumanscarbon nanotubePhysical and Theoretical Chemistryionic liquid0105 earth and related environmental sciencescarbon nanotubesGraphenepollutant adsorptionOrganic Chemistrygraphenesupramolecular gelsWaterSettore CHIM/06 - Chimica Organica021001 nanoscience & nanotechnologyCarbonNanostructureswastewater treatmentBiodegradation EnvironmentalchemistryChemical engineeringChemistry (miscellaneous)Ionic liquidMolecular MedicineAdsorption0210 nano-technologyGelsWater Pollutants ChemicalMolecules (Basel, Switzerland)
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CCDC 706487: Experimental Crystal Structure Determination

2009

Related Article: G.Podoprygorina, M.Bolte, V.Bohmer|2009|Org.Biomol.Chem.|7|1592|doi:10.1039/b819710e

Space GroupCrystallography(11-Iodo-23293540-tetranitro-4445-dipropoxy-319-dioxa-715-diazaheptacyclo[19.15.7.1^913^.1^2731^.1^3842^.0^233^.0^2025^]hexatetraconta-19(46)101220222427(45)2830333538(44)3941-pentadecaene-814-dione) tetrahydrofuran solvate monohydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1505706: Experimental Crystal Structure Determination

2016

Related Article: Disha Mungalpara, Harald Kelm, Arto Valkonen, Kari Rissanen, Sandro Keller, Stefan Kubik|2017|Org.Biomol.Chem.|15|102|doi:10.1039/C6OB02172G

Space GroupCrystallography(RRR)-61830-trimethyl-34581516172027282932373941-pentadeca-azaheptacyclo[31.3.1.125.1913.11417.12125.12629]dotetraconta-1(37)2(42)39(41)101214(40)1521(39)222426(38)273335-pentadecaene-71931-trione dimethyl sulfoxide solvate hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1826427: Experimental Crystal Structure Determination

2018

Related Article: Jie‐Shun Cui, Qian‐Kai Ba, Hua Ke, Arto Valkonen, Kari Rissanen, Wei Jiang|2018|Angew.Chem.,Int.Ed.|57|7809|doi:10.1002/anie.201803349

Space GroupCrystallography10163642-tetrabutoxy-28505456-tetraoxa-1339-diazatridecacyclo[43.7.1.1351.12327.12529.027.0611.01520.01924.03237.03355.04146.04953]hexapentaconta-246810151719212329(55)303234364143454749(53)-icosaene dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1816643: Experimental Crystal Structure Determination

2018

Related Article: Ben-Lin, Hu Ke Zhang, Cunbin An, Dieter Schollmeyer, Wojciech Pisula, Martin Baumgarten|2018|Angew.Chem.,Int.Ed.|57|12375|doi:10.1002/anie.201803230

Space GroupCrystallography1117232941475359-octakis((2-[triisopropylsilyl]ethynyl))-2050-dithia-3715192125333745495155-dodecaazaheptadecacyclo[37.21.2.2927.0238.0436.0634.0832.01426.01624.01822.04362.04456.04654.04852.05761.01364.03163]tetrahexaconta-1(61)246(34)79(64)1012141618212325272931(63)32353739(62)40424446485153555759-hentriacontaene tetrahydrofuran solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1884544: Experimental Crystal Structure Determination

2019

Related Article: Morten K. Peters, Sebastian Hamer, Torben Jäkel, Fynn Röhricht, Frank D. Sönnichsen, Carolina von Essen, Manu Lahtinen, Christian Naether, Kari Rissanen, Rainer Herges|2019|Inorg.Chem.|58|5265|doi:10.1021/acs.inorgchem.9b00349

Space GroupCrystallography3645-bis(26-dichlorophenyl)-8122024-tetraoxa-15161750515253-heptaazanonacyclo[29.9.9.13235.13740.14144.14649.027.01418.02530]tripentaconta-1(40)246141725272931333537(52)384143454749-nonadecaene-1319-dione di-isopropyl ether solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 149239: Experimental Crystal Structure Determination

2001

Related Article: S.Mahboobi, I.Dechant, H.Reindl, H.Pongratz, A.Popp, D.Schollmeyer|2000|J.Heterocycl.Chem.|37|307|doi:10.1002/jhet.5570370215

Space GroupCrystallography439-Dimethyl-1414293942-hexaazaoctacyclo-(40.2.2.0^26^.0^715^.0^813^.0^2836^.0^3035^.0^3741^)hexatetraconta-2(6)7(15)8(13)91128(36)30(35)313337(41)-decaene-353840-tetraoneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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