Search results for "44"
showing 10 items of 1507 documents
Stabilisation of Exotic Tribromide (Br3−) Anions via Supramolecular Interaction with A Tosylated Macrocyclic Pyridinophane. A Serendipitous Case.
2020
Tetraaza-macrocyclic pyridinophane L-Ts, decorated with a p-toluenesulfonyl (tosyl
Chemical Composition and Evaluation of Insecticidal Activity of Calendula incana subsp. maritima and Laserpitium siler subsp. siculum Essential Oils …
2022
The problems of the environment and human health related to the use of synthetic and broad-spectrum insecticides have increasingly motivated scientific research on different alternatives and among these, the use of green systems, such as essential oils, have been explored. Several species of the Apiaceae and Asteraceae families, aromatic herbs rich in secondary bioactive metabolites, are used in the industrial field for pharmaceutical, cosmetic, and food purposes. Different essential oils extracted from some species of these families have shown acute toxicity and attractive and/or repellent effects towards different insects. In our work, we investigated the toxic potential of Calendula inca…
A new member of the fusaricidin family – structure elucidation and synthesis of fusaricidin E
2017
Two hitherto unknown fusaricidins were obtained from fermentation broths of three Paenibacillus strains. After structure elucidation based on tandem mass spectrometry and NMR spectroscopy, fusaricidin E was synthesized to confirm the structure and the suggested stereochemistry. The synthesis was based on a new strategy which includes an efficient access to the 15-guanidino-3-hydroxypentadecanoyl (GHPD) side chain from erucamide.
Single π0 production off neutrons bound in deuteron with linearly polarized photons
2021
The quasifree γ→d→π0n(p) photon beam asymmetry, Σ, has been measured at photon energies, Eγ, from 390 to 610 MeV, corresponding to center of mass energy from 1.271 to 1.424 GeV, for the first time. The data were collected in the A2 hall of the MAMI electron beam facility with the Crystal Ball and TAPS calorimeters covering pion center-of-mass angles from 49∘ to 148∘. In this kinematic region, polarization observables are sensitive to contributions from the Δ(1232) and N(1440) resonances. The extracted values of Σ have been compared to predictions based on partial-wave analyses (PWAs) of the existing pion photoproduction database. Our comparison includes the SAID, MAID and Bonn–Gatchina anal…
IL LAVORATORE DIABETICO: LA GESTIONE INTEGRATA DELL’IDONEITÀ LAVORATIVA SPECIFICA
2017
diabete, idoneità lavorativa
Introducing Teenagers to a Dialogue with Judaism as the Task of School Catechesis
2014
This analysis proves that introducing teenagers to a dialogue with Judaism is one of catechesis’s tasks. This task has been outlined in the post-conciliar documents of the Catholic Church. It underlines the spiritual ties between Catholic people and the Jews and promotes forming an attitude of openness towards followers of the Mosaic religion. It also contributes to mitigating anti-Semitism among Catholic teenagers. At the same time, it raises interest in Jewish traditions and culture. In the religion syllabus in lower and post-secondary schools we can come across numerous references (mainly indirect) to Judaism. The focus on passing honest knowledge about Judaism can be also clearly visibl…
Unusual Regioselectivity in the Opening of Epoxides by Carboxylic Acid Enediolates
2008
Addition of carboxylic acid dianions appears to be a potential alternative to the use of aluminium enolates for nucleophilic ring opening of epoxides. These conditions require the use of a sub-stoichiometric amount of amine (10% mol) for dianion generation and the previous activation of the epoxide with LiCl. Yields are good, with high regioselectivity, but the use of styrene oxide led, unexpectedly, to a mixture resulting from the attack on both the primary and secondary carbon atoms. Generally, a low diastereoselectivity is seen on attack at the primary center, however only one diastereoisomer was obtained from attack to the secondary carbon of the styrene oxide.