Search results for "44"
showing 10 items of 1507 documents
Report of the Scientific Committee of the Spanish Agency for Food Safety and Nutrition (AESAN) on the assessment of olive oil by its nutritional char…
2021
* This record is given in both English and Spanish. The Nutri-Score front-of-pack nutritional labelling system uses a code of letters and colours to inform consumers about the nutritional quality of foods and drinks. However, currently this system does not cover all the positive aspects of foods that possess a specific nutritional quality within the Mediterranean diet, as in the case of olive oil and extra-virgin olive oil. The AESAN Scientific Committee has suggested different possibilities for a more accurate assessment of olive oil and especially virgin olive oil, in the Nutri-Score front-of-pack labelling system, taking into consideration those compounds that are beneficial to the consu…
Complexes of Glycolic Acid with Nitrogen Isolated in Argon Matrices. I. Structures and Thermal Effects.
2019
Molecular complexes between glycolic acid and nitrogen were studied in a low-temperature argon matrix with FTIR spectroscopy, and supported by MP2 and BLYPD3 calculations. The calculations indicate 11 and 10 stable complex structures at the MP2 and BLYPD3 levels of theories, respectively. However, only one hydrogen-bonded complex structure involving the most stable SSC conformer of glycolic acid was found experimentally, where the nitrogen molecule is bound with the carboxylic OH group of the SSC conformer. The complex shows a rich site structure variation upon deposition of the matrix in different temperatures and upon annealing experiments, which provide interesting prospects for site-sel…
Matrix Isolation FTIR and Theoretical Study of Weakly Bound Complexes of Isocyanic Acid with Nitrogen.
2021
Weak complexes of isocyanic acid (HNCO) with nitrogen were studied computationally employing MP2, B2PLYPD3 and B3LYPD3 methods and experimentally by FTIR matrix isolation technique. The results show that HNCO interacts specifically with N2. For the 1:1 stoichiometry, three stable minima were located on the potential energy surface. The most stable of them involves a weak, almost linear hydrogen bond from the NH group of the acid molecule to nitrogen molecule lone pair. Two other structures are bound by van der Waals interactions of N⋯N and C⋯N types. The 1:2 and 2:1 HNCO complexes with nitrogen were computationally tracked as well. Similar types of interactions as in the 1:1 complexes were …
Structure and IR Spectroscopic Properties of HNCO Complexes with SO
2021
FTIR spectroscopy was combined with the matrix isolation technique and quantum chemical calculations with the aim of studying complexes of isocyanic acid with sulfur dioxide. The structures of the HNCO⋯SO2 complexes of 1:1, 1:2 and 2:1 stoichiometry were optimized at the MP2, B3LYPD3, B2PLYPD3 levels of theory with the 6-311++G(3df,3pd) basis set. Five stable 1:1 HNCO⋯SO2 complexes were found. Three of them contain a weak N-H⋯O hydrogen bond, whereas two other structures are stabilized by van der Waals interactions. The analysis of the HNCO/SO2/Ar spectra after deposition indicates that mostly the 1:1 hydrogen-bonded complexes are present in argon matrices, with a small amount of the van de…
Del sacrilegio al desagravio. Culto y ritual de la imagen sagrada en la Valencia del primer franquismo
2021
El presente trabajo aborda, en primer lugar, la mirada sobre los ataques iconoclastas desde la perspectiva del primer franquismo y la construcción del discurso de regeneración nacional por medio de la idea del advenimiento de un nuevo tiempo cristiano. A continuación, se estudia la restitución al culto de las imágenes sagradas, seguido de un estudio del caso valenciano centrado principalmente en los ejemplos de la Virgen de los Desamparados y el Cristo del Grao como representantes de la activación de geografías devocionales. Las dos tesis principales del artículo son que los actos de desagravio se organizaron con la intención de construir un relato oficial de los actos iconoclastas y que fu…
An Updated Review on the Synthesis and Antibacterial Activity of Molecular Hybrids and Conjugates Bearing Imidazole Moiety
2020
The rapid growth of serious infections caused by antibiotic resistant bacteria, especially the nosocomial ESKAPE pathogens, has been acknowledged by Governments and scientists and is one of the world’s major health problems. Various strategies have been and are currently investigated and developed to reduce and/or delay the bacterial resistance. One of these strategies regards the design and development of antimicrobial hybrids and conjugates. This unprecedented critical review, in which our continuing interest in the synthesis and evaluation of the bioactivity of imidazole derivatives is testified, aims to summarise and comment on the results obtained from the end of the 1900s until Februa…
23 GHz VLBI observations of SN 2008ax (Research Note)
2009
We report on phase-referenced 23 GHz Very-Long-Baseline-Interferometry (VLBI) observations of the type IIb supernova SN 2008ax, made with the Very Long Baseline Array (VLBA) on 2 April 2008 (33 days after explosion). These observations resulted in a marginal detection of the supernova. The total flux density recovered from our VLBI image is 0.8 ± 0.3 mJy (one standard deviation). As it appears, the structure may be interpreted as either a core-jet or a double source. However, the supernova structure could be somewhat confused with a possible close by noise peak. In such a case, the recovered flux density would decrease to 0.48 ± 0.12 mJy, compatible with the flux densities measured with the…
O Brasil na rota das migrações internacionais qualificadas espanholas no século XXI
2018
In order to understand recent migration, it is crucial to analyze the migratory modalities such as skilled international migration to Brazil, especially considering the ongoing transnational economic processes and their effects on the corresponding societies. Therefore, this article seeks to understand how the migratory dynamics of highly skilled Spanish professionals to the country are established taking into account the theoretical contribution of the circulation of brains and the category of knowledge workers. For this purpose, information from Brazilian?s Ministry of Labor is used on labor authorizations, financial contributions and insertion in the formal market in Spain; as well as da…
Infortuni e lavoratori stranieri: analisi di un fenomeno in costante evoluzione
2010
Giornale Italiano di Medicina del Lavoro ed Ergonomia