Search results for "547"
showing 10 items of 76 documents
Diseño de ligandos quirales con estructura de imino- y aminopiridina. Aplicación a la reacción de Henry Enantioselectiva
2010
El resumen tanto en castellano como en inglés se adjuntan junto con el archivo de la tesis.
Acid Catalysis with Alkane/Water Microdroplets in Ionic Liquids
2021
Ionic liquids are composed of an organic cation and a highly delocalized perfluorinated anion, which remain tight to each other and neutral across the extended liquid framework. Here we show that n-alkanes in millimolar amounts enable a sufficient ion charge separation to release the innate acidity of the ionic liquid and catalyze the industrially relevant alkylation of phenol, after generating homogeneous, self-stabilized, and surfactant-free microdroplets (1–5 μm). This extremely mild and simple protocol circumvents any external additive or potential ionic liquid degradation and can be extended to water, which spontaneously generates microdroplets (ca. 3 μm) and catalyzes Brönsted rather …
Chiroptical inversion of a planar chiral redox-switchable rotaxane.
2019
Reversible redox-switching of a planar chiral [2]rotaxane with a tetrathiafulvalene-bearing crown ether macrocycle generates a complete sign reversal of the main band in the ECD spectrum, as shown by experiment and rationalised by DFT calculations.
Transposiciones de eudesmanos dirigidas por silicio. Aplicación a la síntesis de eremofilanos y sesquiterpenos espiránicos
2002
"TRANSPOSICIONES DE EUDESMANOS DIRIGIDAS POR SILICIO. APLICACIÓN A LA SÍNTESIS DE EREMOFILANOS Y SESQUITERPENOS ESPIRÁNICOS." La tesis plantea la posibilidad de desarrollar un método que permita acceder de manera sistemática a la obtención de compuestos con esqueleto carbonado de tipo eremofilano o espiro[4.5]decano a partir de la transposición de trialquilsililepoxieudesmanos, en los cuales el grupo trialquilsililo ejerce un efecto director que determina el grupo que migra en la transposición gracias a la capacidad que posee el enlace carbono-silicio de estabilizar un carbocatión en la posición b (efecto b) y de eliminar con facilidad para dar un doble enlace, evitando que se produzcan rea…
Relationships among nasal resistance, age and anthropometric parameters of the nose during growth
2018
Background: Children generally have a higher nasal resistance than adults. Growth changes the size and different anthropometric parameters of the nose. Logarithmic effective resistance and logarithmic vertex resistance were introduced as physically correct parameters for nasal obstruction. The previously published classification of obstruction derived from 36,500 measurements is missing data for patients aged 7 to 19 years. Methodology: Rhinomanometry was performed before and after decongestion with 9 different anthropometric measurements in 225 children and adolescents. Correlations among age, anthropometric measurements, and logarithmic effective and vertex resistance were determined for …
IFT46 Expression in the Nasal Mucosa of Primary Ciliary Dyskinesia Patients: Preliminary Study
2021
Este artículo se encuentra disponible en la siguiente URL: https://journals.sagepub.com/doi/pdf/10.1177/2152656721989288 Background: Primary ciliary dyskinesia (PCD) is characterised by an imbalance in mucociliary clearance leading to chronic respiratory infections. Cilia length is considered to be a contributing factor in cilia movement. Recently, IFT46 protein has been related to cilia length. Therefore, this work aims to study IFT46 expression in a PCD patients cohort and analyse its relationship with cilia length and function, as it was not previously described. Materials and methods: The expression of one intraflagellar transport (IFT46) and two regulating ciliary architecture (FOXJ1 a…
Voz cantada y Electromiografía de Superficie: Un estudio comparativo de la actividad muscular en cantantes formados y no formados
2018
En los últimos años ha habido un incremento del uso de la Electromiografía de Superficie en logopedia, lo que se evidencia en el número creciente de publicaciones en este área en revistas científicas. Este instrumento permite presentar de forma objetiva y precisa la actividad mioeléctrica en tiempo real, es no invasiva y se percibe de fácil aplicación. El objetivo de este trabajo es comparar la actividad mioeléctrica de los músculos maseteros, suprahioideos y esternoicleidomastoideos de cantantes con y sin entrenamiento vocal reglado a través de la Electromiografía de Superficie durante la realización de un fonetograma. La muestra estuvo conformada por 12 sopranos con edades entre 19 y 29 a…
The Impact of Narrow-band Imaging on the Pre- and Intra- operative Assessments of Neoplastic and Preneoplastic Laryngeal Lesions. A Systematic Review
2020
Abstract Introduction Narrow-band imaging is an endoscopic diagnostic tool that, focusing on superficial vascular changes, is useful to detect suspicious laryngeal lesions, enabling their complete excision with safe and tailored resection margins. Objectives To analyze the applications and benefits of narrow-band imaging in detecting premalignant and malignant laryngeal lesions through a comparison with white-light endoscopy. Data Synthesis A literature search was performed in the PubMed, Scopus and Web of Science databases using strict keywords. Then, two authors independently analyzed the articles, read the titles and abstracts, and read completely only the relevant studies according to c…
Canine fossa puncture in endoscopic sinus surgery: report of two cases
2017
Abstract Introduction Chronic rhinosinusitis with nasal polyposis is a common chronic disease that often affects maxillary sinus. Endoscopic sinus surgery is the most common procedure for treating the majority of maxillary sinus lesions. Objective To demonstrate the role of canine fossa puncture during endoscopic sinus surgery procedure in patients with severe maxillary sinus disease. Methods We present 2 cases where canine fossa puncture has been performed as method to obtain a complete access to the maxillary antrum. Results According our experience, 2 cases on 296 endoscopic sinus surgery (0.6%) where antrostomy and used of angled microdebrider were not sufficient, canine fossa puncture …
Top-cited articles in cerebrospinal fluid leak (rhinorrhea and otorrhea) (1945–2018)
2021
Abstract Introduction: As scientific knowledge has grown in biomedicine, it has also become necessary to develop tools to manage and understand the body of evidence. In that sense, bibliometrics has become a consolidated discipline for analyzing scientific activity, enabling the characterization of a particular field or area of knowledge by means of the quantification of the bibliographic characteristics of scientific publications. Objective: The objective of this study was to determine the most frequently cited articles in the field of cerebrospinal fluid rhinorrhea and otorrhea. Methods: The searches took place on the Clarivate Analytics Web of Science platform, which includes the MEDLINE…