Search results for "41"
showing 10 items of 3365 documents
Overcoming Barriers to Transnational Organizing Through Identity Work : Finnish-Estonian Trade Union Cooperation
2018
This article analyses a project by Finnish and Estonian unions to adopt ‘organizing model’ strategies through establishing the transnational ‘Baltic Organising Academy’. Initially aimed at Estonian workplaces, successful campaigns inspired Finnish unions to copy the model in Finland. This cooperation was originally motivated by labour market interdependence between the two countries, and the failure of past social-partnership oriented union strategies in Estonia. The willingness of Finnish and Estonian unions to commit resources to transnational cooperation around an ‘organizing model’ marks a dramatic departure from the unions’ previous strategies. This change was accomplished by transnati…
Uutta tutkimustietoa iäkkäiden sosiaalisesta hyvinvoinnista – SoWell-tutkimushankkeen laaja kyselyaineisto on valmistunut
2021
publishedVersion Non peer reviewed
An Updated Review on the Synthesis and Antibacterial Activity of Molecular Hybrids and Conjugates Bearing Imidazole Moiety
2020
The rapid growth of serious infections caused by antibiotic resistant bacteria, especially the nosocomial ESKAPE pathogens, has been acknowledged by Governments and scientists and is one of the world’s major health problems. Various strategies have been and are currently investigated and developed to reduce and/or delay the bacterial resistance. One of these strategies regards the design and development of antimicrobial hybrids and conjugates. This unprecedented critical review, in which our continuing interest in the synthesis and evaluation of the bioactivity of imidazole derivatives is testified, aims to summarise and comment on the results obtained from the end of the 1900s until Februa…
L'interprete al cinema: stereotipi, pregiudizi e realtà
2020
The figure of the interpreter in history has always oscillated between visibility and invisibility. Although today there is a tendency to give it increasing recognition, some categories (cultural mediators, war and sign interpreters) still remain in a poorly recognized situation and often operate in precarious working conditions. The interpreter as a subject of study has been present in world literature for years. We will investigate what has become the interpreter as a subject in world cinema. What is the semiotic process for which a given image of the interpreter communicates a certain cliché or suggests certain characteristics that the director (or the screenwriter) wanted to highlight. …
Using the Electronics Development Advantage in Creating a Buzz for the Airline Passengers
2013
More and more airlines are trying to show their customers their ability to understand their needs, the market trends and the importance of technology in their lives. In response to the rapid development of the consumer electronics, the airline companies focus their attention on offering their customers the possibility to book a flight or check-in using a smartphone, spend time watching movies or be connected to the internet during the flight. Customers search for airlines who are more ”tech-geek” and opened to new technologies, which allows them to rate the airline companies through apps or connect more often with the airline through social-media. Technology has become an important part in …
O Brasil na rota das migrações internacionais qualificadas espanholas no século XXI
2018
In order to understand recent migration, it is crucial to analyze the migratory modalities such as skilled international migration to Brazil, especially considering the ongoing transnational economic processes and their effects on the corresponding societies. Therefore, this article seeks to understand how the migratory dynamics of highly skilled Spanish professionals to the country are established taking into account the theoretical contribution of the circulation of brains and the category of knowledge workers. For this purpose, information from Brazilian?s Ministry of Labor is used on labor authorizations, financial contributions and insertion in the formal market in Spain; as well as da…
Post-synthesis alumination of MCM-41: Effect of the acidity on the HDS activity of supported Pd catalysts
2010
Abstract Siliceous MCM-41 with different amount of alumina, from 0.25 up to 4.0 wt%, were prepared by impregnation of the MCM-41 with aqueous solution of Al(NO) 3 ·9H 2 O. The modified mesoporous silicas were then used as supports for Pd catalysts prepared by wet-impregnation from PdCl 2 precursor. Supports and corresponding Pd catalysts were characterized by XRD, XPS and NH 3 -TPD. The catalytic behavior was tested in the hydrodesulfurization (HDS) reaction of thiophene. An increase of the hydrodesulfurization activity with increasing alumina amount up to 0.5 wt% was observed. On the basis of the acidity change of the support and the structural modification underwent by the deposited palla…
Nature of cobalt active species in hydrodesulfurization catalysis: combined support and preparation method effects
2007
Abstract Co/γ-Al2O3, Co/SiO2, Co/MCM-41, Co/ASA and Co/S2 (amorphous aluminosilicate with Al/Si = 0.13 and with Al/Si ≈ 2, respectively) were prepared by the method of wet impregnation and by the method of precipitation in the presence of sodium carbonate. The samples were characterised by XPS, XRD and TPR. The catalytic activity was tested in the hydrodesulfurization of thiophene using a continuous flow reactor. Among the wet impregnated catalysts those supported on the amorphous and ordered mesoporous silica exhibited higher HDS activity as compared to the alumina containing supports. Particularly, the use of the mesoporous, high surface area MCM-41 support, determined the best performing…
Halogen bonding and host–guest chemistry between N-alkylammonium resorcinarene halides, diiodoperfluorobutane and neutral guests
2019
Single crystal X-ray structures of halogen-bonded assemblies formed between host N-hexylammonium resorcinarene bromide (1) or N-cyclohexylammonium resorcinarene chloride (2), and 1,4-diiodooctafluorobutane and accompanying small solvent guests (methanol, acetonitrile and water) are presented. The guests’ inclusion affects the geometry of the cavity of the receptors 1 and 2, while the divalent halogen bond donor 1,4-diiodooctafluorobutane determines the overall nature of the halogen bond assembly. The crystal lattice of 1 contains two structurally different dimeric assemblies A and B, formally resulting in the mixture of a capsular dimer and a dimeric pseudo-capsule. 1H and 19F NMR analyses …
A kinetic study of the basic hydrolysis of 2-phenylethyl nitrite in the presence of borate buffer and β-cyclodextrin
2002
The kinetics of the hydrolysis of 2-phenylethyl nitrite have been studied in basic aqueous solutions (borate buffer) in the absence and presence of β-cyclodextrin. The observed kinetic trends show that the hydrolysis reaction consists of at least three subsequent processes. The first is a fast acid-base reaction between the boron atom of boric acid and oxygen atom of the alkyl nitrite. The second one should be the nucleophilic attack of hydroxyl ion on the alkyl nitrite. The last process could be referred to as a combination of transfer of hydrogen acid to a water molecule followed by ruptures of nitrogen-oxygen and boron-oxygen bonds. The effect of β- cyclodextrin on each process is also d…